公开(公告)号：EP2621964B1

公开(公告)日：2017-05-17

申请号：EP11763925.2

申请日：2011-09-29

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COLLINA, Gianni ,  EVANGELISTI, Daniele ,  GADDI, Benedetta ,  FAIT, Anna

IPC: C08F10/06 ,  C01F5/30 ,  C08F4/634 ,  C08F4/654 ,  C08F4/631 ,  C08F4/651 ,  C08F4/628 ,  C08F4/648

CPC classification number: C08F4/10 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F2500/24 ,  C08F4/6548 ,  C08F4/651 ,  C08F4/6543 ,  C08F4/6574

公开(公告)号：EP1948703B1

公开(公告)日：2009-04-29

申请号：EP06819401.8

申请日：2006-11-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： BACCI, Dino ,  FAIT, Anna ,  MORINI, Giampiero ,  PELLEGATTI, Giampaolo ,  PIEMONTESI, Fabrizio

IPC: C08F210/02

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/11 ,  C08F2500/20

Abstract: Propylene-ethylene copolymers are flexible and show a very good balance between softness and mechanical properties in their crude state are obtained by solution polymerization in the presence of Ziegler-Natta catalysts. The said copolymers comprise from 10 to 50%wt of ethylene and are characterized by: product of the comonomer reactivity ratio r1 r2 =1.5; absence of 2,1 propylene insertions and tensile strength at break higher than 4 Mpa.

公开(公告)号：EP2331584B1

公开(公告)日：2012-11-21

申请号：EP09783122.6

申请日：2009-09-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COLLINA, Gianni ,  FAIT, Anna ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  PEDRIALI, Lorella ,  SPOTO, Rosa ,  VINCENZI, Paolo

IPC: C08F4/651 ,  C08F4/649 ,  C08F10/00

CPC classification number: C08F10/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/2208 ,  B01J31/26 ,  B01J31/38 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/34 ,  C08F210/06 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/17

公开(公告)号：EP2516481A1

公开(公告)日：2012-10-31

申请号：EP10794988.5

申请日：2010-12-17

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： BRITA, Diego ,  COLLINA, Gianni ,  EVANGELISTI, Daniele ,  FAIT, Anna ,  GADDI, Benedetta ,  MORINI, Giampiero ,  BAITA, Pietro ,  MARTURANO, Lorella ,  MAVRIDIS, Harry

IPC: C08F4/654 ,  C08F4/649 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F110/02 ,  C08F2410/03 ,  C08F4/6543 ,  C08F4/6545 ,  C08F4/6494 ,  C08F2/001 ,  C08F2500/07 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/14 ,  C08F2500/18 ,  C08F2500/11

Abstract: Catalyst component comprising Mg, Ti, and halogen atoms, and is characterized in that (a) the Ti atoms are present in an amount higher than 4% based on the total weight of the said catalyst component, (b) the amount of Mg and Ti atoms is such that the Mg/Ti molar ratio is higher than 2 and (c) by a X-ray diffraction spectrum, in which, in the range of 2θ diffraction angles between 47° and 52°, at least two diffraction lines are present at diffraction angles 2θ of 48.3 ± 0.2°, and 50.0 ± 0.2°, the most intense diffraction lines being the one at 2θ of 50.0 ± 0.2°, the intensity of the other diffraction line being equal to or lower than the intensity of the most intense diffraction line.

公开(公告)号：EP2331584A1

公开(公告)日：2011-06-15

申请号：EP09783122.6

申请日：2009-09-17

Applicant: Basell Poliolefine Italia S.R.L.

Inventor： COLLINA, Gianni ,  FAIT, Anna ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  PEDRIALI, Lorella ,  SPOTO, Rosa ,  VINCENZI, Paolo

IPC: C08F4/651 ,  C08F4/649 ,  C08F10/00

CPC classification number: C08F10/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/2208 ,  B01J31/26 ,  B01J31/38 ,  C08F10/06 ,  C08F210/16 ,  C08F4/6492 ,  C08F4/651 ,  C08F2/34 ,  C08F210/06 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/17

Abstract: Prepolymerized catalyst component for the polymerization of olefins CH
2 =CHR, wherein R is hydrogen or a C
1 -C
12 hydrocarbyl group, comprising a solid catalyst component characterized by comprising Mg, Ti halogen and an electron donor (ID) selected from the alkyl esters of aromatic dicarboxylic acids in such an amount that the molar ratio ID/Mg ranges from 0.025 to 0.07 and the Mg/Ti molar ratio is higher than 13, said prepolymerized catalyst component containing an amount of ethylene pre-polymer up to 5Og per g of said solid catalyst component.

公开(公告)号：EP2225290A1

公开(公告)日：2010-09-08

申请号：EP08864802.7

申请日：2008-12-18

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： ARICH DE FINETTI, Nicolò ,  BIGIAVI, Daniele ,  FAIT, Anna

IPC: C08F6/10 ,  C08F10/00

CPC classification number: C08F6/003 ,  B01J19/1862 ,  B01J2219/00092 ,  B01J2219/00103 ,  C08F4/65912 ,  C08F4/65927 ,  C08F10/00 ,  Y10S526/943 ,  C08L23/00 ,  C08F2/06

Abstract: A solution process for polymerizingone or more α-olefins of formula CH2=CHR, where R is H or an alkyl radical C1-12,to produce a polyolefin soluble in the reaction medium, the process comprising: a) polymerizing said one or more α-olefins in a solution phase in the presence of a polymerization catalyst and a inert solvent having a vapor pressure lower than 100 kPa at 20°C; b) separating the produced polyolefin from the unreacted monomers and the inert solvent by means of a sequence of at least three volatilization chambers operating at a decreasing pressure, the second devolatilization chamber being operated at a pressure from 0.8 to 5 bar.

Abstract translation: 一种聚合一种或多种式CH 2 = CHR（其中R为H或烷基C1-12）的α-烯烃以制备可溶于反应介质中的聚烯烃的溶液方法，所述方法包括：a）使所述一种或多种α 在20℃下在聚合催化剂和蒸气压低于100kPa的惰性溶剂存在下在溶液相中进行聚合; b）通过一系列在减压下操作的至少三个挥发室将所生产的聚烯烃与未反应的单体和惰性溶剂分离，第二脱挥发室在0.8-5巴的压力下操作。

公开(公告)号：EP1343583B1

公开(公告)日：2010-01-27

申请号：EP01994766.2

申请日：2001-12-04

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： ARLETTI, Arrigo ,  FAIT, Anna

IPC: B01J27/138 ,  C01F5/30 ,  C08F10/00 ,  C08F4/02 ,  B01J37/00 ,  B01J35/08

CPC classification number: C08F10/00 ,  B01J27/138 ,  B01J35/08 ,  B01J37/0072 ,  C08F110/06 ,  C08F4/6545 ,  C08F4/022 ,  C08F2500/18 ,  C08F2500/24

公开(公告)号：EP1948703A1

公开(公告)日：2008-07-30

申请号：EP06819401.8

申请日：2006-11-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： BACCI, Dino ,  FAIT, Anna ,  MORINI, Giampiero ,  PELLEGATTI, Giampaolo ,  PIEMONTESI, Fabrizio

IPC: C08F210/02

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/15 ,  C08F2500/11 ,  C08F2500/20

Abstract: Propylene-ethylene copolymers are flexible and show a very good balance between softness and mechanical properties in their crude state are obtained by solution polymerization in the presence of Ziegler-Natta catalysts. The said copolymers comprise from 10 to 50%wt of ethylene and are characterized by: product of the comonomer reactivity ratio r1•r2 ≤1.5; absence of 2,1 propylene insertions and tensile strength at break higher than 4 Mpa.

Abstract translation: 丙烯 - 乙烯共聚物是柔性的，并且在Ziegler-Natta催化剂存在下通过溶液聚合获得它们的粗状态下的柔软度和机械性能之间的非常好的平衡。 所述共聚物包含10至50重量％的乙烯并且特征在于：共聚单体反应性比率r1·r2≤1.5的产物; 不存在2,1丙烯插入并且断裂拉伸强度高于4Mpa。

公开(公告)号：EP1353962B1

公开(公告)日：2008-05-21

申请号：EP01270558.8

申请日：2001-12-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： COVEZZI, Massimo ,  FAIT, Anna ,  DI BENEDETTO, Almerinda

IPC: C08F4/654 ,  C08F10/00

CPC classification number: C08F10/00 ,  C08F110/06 ,  C08F4/6543 ,  C08F2500/15 ,  C08F2500/18

Abstract: A process is provided for the preparation of a solid catalyst component for the polymerisation of olefins, comprising continuously feeding a liquid containing a titanium compound having at least one titanium-halogen bond into a vessel containing a solid comprising a magnesium halide and continuously discharging liquid from the vessel, whereby the concentration of the solid is maintained within the range of between 80 and 300 g/l, and the product between the average residence time of the liquid in the vessel and the concentration of the solid is maintained below 10,000 min*g/l. An advantage of the process is the reduced time and reactor volume necessary to prepare the catalysts, which show good activity and stereospecificity.