公开(公告)号：US11999816B2

公开(公告)日：2024-06-04

申请号：US16980084

申请日：2019-03-12

Applicant: BASF SE

Inventor： Frank Prissok ,  Elmar Poeselt ,  Dirk Kempfert ,  Lionel Gehringer ,  Juergen Weiser ,  Matthias Goldbeck

IPC: C08G18/50 ,  C08F4/80 ,  C08G18/76 ,  C08J11/04

CPC classification number: C08G18/5045 ,  C08F4/80 ,  C08G18/7671 ,  C08J11/04 ,  C08J2375/04

Abstract: The present invention relates to a process for producing a thermoplastic polyurethane reacting at least one thermoplastic polyurethane (TPU-1) or a polyurethane mixture comprising a thermoplastic polyurethane (TPU-1) with at least one compound (V1) comprising two hydroxyl groups to obtain a mixture (G-a) comprising a thermoplastic polyurethane (TPU-2) and the reaction of the mixture (G-a) with a mixture (G-b) comprising an isocyanate composition (ZI) comprising at least one diisocyanate and optionally and a polyol composition (ZP) comprising at least one polyol (P2) to obtain a thermoplastic polyurethane (TPU target), wherein the proportion of the employed components (ZI) and (ZP) is matched to the hard segment content of the employed thermoplastic polyurethane (TPU-1), (V1) and the hard segment content of the thermoplastic polyurethane (TPU target). The invention further relates to a thermoplastic polyurethane obtained or obtainable by such a process and to the use thereof for producing extruded, injection molded and pressed articles as well as foams, cable sheathings, hoses, profiles, drive belts, fibers, nonwovens, films, moldings, soles, sporting goods, shoes, plugs, housings, damping elements for the electricals industry, automotive industry, mechanical engineering, 3D printing, medicine and consumer goods.

公开(公告)号：US11739475B2

公开(公告)日：2023-08-29

申请号：US17753295

申请日：2020-08-28

Applicant: BASF SE

Inventor： Frank Prissok ,  Juergen Ahlers ,  Amir Doroodian ,  Michael Harms

IPC: D06N3/00 ,  D06N3/14 ,  B32B38/00 ,  B32B38/16

CPC classification number: D06N3/0095 ,  B32B38/164 ,  D06N3/0011 ,  D06N3/0027 ,  D06N3/14 ,  B32B2038/168 ,  B32B2305/026 ,  B32B2305/20 ,  B32B2309/02 ,  B32B2309/105 ,  B32B2375/00 ,  D06N2201/0281 ,  D06N2205/16 ,  D06N2209/123 ,  D06N2211/10 ,  D06N2211/106 ,  D06N2213/02 ,  D10B2401/10 ,  D10B2501/04

Abstract: A composite material contains a nonwoven layer (i) which contains fibers formed from a first thermoplastic elastomer having meshes with a mesh size in the range from 10 to 100 μm, and a membrane layer (ii) which contains a second thermoplastic elastomer and having a layer thickness of less than 30 μm. The membrane is either pore-free (ii.1) or is porous and has pores with an average pore diameter of less than 2000 nm (ii.2). The membrane (ii) is at least partially in direct contact with the fibers of the nonwoven layer (i) and covers the mesh openings in the nonwoven layer (i) at least partially. The fibers of the first nonwoven layer (i) and the membrane (ii) in the contact area are at least partly joined to one another in an interlocking manner.

公开(公告)号：US11161956B2

公开(公告)日：2021-11-02

申请号：US15557543

申请日：2016-03-11

Applicant: BASF SE

Inventor： Frank Prissok ,  Michael Harms ,  Markus Schuette

IPC: C08J9/232 ,  C08J9/224 ,  B29C44/34 ,  A43B13/04 ,  B29C35/08 ,  C08G18/00 ,  B29K75/00 ,  B29L31/50 ,  B29L31/00 ,  B29K105/04 ,  B29K105/00

Abstract: A method for producing bead foams from foam beads based on thermoplastic elastomers, especially thermoplastic polyurethane, comprises foam beads being wetted with a polar liquid and joined together thermally in a mold via high-frequency electromagnetic radiation, especially microwave radiation, and also the bead foams obtainable therefrom.

公开(公告)号：US11053368B2

公开(公告)日：2021-07-06

申请号：US17031241

申请日：2020-09-24

Applicant: BASF SE

Inventor： Frank Prissok ,  Frank Braun

IPC: C08J9/16 ,  C08J9/232 ,  C08J9/18 ,  A43B13/04 ,  A43B13/18 ,  A43B17/14 ,  C08G18/48 ,  C08L75/04 ,  B29B9/06 ,  B29B9/12 ,  B29B9/14 ,  B29B9/16 ,  A43B13/02 ,  C08G18/10 ,  C08G18/76 ,  C08J3/12 ,  C08J9/14 ,  C08G101/00 ,  C08K3/32

Abstract: Expandable thermoplastic polyurethane comprising blowing agent, wherein the Shore hardness of the thermoplastic polyurethane is from A 44 to A 84.

公开(公告)号：US10907006B2

公开(公告)日：2021-02-02

申请号：US16063514

申请日：2016-12-21

Applicant: BASF SE

Inventor： Zeljko Tomovic ,  Frank Prissok ,  Kathrin Cohen

IPC: C08G18/48 ,  C08G18/66 ,  C08G18/76 ,  C08G18/24 ,  C08G18/32 ,  C08G18/40 ,  C08G18/42

Abstract: The present invention relates to a method for producing a molded body (MB) comprising the production of a thermoplastic polyurethane, the production of a molded body (MB*) from the thermoplastic polyurethane, heating the molded body (MB*) to a temperature below the temperature at which there is permanent deformability of the molded body (MB*), and above the switching temperature of the thermoplastic polyurethanes, elongating the heated molded body (MB*) with obtention of a molded body (MB), and cooling the molded body (MB) to a temperature below the switching temperature of the thermoplastic polyurethane, and the molded body obtained or obtainable by such a method. The present invention further relates to a thermoplastic polyurethane with shape memory and the use of a thermoplastic polyurethane for producing a molded body with shape memory effect in a temperature range from 0° C. to 130° C.

公开(公告)号：US10882009B2

公开(公告)日：2021-01-05

申请号：US16069206

申请日：2017-01-16

Applicant: BASF SE

Inventor： Dietrich Scherzer ,  Frank Prissok ,  Lena Arnold ,  Juergen Ahlers ,  Martin Weber

IPC: B01D69/14 ,  B01D69/02 ,  B01D71/26 ,  B01D71/54 ,  C08J5/18 ,  C08K7/22 ,  B01D53/22 ,  C08K5/56 ,  B82Y30/00 ,  C08K5/00

Abstract: The present invention relates to shaped bodies comprising a composition (Z1), wherein said composition comprises at least one polymer having an elongation at break of >30% and at least one porous metal-organic framework material, to processes for producing shaped bodies of this kind and to the use of a composition (Z1) comprising at least one polymer having an elongation at break of >30% and at least one porous metal-organic framework material for production of a film, membrane or laminate having a water vapor permeability according to DIN 53122 at 38° C./90% rel. humidity of greater than 1000 g/(m2*d), based on a film thickness of 10 μm.

公开(公告)号：US10005218B2

公开(公告)日：2018-06-26

申请号：US14391870

申请日：2013-04-12

Applicant: BASF SE

Inventor： Hans Rudolph ,  Rainer Klostermann ,  Torben Kaminsky ,  Bernd Lohaus ,  Jürgen Ahlers ,  Bernhard Schmied ,  Peter Gutmann ,  Klaus Hahn ,  Frank Prissok ,  Elke Marten ,  Christian Däschlein

IPC: B29C47/00 ,  B29B9/06 ,  C08G18/66 ,  C08G18/76 ,  C08J9/12 ,  C08G18/08 ,  B29C44/34 ,  B29B9/12 ,  B29B9/14 ,  B29B9/16 ,  C08J9/14 ,  C08J9/16 ,  C08J9/34 ,  B29K75/00 ,  B29L31/00

Abstract: The invention relates to a process for production of expanded pellets from a polymer melt comprising a blowing agent, said process comprising the steps of: a) pressing the polymer melt comprising a blowing agent through a perforated disk controlled to a temperature between 150° C. and 280° C. and into a pelletizing chamber, b) using a cutting device to comminute the polymer melt pressed through the temperature-controlled perforated disk into individual expanding pellets, c) discharging the pellets from the pelletizing chamber using a liquid stream, wherein the blowing agent comprises CO2 or N2 or a combination of CO2 and N2 and the pelletizing chamber is traversed by a stream of liquid which is controlled to a temperature between 10° C. and 60° C. and the pressure of which is from 0.7 bar to 20 bar above ambient pressure, the pressure and temperature for the liquid in the pelletizing chamber and also the temperature for the perforated disk being chosen such that the pellets are expanded in the pressurized liquid by the blowing agent they contain so as to produce expanded pellets having an uninterrupted skin.

公开(公告)号：US09957347B2

公开(公告)日：2018-05-01

申请号：US14770224

申请日：2014-02-24

Applicant: BASF SE

Inventor： Frank Prissok ,  Henning Wettach

IPC: C08G18/10 ,  C08G18/76 ,  C08G18/73 ,  C08G18/66 ,  C08G18/08 ,  C08G18/12 ,  C09D175/06 ,  C08G18/42 ,  C08G18/32 ,  C08G18/34

CPC classification number: C08G18/73 ,  C08G18/0895 ,  C08G18/10 ,  C08G18/12 ,  C08G18/3206 ,  C08G18/348 ,  C08G18/4238 ,  C08G18/664 ,  C08G18/7671 ,  C08G2350/00 ,  C09D175/06 ,  C08G18/7664

Abstract: The present invention relates to a process for producing a polyurethane, comprising at least the following steps (A) bringing at least one polymer polyol into contact with an amount of from 0.1 to 20 mol %, based on the entire amount of polyisocyanate, of at least one first polyisocyanate, in order to obtain a prepolymer which in essence has terminal hydroxy groups, and (B) bringing the prepolymer from step (A) into contact with at least one second polyisocyanate and optionally with further additives, in order to obtain the polyurethane, to a polyurethane obtainable via said process, and also to the use of this polyurethane as cladding in automobiles, coatings, cables, plug connectors, solar modules, foils, moldings, shoe soles and shoe components, balls and ball components, rollers, fibers, profiles, laminates and wiper blades, hoses, cable plugs, bellows, drag cables, cable sheathing, gaskets, nonwoven fabrics, drive belts, or damping elements.

公开(公告)号：US09920159B2

公开(公告)日：2018-03-20

申请号：US14770224

申请日：2014-02-24

Applicant: BASF SE

Inventor： Frank Prissok ,  Henning Wettach

IPC: C08G18/10 ,  C08G18/76 ,  C08G18/73 ,  C08G18/66 ,  C08G18/08 ,  C08G18/12 ,  C09D175/06 ,  C08G18/42 ,  C08G18/32 ,  C08G18/34

Abstract: The present invention relates to a process for producing a polyurethane, comprising at least the following steps (A) bringing at least one polymer polyol into contact with an amount of from 0.1 to 20 mol %, based on the entire amount of polyisocyanate, of at least one first polyisocyanate, in order to obtain a prepolymer which in essence has terminal hydroxy groups, and (B) bringing the prepolymer from step (A) into contact with at least one second polyisocyanate and optionally with further additives, in order to obtain the polyurethane, to a polyurethane obtainable via said process, and also to the use of this polyurethane as cladding in automobiles, coatings, cables, plug connectors, solar modules, foils, moldings, shoe soles and shoe components, balls and ball components, rollers, fibers, profiles, laminates and wiper blades, hoses, cable plugs, bellows, drag cables, cable sheathing, gaskets, nonwoven fabrics, drive belts, or damping elements.

公开(公告)号：US09815931B2

公开(公告)日：2017-11-14

申请号：US13772971

申请日：2013-02-21

Applicant: BASF SE

Inventor： Frank Prissok ,  Michael Harms

IPC: C08G18/08 ,  C08G18/66 ,  C08G18/76 ,  C08G18/34 ,  C08G101/00

CPC classification number: C08G18/14 ,  C08G18/34 ,  C08G18/6692 ,  C08G18/7664 ,  C08G2101/0008

Abstract: A process for producing a rigid polymer foam comprises reacting components A to C in the presence of component D or an isocyanate-functional prepolymer of components A and B with component C in the presence of component D, the total amount of which is 100 wt %, (A) 35 to 65 wt % of at least one polyisocyanate component A, (B) 5 to 50 wt % of at least one polyol component B, (C) 1 to 59 wt % of at least one polycarboxylic acid component C, and (D) 0.01 to 3 wt % of at least one Lewis base component D, wherein the reaction takes place with release of carbon dioxide.