公开(公告)号：CA703735A

公开(公告)日：1965-02-09

申请号：CA703735D

Applicant: BASF AG

Inventor： HORNBERGER PAUL ,  CORR HUBERT ,  HAARER ERICH ,  WINDERL SIEGFRIED

公开(公告)号：GB921477A

公开(公告)日：1963-03-20

申请号：GB1774261

申请日：1961-05-16

Applicant: BASF AG

Inventor： CORR HUBERT ,  HAARER ERICH ,  HORNBERGER PAUL

IPC: C07C29/149

Abstract: Catalysts for the hydrogenation of carboxylic acids to alcohols consist of a metal hydrogenation catalyst, the catalytic activity of which is impaired by sulphur, and which is prepared by sintering the metals which may be used are preferably copper, silver, manganese, iron, nickel and especially cobalt and may be supported on pumice, alumina, kieselguhr, silica gel, synthetic or natural silicates, porcelain or quartz. The "sintering" is defined as heating the catalyst to a temperature which is not high enough to melt the catalyst but high enough to unite the particles in order to reduce the surface area and to improve the mechanical strength. If desired the oxide of the metal may be sintered and then reduced to the metal.ALSO:Carboxylic acids are hydrogenated in the liquid phase to alcohols at elevated temperature and at atmospheric or increased pressure by means of hydrogen in the presence of a metal hydrogenation catalyst, the catalytic activity of which is impaired by sulphur, and which has been prepared by sintering. The term "prepared by sintering" is defined as heating the catalyst to a temperature which is not high enough to melt the catalyst but high enough to unite the particles to reduce the surface area and to improve the mechanical strength. The process is particularly suitable for the hydrogenation of fatty acids with 3-20 carbon atoms, alkanoic dicarboxylic acids with 3-12 carbon atoms, aliphatic hydroxycarboxylic acids with 4-8 carbon atoms, aromatic hydroxycarboxylic acids with 7-9 carbon atoms, mononuclear aromatic monoor dicarboxylic acids and cycloalkanoic monoand dicarboxylic acids with 5 or 6 carbon atoms in the ring. The acids are preferably treated in aqueous or alcoholic solution at 150-300 DEG C The preferred catalysts are copper, silver, manganese, iron, nickel and especially cobalt. The catalyst may be sintered, if desired, in admixture with carrier substances such as pumice, alumina, kieselguhr, silica gel, silicates, porcelain or quartz, at temperatures which preferably lie only just below the melting-point of the metal used. The oxides of the metals may be used as starting materials for the catalysts and in this case they are sintered and then reduced to the metal. Examples are given of the conversion of (a) adipic acid to hexane-diol-(1,6); (b) glutaric acid to pentane-diol-(1,5); (c) the acid-containing product obtained by the oxidation of cyclohexane to a mixture of hexanediol-(1,6), pentanediol-(1,5) and butane-diol-(1,4); (d) propionic acid to n-propyl alcohol; (e) benzoic acid to benzyl alcohol; (f) cyclohexyl carboxylic acid to cyclohexyl carbinol; (g) salicylic acid to salicyl alcohol and (h) o -hydroxycaproic acid to hexanediol-(1,6).