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21.
公开(公告)号:CA2345727A1
公开(公告)日:2000-04-20
申请号:CA2345727
申请日:1999-09-28
Applicant: BASF AG
Inventor: STUVEN UWE , ENGELHARDT FRITZ , SCHLIWA RUDOLF , DENTLER JOACHIM , HERFERT NORBERT
IPC: A61F13/15 , A61F13/53 , A61L15/00 , A61L15/60 , B01J20/26 , B01J20/30 , C08F2/01 , C08F8/44 , C08F220/06 , C08F251/00 , C08F261/04 , C08F283/00 , C08F283/02 , C08F283/06 , C08F291/00 , C08J3/12 , C09K3/00
Abstract: The invention relates to a method for producing water-swellable hydrophilic polymers by neutralising the acid hydrogel with a degree of neutralisation o f 0 40 mol. % to a final degree of neutralisation of 60 85 mol. % by mixing wi th a neutralising agent in an opener using a system consisting of a screw, a rotating blade, a restricted flow area and a breaker plate, the capacity of the opener being 1000 to 6000 Wh/m3, the hydrogel being guided through an ar ea with an energy dissipation density of 400 to 800 W/l mixing volume, the average residence time of the hydrogel in the opener being 5 to 30 seconds, and the free perforated surface of the breaker plate being 20 to 40 %.
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公开(公告)号:DE19807504A1
公开(公告)日:1999-08-26
申请号:DE19807504
申请日:1998-02-21
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , STUEVEN UWE , ENGELHARDT FRITZ , DANIEL THOMAS
Abstract: 1,4,6,9-Tetraoxa-5-silaspiro(4.4)nonanes (diglycol silicates) (I) are used as crosslinking agents for surface crosslinking of particles of superabsorbing polymer. 1,4,6,9-Tetraoxa-5-silaspiro(4.4)nonanes (diglycol silicates) of formula (I) are used as crosslinking agents for surface crosslinking of particles of superabsorbing polymer: R, R' = hydrogen (H) or 1-6 carbon (C) alkyl. An Independent claim is also included for surface-crosslinked superabsorbing polymer produced in this way.
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公开(公告)号:DE59906513D1
公开(公告)日:2003-09-11
申请号:DE59906513
申请日:1999-02-24
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
Abstract: The invention contains a process for the surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked by means of an increase in temperature and are dried, wherein the crossiinker comprises a bis-2-oxazolidinone or a poly-2-oxazolidinone comprising structural units of the formulain which R1 is branched or unbranched C1-C18-alkylene, branched or unbranched C2-C18-alkenylene, C5-C18-cycloalkylene, phenylene, naphthylene, anthracenylene, hydrocarbon-substituted phenylene, naphthylene or anthracenylene or another substituted or unsubstituted C6-C18-arylene radical, R2 is branched or unbranched C1-C18-alkylene and n is an integer from 1 to 50 or a mixture of bis-2-oxazolidinones and poly-2-oxazolidinones dissolved in an inert solvent.
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公开(公告)号:ES2172310T3
公开(公告)日:2002-09-16
申请号:ES99910244
申请日:1999-02-19
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , STUVEN UWE , ENGELHARDT FRITZ , DANIEL THOMAS
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25.
公开(公告)号:PL347244A1
公开(公告)日:2002-03-25
申请号:PL34724499
申请日:1999-09-28
Applicant: BASF AG
Inventor: DENTLER JOACHIM , HERFERT NORBERT , SCHLIWA RUDOLF , STUEVEN UWE , ENGELHARDT FRITZ
IPC: A61F13/15 , A61F13/53 , A61L15/00 , A61L15/60 , B01J20/26 , B01J20/30 , C08F2/01 , C08F8/44 , C08F220/06 , C08F251/00 , C08F261/04 , C08F283/00 , C08F283/02 , C08F283/06 , C08F291/00 , C08J3/12 , C09K3/00
Abstract: Water-swellable hydrophilic polymers are prepared by neutralization of the acidic hydrogel having a degree of neutralization of 0-40 mol % to an ultimate degree of neutralization of 60-85 mol % by mixing with a neutralizing agent in a mincer comprising a system of screw, rotating blade, restricted flow zone and breaker plate, whereinthe mincer has a power output of from 1000 to 6000 Wh/m3the hydrogel passes through a zone having-an energy dissipation density of from 400 to 800 W/1 of mixing volumethe average residence time of the hydrogel in the mincer is from 5 to 30 secondsthe breaker plate has an open area of from 20 to 40%.
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公开(公告)号:DE59900628D1
公开(公告)日:2002-02-21
申请号:DE59900628
申请日:1999-02-19
Applicant: BASF AG
Inventor: FUNK RUEDIGER , FRENZ VOLKER , STUEVEN UWE , ENGELHARDT FRITZ , DANIEL THOMAS
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公开(公告)号:DE19854574A1
公开(公告)日:2000-05-31
申请号:DE19854574
申请日:1998-11-26
Applicant: BASF AG
Inventor: RIEGEL ULRICH , WEISMANTEL MATTHIAS , FRENZ VOLKER , DANIEL THOMAS , ENGELHARDT FRITZ
IPC: A21B1/22 , A21B1/44 , A61F13/53 , A61L15/60 , C08F8/30 , C08J3/24 , C08K5/353 , C08L101/00 , D04H1/42 , D06M15/263 , C08F8/00
Abstract: The invention relates to a method for the secondary gel and/or surface cross-linking of water-absorbent polymers, according to which the polymers are treated with a surface cross-linking solution and during or after this treatment subjected to secondary cross-linking and drying by temperature elevation. The method is characterized in that as cross-linking agent the solution for secondary surface cross-linking contains, dissolved in an inert solvent, a compound of formula (I) in which R , R , R , R independently of each other are hydrogen, C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl or C1-C12-alkoxy; R is C1-C16-alkyl, C1-C4-hydroxyalkyl, C6-C12-aryl, C1-C16-alkenyl or a group of the formula -(CH2)n-COOH or -(CH2)n-SO3H in the acid form or in the form of their metal salts, ammonium salts or triethanol ammonium salts or -(CH2-CH2-O-)m-R ; R is hydrogen or C1-C16-alkyl; n is a number between 1 and 10; and m is a number between 1 and 20. The invention also relates to the liquid-absorbent polymers obtained in this manner and to their use in hygiene articles, packaging materials and nonwovens.
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公开(公告)号:AU2726199A
公开(公告)日:1999-09-15
申请号:AU2726199
申请日:1999-02-24
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MATTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
Abstract: The invention contains a process for the surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked by means of an increase in temperature and are dried, wherein the crossiinker comprises a bis-2-oxazolidinone or a poly-2-oxazolidinone comprising structural units of the formulain which R1 is branched or unbranched C1-C18-alkylene, branched or unbranched C2-C18-alkenylene, C5-C18-cycloalkylene, phenylene, naphthylene, anthracenylene, hydrocarbon-substituted phenylene, naphthylene or anthracenylene or another substituted or unsubstituted C6-C18-arylene radical, R2 is branched or unbranched C1-C18-alkylene and n is an integer from 1 to 50 or a mixture of bis-2-oxazolidinones and poly-2-oxazolidinones dissolved in an inert solvent.
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公开(公告)号:MY124251A
公开(公告)日:2006-06-30
申请号:MYPI9900614
申请日:1999-02-22
Applicant: BASF AG
Inventor: FUNK RUDIGER , FRENZ VOLKER , RIEGEL ULRICH , WEISMANTEL MARTHIAS , ENGELHARDT FRITZ , DANIEL THOMAS
IPC: C07D263/20 , C08F8/30 , A61L15/00 , A61L15/60
Abstract: THE INVENTION RELATES TO A PROCESS FOR THE GEL OR SURFACE POSTCROSSLINKING OF WATER- ABSORBING POLYMERS IN WHICH THE POLYMERS ARE TREATED WITH A SURFACE POSTCROSSLINKING SOLUTION AND DURING OR AFTER THE TREATMENT ARE POSTCROSSLINKED AND DRIED BY MEANS OF AN INCREASE IN TEMPERATURE, THE CROSSLINKER BEING A COMPOUND OF THE FORMULA IN WHICH R1 AND R2 INDEPENDENTLY OF ONE ANOTHER ARE H , HYDROXYL, PHENYL OR C1-C6- ALKYL, R3 IS HYDROGEN. C1-C12- ALKYL , C1-C12- ALKYL, C1-C12- ALKENYL OR C6-C12-ARYL AND R4 AND R5 INDEPENDENTLY OF ONE ANOTHER ARE C1-C12- ALKYL, C1-C12- ALKENYL, C6-C12- ARYL, HYDROXYL, C1-C12- ALKOXY OR HYDROGEN, DISSOLVED IN AN INERT SOLVENT, TO WATER- ABSORBING POLYMERS WHICH CAN BE OBTAINED BY SAID PROCESS, AND TO THEIR USE IN HYGIENE ARTICLES, PACKAGING MATERIALS AND NONWOVENS.
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公开(公告)号:DE59902461D1
公开(公告)日:2002-10-02
申请号:DE59902461
申请日:1999-01-20
Applicant: BASF AG
Inventor: FUNK RUEDIGER , HERFERT NORBERT , RIEGEL ULRICH , WEISMANTEL MATTHIAS , DANIEL THOMAS , ENGELHARDT FRITZ
IPC: C08J7/04 , B01J13/02 , B01J20/26 , C08F251/00 , C08F251/02 , C08J3/12 , C08L51/00 , C08L51/02
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