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公开(公告)号:DE883650C
公开(公告)日:1953-07-20
申请号:DEB0006849
申请日:1942-05-21
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , UFER HANNS DR
IPC: C08G73/00
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公开(公告)号:DE874309C
公开(公告)日:1953-04-23
申请号:DEB0016397
申请日:1951-08-22
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , GASSENMEIER ERNST DR
IPC: C07C307/02
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公开(公告)号:DE873746C
公开(公告)日:1953-04-16
申请号:DEB0006573
申请日:1935-12-14
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , STEINBRUNN GUSTAV DR , FREUDENBERGER HEINRICH DR
IPC: B29D23/20 , B65D65/38 , C08F2/22 , C08F214/06 , C08F222/14 , C09J127/06 , D01F6/08 , D06M15/263 , H01B3/18
Abstract: The invention described in the parent Specification is modified by the use of fumaric instead of maleic esters, the products being useful for the same purposes. In examples: (1) vinyl chloride and dimethyl fumarate are emulsified in an aqueous solution of sodium a -hydroxyoctodecane sulphonate, hydrogen peroxide, potassium persulphate and formic acid, and polymerized at 40 to 45 DEG C., the polymerizate being coagulated by aluminium sulphate solution, washed with water followed by dilute caustic soda, filtered, and dried to give a product soluble in methylene chloride; (2) diethyl fumarate is emulsified in an aqueous solution of sodium a -hydroxyoctodecane sulphonate, sodium persulphate, hydrogen peroxide, and ammonium formate, and vinyl chloride is added, the mixture being then polymerized at 45 DEG C., unchanged fumarate being blown off by steam and the product worked up as in example 1. There may be used instead of diethyl fumarate the neutral fumarate of ethylene glycol monomethyl ether or di-n- or di-iso-butyl fumarate or the fumarates of mixtures of aliphatic alcohols having 6 and 7 carbon atoms (such as are obtained in the catalytic hydrogenation of carbon monoxide), the products being particularly suitable for insulating and jacketing cables. Specifications 376,479 and 466,898 are referred to.
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公开(公告)号:DE871514C
公开(公告)日:1953-03-23
申请号:DEB0007623
申请日:1942-06-24
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , RAUTENSTRAUCH CURT DR , KLING AUGUST DR
IPC: C08F214/08
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公开(公告)号:DE869868C
公开(公告)日:1953-03-09
申请号:DEB0002032
申请日:1950-02-12
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , JOST KONRAD DR
IPC: C08F220/44
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公开(公告)号:DE856682C
公开(公告)日:1952-11-24
申请号:DEB0007079
申请日:1941-10-18
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , UFER HANNS DR
IPC: C10L1/16
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公开(公告)号:DE850007C
公开(公告)日:1952-09-22
申请号:DEB0013140
申请日:1950-12-22
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , TRIEM GEORG DR , SPAENIG HERMANN DR
IPC: C07D207/26 , C07D207/267 , C07D207/27
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公开(公告)号:DE842345C
公开(公告)日:1952-06-26
申请号:DEP0024412
申请日:1948-12-11
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , SPAENIG HERMANN DR , SCHUSTER CURT DR
IPC: C07D295/13
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公开(公告)号:DE803004C
公开(公告)日:1951-02-26
申请号:DEP0003090
申请日:1948-10-02
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR , SCHUSTER CURT DR
IPC: C07D339/08 , C08G61/12
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公开(公告)号:DE801120C
公开(公告)日:1950-12-21
申请号:DEP0001056
申请日:1948-10-02
Applicant: BASF AG
Inventor: HOPFF HEINRICH DR
IPC: B60C19/12
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