公开(公告)号：MX383585B

公开(公告)日：2025-03-14

申请号：MX2016001031

申请日：2016-01-22

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： SCHRÖDER ALEXANDER ,  PARVULESCU ANDREI-NICOLAE ,  SEELIG BIANCA ,  BARTOSCH CHRISTIAN ,  URBANCZYK DANIEL ,  RIEDEL DOMINIC ,  TELES JOAQUIM HENRIQUE ,  WEBER MARKUS ,  RESCH PETER ,  KAMPE PHILIP ,  MÜLLER ULRICH ,  WEGERLE ULRIKE

IPC: B01J29/90 ,  B01J29/70 ,  B01J29/89 ,  B01J35/00 ,  B01J37/00 ,  B01J37/02 ,  B01J37/06 ,  B01J37/10 ,  B01J38/48 ,  C07D301/12 ,  C07D303/04

Abstract: La presente invención se refiere a un proceso para la regeneración de un catalizador que comprende una zeolita que contiene titanio, donde dicho catalizador ha sido utilizado en un proceso para la preparación de un óxido de olefina y que tiene fosfato depositado en la misma, donde dicho proceso para la regeneración comprende las etapas de : (a) separar la mezcla de reacción del catalizador, (b) lavar el catalizador obtenido del punto (a) con sistema acuoso líquidos; (c) opcionalmente secar el catalizador obtenido del punto (b) en una corriente gaseosa que comprende un gas inerte a una temperatura de menos de 300°C; (d) calcinar el catalizador obtenido de (c) en una corriente gaseosa que comprende oxígeno a una temperatura de al menos 300°C.

公开(公告)号：SG11201600530YA

公开(公告)日：2016-02-26

申请号：SG11201600530Y

申请日：2014-07-16

Applicant: BASF SE ,  DOW GLOBAL TECHNOLOGIES LLC

Inventor： TELES JOAQUIM HENRIQUE ,  SEELIG BIANCA ,  RIEDEL DOMINIC ,  KAMPE PHILIP ,  URBANCZYK DANIEL ,  WEBER MARKUS ,  MÜLLER ULRICH ,  PARVULESCU ANDREI-NICOLAE ,  GUMLICH KAI ,  BASSLER PETER ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF ,  WITZL WERNER

IPC: B01J29/89 ,  B01J27/16 ,  B01J37/02 ,  C07D301/12

Abstract: A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, optionally propane, and at least one dissolved potassium salt of a phosphorus oxyacid wherein the molar ratio of potassium relative to phosphorus in the at least one potassium salt of a phosphorus oxyacid is in the range of from 0.6 to 1.4; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW comprising zinc, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation reactor, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane; (iii) removing an effluent stream from the epoxidation reactor, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the at least one dissolved potassium salt of a phosphorus oxyacid, optionally propene, and optionally propane.

公开(公告)号：ZA201305012B

公开(公告)日：2014-09-25

申请号：ZA201305012

申请日：2013-07-04

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  BASSLER PETER ,  BARTOSCH CHRISTIAN ,  KAMPE PHILIP ,  GOBBEL HANS-GEORG ,  MULLER ULRICH ,  JACUBINAS RICHARD

IPC: C07D20060101

Abstract: A continuous process for the production of propylene oxide comprising reacting propene with hydrogen peroxide in methanolic solution in the presence of a titanium silicalite-1 catalyst to obtain propylene oxide, wherein a reaction feed comprising propene, methanol and hydrogen peroxide is introduced into a reactor, said reaction feed containing potassium cations and phosphorus in the form of anions of at least one phosphorus oxyacid.

公开(公告)号：ZA201109019B

公开(公告)日：2013-02-27

申请号：ZA201109019

申请日：2011-12-08

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： KAMPE PHILIP ,  RESCH PETER ,  CHIN SOO YIN ,  BABLER PETER ,  MULLER ULRICH ,  SCHINDLER GOTZ-PETER ,  GOBBEL HANS-GEORG ,  TELES JOAQUIM HENRIQUE ,  GUMLICH KAI ,  GRABLER THOMAS ,  BARTOSCH CHRISTIAN ,  JACUBINAS RICHARD ,  WEIDENBACH MEINOLF

IPC: C07D20060101

公开(公告)号：SG178027A1

公开(公告)日：2012-03-29

申请号：SG2012002499

申请日：2010-07-16

Applicant: BASF SE ,  DOW CHEMICAL CO

Inventor： TELES JOAQUIM HENRIQUE ,  GOEBBEL HANS-GEORG ,  BASLER PETER ,  KAMPE PHILIP ,  GUMLICH KAI ,  BARTOSCH CHRISTIAN ,  MUELLER ULRICH ,  JACUBINAS RICHARD ,  TRUKHAN NATALIA ,  WEIDENBACH MEINOLF ,  COGSWELL MARTIN

Abstract: A method for separating acetonitrile from water, comprising (i) providing a stream S1 containing at least 95 wt.-%, based on the total weight of S1, acetonitrile and water, wherein the weight ratio of acetonitrile : water is greater than 1; (ii) adding a stream P, comprising at least 95 wt.-% C3, based on the total weight of stream P, to S1 to obtain a mixed stream S2, C3 being propene optionally admixed with propane with a minimum weight ratio of propene : propane of 7:3; (iii) subjecting S2 to a temperature of 92 °C at most and a pressure of at least 10 bar, obtaining a first liquid phase L1 essentially consisting of C3, acetonitrile, and water, and a second liquid phase 12 essentially consisting of water and acetonitrile wherein the weight ratio of acetonitrile : water in L2 is less than 1; (iv) separating L1 from L2.