公开(公告)号：EP3071627B1

公开(公告)日：2018-01-31

申请号：EP14815135.0

申请日：2014-11-18

Applicant: Dow Global Technologies LLC

Inventor： DAVIS, Anna V. ,  NICKIAS, Peter N.

IPC: C08G65/10 ,  C08G65/12 ,  C08G65/26

CPC classification number: C08G65/12 ,  B01J2531/11 ,  C08G65/10 ,  C08G65/266 ,  C08G65/269

Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) first row transition metals excluding Zn, preferably Sc, Ti, V, Cr, Mn, Ni, and Co, more preferably Ti, (II) second row transition metals, preferably Y and Zr, more preferably Zr, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

公开(公告)号：EP3071628A1

公开(公告)日：2016-09-28

申请号：EP14820966.1

申请日：2014-11-18

Applicant: Dow Global Technologies LLC

Inventor： DAVIS, Anna V. ,  NICKIAS, Peter N.

IPC: C08G65/26 ,  B01J31/02 ,  C08G65/10 ,  C08G65/12

CPC classification number: C08G65/269 ,  B01J31/0212 ,  C08G65/10 ,  C08G65/12 ,  C08G65/2654 ,  C08G65/266

Abstract: The present invention concerns a catalyst formulation comprising: (a) a Zn catalyst comprising a Zn compound having alcoholate ligand(s) derived from one or more polyols, and (b) a catalyst additive comprising a metal compound (i) having alcoholate ligand(s) derived from one or monohydric alcohol wherein the metal is selected from: (I) group 13 metals, preferably B, Al, Ga, and In, more preferably Al, (II) combinations of Al with group 14 metals or semi-metals, preferably a combination of Al and Si, and (III) combinations of at least two metals selected from (I) and (II). The present invention also relates to a process for polymerizing an epoxide monomer, preferably ethylene oxide, comprising carrying out the process in the presence of the catalyst formulation.

Abstract translation: 本发明涉及催化剂制剂，其包含：（a）包含具有衍生自一种或多种多元醇的醇化物配体的Zn化合物的Zn催化剂，和（b）包含金属化合物（i）的催化剂添加剂，所述金属化合物具有醇化物配体 （I）第13族金属，优选B，Al，Ga和In，更优选Al，（II）Al与第14族金属或半金属的组合，其中所述金属选自 ，优选Al和Si的组合，和（III）选自（I）和（II）的至少两种金属的组合。 本发明还涉及一种聚合环氧化物单体，优选环氧乙烷的方法，包括在催化剂制剂存在下进行该方法。