HIDROXIBENCILTIOETERES SUSTITUIDOS CON S-PERFLUOROALQUILO Y DERIVADOS COMO MODIFICADORES DE SUPERFICIE.

    公开(公告)号:ES2328418T3

    公开(公告)日:2009-11-12

    申请号:ES07729839

    申请日:2007-06-04

    Applicant: BASF SE

    Abstract: Un proceso para reducir la energía de superficie de materiales orgánicos que comprende tratar el material orgánico con por lo menos un compuesto de la Fórmula I **(Ver fórmula)** en donde, cuando n es 1, R1 es hidrógeno, alquiloC1-C25, alqueniloC2-C25, -CO-R5, -CH-(R10)-CO-R5, -C-(R10)2CO-R5, -CO-N-(R6)-R7, -CH-(R10) CO-N-(R6)-R7, -C-(R10)2CO-N-(R6)-R7, -CH-(R10)-COOR5 o -C-(R10)2CO-OR5; cuando n es 2, R1 no se sustituye o con alquiloC1-C4 bencilo o fenilo sustituido con alquilenoC1-C24; con oxígeno o azufre interrumpido alquilenoC2-C24; -CO-R8-CO-, -CH-(R10)-CO-R8-CO-CH-(R10)-, -C-(R10)2CO-R8-CO-C-(R10)2-, -CO-N- (R6)-R9-N-(R6)-CO-, -CH-(R10)-CO-N-(R6)-R9-N-(R6)-CO-CH-(R10)-, -C-(R10)2CO-N-(R6)-R9-N-(R6)-CO-C-(R10)2-, -CH-(R10)-CO-O-R9-O-CO-CH-(R10)-o-C-(R10)2CO-O-R9-O-CO-C-(R10)2-; cuando n es 3, R1 es **(Ver fórmula)** R2, R3 y R4 independientemente uno del otro son hidrógeno, alquiloC1-C25, alqueniloC2-C25, -CH-(R11)-S-(O)p- R12, **(Ver fórmula)** con la condición que por lo menos uno de los radicales R2, R3 o R4 es -CH-(R11)-S-(O)p-R12; R5 es alquiloC1-C25, alqueniloC2-C25, no sustituido o con alquiloC1-C4 o halógeno sustituido con fenilo; o FenilalquiloC7-C12, R6 es hidrógeno o alquiloC1-C4 R7 es hidrógeno, alquiloC1-C25, no sustituido o con alquiloC1-C4 o halógeno sustituido con fenilo; R8 es fenileno, no sustituido o con alquiloC1-C4 bencilo o fenilo sustituido con alquilenoC1-C24; con oxígeno o azufre interrumpido por alquilenoC2-C24; R9 es un enlace directo; no sustituido o con alquiloC1-C4 bencilo o fenilo sustituido con alquilenoC2-C24; o con oxígeno o azufre interrumpido con alquilenoC2-C24; R10 es hidrógeno o alquiloC1-C8, R11 es hidrógeno, alquiloC1-C8, no sustituido o con alquiloC1-C4 sustituido con fenilo; R12 es un radical orgánico lineal o ramificado, alquilo o alquenilo perfluorinado monovalente que tiene de cuatro a veinte átomos de carbono completamente fluorinados, R13 es hidrógeno, alquiloC1-C25, alqueniloC2-C25, -CO-R5, -CO-N-(R6)-R7 o -CH2-CO-N-(R6)-R7, R14 es hidrógeno, alquiloC1-C25, alqueniloC2-C25 o -CH-(R11)-S-(O)p-R12, R15 es hidrógeno, alquiloC1-C25, alqueniloC2-C25 o -CH-(R11)-S-(O)p-R12, R16 es no sustituido o con alquiloC1-C4 sustituido con metileno, -S-, -S-(O)-, -S-(O)2-o-CO-; R17 es alquiloC1-C4 n es 1, 2 o 3, y p es 0, 1 o 2.

    22.
    发明专利
    未知

    公开(公告)号:AT439403T

    公开(公告)日:2009-08-15

    申请号:AT07729839

    申请日:2007-06-04

    Applicant: BASF SE

    Abstract: The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.

    ADDITIVE MIXTURE
    24.
    发明专利

    公开(公告)号:CA2828503A1

    公开(公告)日:2012-09-20

    申请号:CA2828503

    申请日:2012-03-19

    Applicant: BASF SE

    Abstract: An additive mixture containing (A) a binary system consisting of components (A1 ) and (A2), wherein (A1) is at least one organic cyclic phosphoric acid ester of the formula (I) wherein R0 is a direct bond, -S-, C3-C12cycloalkylidene or a group -C(X1)(X2)- with X1 and X2 independently of one another being hydrogen, C1-C18alkyl or C3-C12cycloalkyl; and the radicals R1 are identical and are C1-C18alkyl or C3-C12cycloalkyl unsubstituted or substituted by one, two or three C1-C4alkyl; and (A2) is at least one alkali or alkaline earth metal salt of a saturated or unsaturated aliphatic mono or dicarboxylic acid unsubstituted or substituted by -OH; and (B) a divalent metal alcoholate wherein the metal is Zn, Ca or Mg.

    26.
    发明专利
    未知

    公开(公告)号:AT522569T

    公开(公告)日:2011-09-15

    申请号:AT09705627

    申请日:2009-01-19

    Applicant: BASF SE

    Abstract: The invention describes a process for reducing the amount of saturated or unsaturated monomers and oligomers during production and processing of styrenic polymers comprising a mixture of at least two components selected from the group consisting of a) phenol thioethers, b) phenol acrylates, c) 3-arylbenzofuran-2-ones and d) 1,1-di-substituted ethylenes or tri-substituted ethylenes.

    27.
    发明专利
    未知

    公开(公告)号:AT495145T

    公开(公告)日:2011-01-15

    申请号:AT06707887

    申请日:2006-01-30

    Applicant: BASF SE

    Abstract: The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one melt additive of a compound of the formula I R1(I)R3XR2 wherein the general symbols are as defined in claim 1. The compounds of the formula I are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.

    28.
    发明专利
    未知

    公开(公告)号:AT443104T

    公开(公告)日:2009-10-15

    申请号:AT04804681

    申请日:2004-12-06

    Applicant: BASF SE

    Abstract: The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula (I).

    29.
    发明专利
    未知

    公开(公告)号:DE602007001975D1

    公开(公告)日:2009-09-24

    申请号:DE602007001975

    申请日:2007-06-04

    Applicant: BASF SE

    Abstract: The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R2, R3 or R4 is —CH(R11)—S(O)p—R12; R11 is hydrogen, C1-C8alkyl, unsubstituted or with C1-C4alkyl substituted phenyl; R12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.

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