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公开(公告)号:US20250041828A1
公开(公告)日:2025-02-06
申请号:US18694478
申请日:2022-09-16
Applicant: BASF SE
Inventor: Thomas Daniel , Sebastian Marius Raupp , Monte Alan Peterson , Vernon Lynn Adey , Karl Possemiers
Abstract: A process for producing surface postcrosslinked superabsorbent particles, wherein an aqueous monomer solution with a small amount of initiator is polymerized to give a polymer gel, the resultant polymer gel is extruded through a die plate, the extruded polymer gel is dried on an air circulation belt drier having one or more zones, and the resultant polymer particles are ground and classified and then thermally surface postcrosslinked, wherein the temperatures of the drying gas supplied in the course of drying in the forward zones of the air circulation belt drier are from 120 to 160° C., and the speeds of the air supplied are from 1.2 to 3.0 m/s.
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公开(公告)号:US12042365B2
公开(公告)日:2024-07-23
申请号:US16482045
申请日:2018-02-12
Applicant: BASF SE
Inventor: Thomas Daniel , Christophe Bauduin , Katrin Baumann , Katarzyna Dobrosielska-Oura
IPC: A61F13/15 , A61F13/537 , A61L15/60 , A61F13/53
CPC classification number: A61F13/537 , A61L15/60 , A61F2013/530708
Abstract: A fluid-absorbent article includes an upper liquid-pervious layer (A), a lower liquid-impervious layer (B), a fluid-absorbent core (C) between (A) and (B) including at least 60% by weight of non-surface postcrosslinked fluid-absorbent polymer particles and not more than 40% by weight of fibrous material, based on the sum of non-surface postcrosslinked fluid-absorbent polymer particles and fibrous material. An acquisition-distribution layer (D) between (A) and (C) includes at least 90% by weight of synthetic fibers and not more than 10% by weight of cellulose based fibers, based on the sum of synthetic fibers and cellulose based fibers. The basis weight of the acquisition-distribution layer (D) is at least 70 gsm. The fluid-absorbent polymer particles have a saline flow conductivity (SFC) of less than 5×10−7 cm3s/g and an AUHL of less than 15 g/g. Preferably the acquisition-distribution layer (D) is a non-woven web including a three dimensional network of fibers.
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公开(公告)号:US20210354108A1
公开(公告)日:2021-11-18
申请号:US17282012
申请日:2019-10-23
Applicant: BASF SE
Inventor: Katrin Baumann , Stephan Bauer , Thomas Daniel , Norbert Herfert , Christophe Bauduin
IPC: B01J20/26 , C08F220/06 , C08J3/24 , B01J20/28 , B01J20/30
Abstract: The invention relates to a process for producing long-term color stable superabsorbent polymer particles, comprising polymerization of a monomer solution, drying the resulting polymer gel, optionally grinding and classifying the resulting dried polymer gel and thermally surface post-crosslinking and cooling the resulting polymer particles, wherein a thermal surface post-cross-linker and hydrogen peroxide are added to the polymer particles prior to the thermal surface post-crosslinking.
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公开(公告)号:US20210121852A1
公开(公告)日:2021-04-29
申请号:US17046033
申请日:2019-04-09
Applicant: BASF SE
Inventor: Norbert Herfert , Bootsara Parchana , Sunantha Kaenthong , Stephan Bauer , Thomas Daniel , Katrin Baumann
IPC: B01J20/26 , C08F220/06 , B01J20/28 , B01J20/30
Abstract: The invention relates to a process for producing long-term color stable superabsorbent polymer particles, comprising polymerization of a monomer solution, wherein the monomer solution comprises at least 0.01% by weight of 1-hydroxyethane-1,1-diphosphonic acid or a salt thereof and at least 0.01% by weight of 2-hydroxy-2-sulfonatoacetic acid or a salt thereof.
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公开(公告)号:US20210016247A1
公开(公告)日:2021-01-21
申请号:US17043764
申请日:2019-04-01
Applicant: BASF SE
Inventor: Christophe Bauduin , Thomas Daniel
Abstract: A highly permeable superabsorbent is prepared by a process comprising
polymerizing an aqueous monomer solution comprising a) at least one ethylenically unsaturated monomer which bears acid groups and is optionally at least partly in salt form, b) at least one crosslinker, c) at least one initiator, d) optionally one or more ethylenically unsaturated monomers copolymerizable with the monomers mentioned under a), and e) optionally one or more water-soluble polymers; drying the resulting polymer, optionally grinding the dried polymer and sieving the ground polymer, optionally surface postcrosslinking the dried and optionally ground and sieved polymer, wherein, after drying, grinding or sieving, and, if surface postcrosslinking is conducted, during or after this surface postcrosslinking, x-ray-amorphous aluminum hydroxide powder is added.-
公开(公告)号:US10806640B2
公开(公告)日:2020-10-20
申请号:US15471281
申请日:2017-03-28
Applicant: BASF SE
Inventor: Norbert Herfert , Somjate Sonkaew , Thomas Daniel , Tanyatorn Sitkhunthod
Abstract: An absorbent core and an absorbent article respectively with improved properties, especially rewet performance, are disclosed. The absorbent core has at least two layers, wherein each layer comprising from 0 to 10% by weight fibrous material and from 90 to 100% by weight water-absorbent polymer particles, based on the sum of water-absorbent polymer particles and fibrous material. The surface-postcrosslinked water absorbent polymer particles within the upper layer have a sphericity of at least 0.89 and a CRC of at least 34 g/g. Preferably the water-absorbent polymer particles have a sphericity of at least 0.89 and the sum of the CRC and AUL (0.3 psi, 21 g cm−2) (EDANA 442.2-02) of the water absorbent polymer particles is at least 65 g/g.
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公开(公告)号:US10208170B2
公开(公告)日:2019-02-19
申请号:US14443082
申请日:2013-11-07
Applicant: BASF SE
Inventor: Thomas Daniel , Norbert Herfert , Stephan Bauer , Katrin Baumann , Birgit Reinhard , Jürgen Freiberg , Christophe Bauduin , Katarzyna Dobrosielska-Oura , Michael A. Mitchell
IPC: C08J3/24 , A61L15/22 , A61L15/42 , B01J20/26 , B01J20/28 , C08F220/06 , C08J9/00 , A61L15/60 , C08F222/10
Abstract: The present invention relates to a process for producing surface-postcrosslinked water-absorbent polymer particles by coating of water-absorbent polymer particles having a content of residual monomers in the range from 0.03 to 15% by weight with at least one surface-postcrosslinker and thermal surface-postcrosslinking at temperatures in the range from 100 to 180° C.
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公开(公告)号:US09840598B2
公开(公告)日:2017-12-12
申请号:US14407490
申请日:2013-06-21
Applicant: BASF SE
Inventor: Christophe Bauduin , Thomas Daniel , Asif Karim
CPC classification number: C08J3/245 , A61L15/22 , A61L15/24 , A61L15/42 , A61L15/60 , C08F6/008 , C08J2333/02
Abstract: The present invention relates to a process for producing water-absorbing polymer particles having an improved profile of properties, comprising thermal surface postcrosslinking in the presence of a salt of a polyvalent metal cation and a complexing anion and subsequent aftertreatment, the aftertreatment comprising coating with a salt of a polyvalent metal cation and a non-complexing anion, and remoisturization with further drying.
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公开(公告)号:US20170312148A1
公开(公告)日:2017-11-02
申请号:US15520092
申请日:2015-10-14
Applicant: BASF SE
Inventor: Katarzyna Dobrosielska-Oura , Christophe Bauduin , Markus Tönnessen , Mark Elliott , Markus Vogt , Thomas Daniel , Norbert Herfert , Marc Haefner , Alexandra Faubel
IPC: A61F13/537 , A61L15/60 , A61L15/22 , A61F13/539 , A61F13/15 , A61F13/534 , A61F13/53
CPC classification number: A61F13/53717 , A61F13/15203 , A61F13/53 , A61F13/539 , A61F2013/15406 , A61F2013/530591 , A61F2013/5349 , A61F2013/5395 , A61L15/225 , A61L15/60
Abstract: The present invention relates to a fluid-absorbent article, comprising a fluid-absorbent core, comprising from 0 to 90% by weight fibrous material and from 10 to 100% by weight water-absorbent polymer particles having a mean sphericity (SPHT) from 0.8 to 0.95, based on the sum of water-absorbent polymer particles and fibrous material;and an acquisition-distribution layer between having a three dimensional apertured structure having a femal side (5) and a male side (6), wherein the femal side presents a multiplicity of openings extending in the form of through holes in the direction of a lower surface of the same structure being the male side, wherein the quantity of the water absorbent polymer particles within the fluid absorbent core is at least 3 g.
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公开(公告)号:US09532906B2
公开(公告)日:2017-01-03
申请号:US14353342
申请日:2012-10-24
Applicant: BOSTIK INC. , BASF SE
Inventor: Christophe Bauduin , Jean-Francois Chartrel , Thomas Daniel , Julien Liger , Renate Wuestefeld
IPC: A61F13/15 , A61F13/539 , A61F13/53 , A61F13/538 , A61F13/532
CPC classification number: A61F13/15699 , A61F13/15658 , A61F13/15707 , A61F13/15747 , A61F13/532 , A61F13/5323 , A61F13/538 , A61F13/539 , A61F2013/530481 , A61F2013/530547 , A61F2013/530562 , A61F2013/53908 , A61F2013/53925 , A61F2013/53933 , A61F2013/5395 , A61F2013/53958 , Y10T156/10 , Y10T156/1049
Abstract: The present invention is directed to a liquid-absorbing article comprising: a first sheet layer presenting an array of absorbent receiving pockets; masses of superabsorbent material, which masses are placed in said absorbent receiving pockets; a second sheet layer placed on top of the first layer; bonding beads placed between the respective pockets.
Abstract translation: 本发明涉及一种制备吸收制品的新方法,其中该方法包括提供第一片层(2); 在第一辊C2上使所述第一层适配,由此在所述层上形成纵向波纹; 使所述波纹层(2)适合于第二辊子C3,从而得到凹穴图案(4,4a); 将预先计量的SAP颗粒材料(6)提供到所述袋中; 提供第二片层(7)材料并将其固定以与所述第一片层夹持; 并整理吸收制品。
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