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公开(公告)号:DE4134497A1
公开(公告)日:1993-04-22
申请号:DE4134497
申请日:1991-10-18
Applicant: BASF AG
Inventor: MERGER FRANZ DR , BRUDERMUELLER MARTIN DR , SCHMIDT-RADDE MARTIN DR
IPC: C07C29/141 , C07C29/145 , C07C33/46 , C07C41/18 , C07C43/174
Abstract: Process for the preparation of 4-halobenzyl alcohols of the general formula I … … in which …… R represents hydrogen, C1- to C20-alkyl, C2- to C20-alkoxyalkyl, C3- to C20-cycloalkyl, C4- to C30-cycloalkylalkyl, … R represents C1- to C20-alkyl, C2- to C20-alkoxyalkyl, C3- to C20-cycloalkyl, C4- to C30-cycloalkylalkyl, … X represents halogen and … m represents 0 to 2, … in which haloaromatic carbonyl compounds of the formula II … … in which the substituents R , R and X and the index m have the abovementioned meaning, are reacted with hydrogen in the presence of an amine on copper catalysts at 50 to 130 DEG C and pressures of 10 to 200 bar, if appropriate in the presence of an inert solvent.