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公开(公告)号:CA2031786A1
公开(公告)日:1991-06-10
申请号:CA2031786
申请日:1990-12-07
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B32B9/00 , C07D213/30 , C07D213/38 , C07D213/77 , G02F1/361 , B05D5/06 , H01S3/108 , B05D5/12 , G02F1/35
Abstract: HOE 89/F 390 Layer element and a process for its preparation A layer element usable for NLO purposes can be prepared by the Langmuir-Blodgett technique. It comprises a solid substrate and at least two thin layers of regular structure applied thereupon, which layers contain at least one amphiphilic compound of the formula (I) Z- (I) in which R1 is H(CH2)nO, H(CH2)nS or , R2 and R3, independently of one another, are H, H(CH2)pO-, H(CH2)pS- or , X is a single bond, -CH=CH-, -N=N-, -CH=N-NH-, or -CH=N, Y is a divalent radical O, NH or S, R4 is -H, -CO-(CH2)tH, -(CH2)t-H or YR4 is -COO-, -CONH2, H, OH, SO2(CH2)uH, -COz(CH2)tH or -CO2(CH2)vOH, Z is at least in part a polyanion, 1 is a number from 1-10, n is a number from 10-25, m is a number from 0-25, p is a number from 10-25, q is a number from 10-25, r is a number from 0-25, t is a number from 0-25, u is a number from 1-20, and v is a number from 2-10.
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公开(公告)号:DK655589D0
公开(公告)日:1989-12-21
申请号:DK655589
申请日:1989-12-21
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B32B27/30 , C07C233/05 , C07C233/80 , C08F20/34 , C08F20/36 , C08F20/52 , C08F20/60 , C08J5/18 , C07C235/74 , B32B27/06
Abstract: Amphiphilic monomers with mixed-chain structures of the formula in which Y denotes -O- or -NH- X denotes a group of the formula -(CH2)n- or -(CH2-O-CH2)n- l denotes an integer from 0 to 10, n denotes an integer from 1 to 10, R1 denotes hydrogen, methyl, chlorine, cyano, fluorine or bromine, R2 denotes C1-C24-alkyl or C1-C24-fluoroalkyl and R3 denotes C8-C24-alkyl or C8-C24-fluoralkyl, with the proviso that the groups R2 and R3 contain a different number of carbon atoms. The monomers are polymerized on their own or together with other comonomers. The polymers obtained are suitable for the preparation of ultra-thin layers on a suitable layer support.
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公开(公告)号:FI894182A0
公开(公告)日:1989-09-05
申请号:FI894182
申请日:1989-09-05
Applicant: HOECHST AG
Inventor: CHERDRON HARALD , PRASS WERNER , SCHEUNEMANN UDE , LUPO DONALD
Abstract: Polyamides of the general formula [N(A)-X-N(B)-CO-Y-CO-]n are described, in which Y denotes a divalent group, X a divalent radical whose chain contains at least two carbon atoms, A and B independently of one another denote H or a C1 to C26 alkyl group and n denotes an integer greater than 4. The said polyamides contain at least one alkyl group of C6 to C26 per repeating unit. The groups X and/or Y contain at leat one CH2 group in the chain. The polyamides are prepared by reaction of a diamine of the formula NHA-X-NHB with an about equimolar amount of a reactive derivative of a dicarboxylic acid of the formula COOH-Y-COOH. The polyamides obtained can be used in order to prepare highly ordered monomolecular LB films on a support. For this purpose, the polyamide is dissolved in a volatile organic solvent which is immiscible with water and the solution is spread on the water/air interface. After evaporation of the solvent the layer is compressed and transferred to a solid support by the LB technique. The film is very stable and can be used to prepare optical waveguide systems, filters for optical purposes or protective layers.
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公开(公告)号:DE69409009T2
公开(公告)日:1998-10-01
申请号:DE69409009
申请日:1994-05-31
Applicant: HOECHST AG
Inventor: ROTH CHRISTOPH , LIU YUAN , PRASS WERNER , YAMAMOTO TETSU , MOTOSUGI KENJI
Abstract: PCT No. PCT/EP94/01768 Sec. 371 Date Nov. 7, 1995 Sec. 102(e) Date Nov. 7, 1995 PCT Filed May 31, 1994 PCT Pub. No. WO94/28395 PCT Pub. Date Dec. 8, 1994Disclosed and claimed is an optical sensor for the detection of chemical species. The optical sensor includes an optical waveguide having a guiding thin film. The thickness of the refrative index of the guiding thin film changes due to adsorption or absorption of the chemical species or reaction of the chemical species with the guiding thin film. The thickness of the guiding thin film is above the cutoff thickness in the presence of gaseous or liquid chemical species to be detected. And, the thickness of the guiding thin film is below the cutoff thickness in the absence of such chemical species.
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公开(公告)号:AT167848T
公开(公告)日:1998-07-15
申请号:AT95935441
申请日:1995-10-10
Applicant: HOECHST AG
Inventor: GEISS GERHARD , MUELLER HANS-KARL , PRASS WERNER , SCHEUNEMANN UDE , ZIMMERMANN ANDREAS
IPC: C08J3/12 , C01B33/14 , C01B33/145 , C01B33/16 , C04B14/06 , C04B20/00 , C04B30/02 , C04B38/08 , C08J3/20 , C08K3/36 , C08L101/00 , C09J1/00 , C09J11/04
Abstract: PCT No. PCT/EP95/03989 Sec. 371 Date Apr. 17, 1997 Sec. 102(e) Date Apr. 17, 1997 PCT Filed Oct. 10, 1995 PCT Pub. No. WO96/12683 PCT Pub. Date May 2, 1996The invention relates to a composition comprising between 30 and 95% by volume of aerogel particles and at least one aqueous binder, where the particle diameter of the aerogel particles is less than 0.5 mm and the aerogel particles preferably have hydrophobic surface groups, a process for the preparation thereof, and the use thereof.
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公开(公告)号:DE69409009D1
公开(公告)日:1998-04-16
申请号:DE69409009
申请日:1994-05-31
Applicant: HOECHST AG
Inventor: ROTH CHRISTOPH , LIU YUAN , PRASS WERNER , YAMAMOTO TETSU , MOTOSUGI KENJI
Abstract: PCT No. PCT/EP94/01768 Sec. 371 Date Nov. 7, 1995 Sec. 102(e) Date Nov. 7, 1995 PCT Filed May 31, 1994 PCT Pub. No. WO94/28395 PCT Pub. Date Dec. 8, 1994Disclosed and claimed is an optical sensor for the detection of chemical species. The optical sensor includes an optical waveguide having a guiding thin film. The thickness of the refrative index of the guiding thin film changes due to adsorption or absorption of the chemical species or reaction of the chemical species with the guiding thin film. The thickness of the guiding thin film is above the cutoff thickness in the presence of gaseous or liquid chemical species to be detected. And, the thickness of the guiding thin film is below the cutoff thickness in the absence of such chemical species.
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公开(公告)号:GR3015739T3
公开(公告)日:1995-07-31
申请号:GR950400878
申请日:1995-04-10
Applicant: HOECHST AG
Inventor: HAUBS MICHAEL , PRASS WERNER
Abstract: PCT No. PCT/EP90/02021 Sec. 371 Date Jul. 2, 1992 Sec. 102(e) Date Jul. 2, 1992 PCT Filed Nov. 26, 1990 PCT Pub. No. WO91/09669 PCT Pub. Date Jul. 11, 1991.Composite membrane, process for its production and its use A composite membrane for gas separation having a three-layer structure, constructed from A) a supporting membrane layer made of porous polymer, B) a nonporous, gas-permeable intermediate layer, C) a permselective layer of regularly arranged organic molecules having a layer thickness of 3 to 100 nm, the layers (A) and (C) enclosing the intermediate layer (B), wherein the permselective layer (C) is constructed from regularly arranged amphiphilic molecules which contain one or two alkyl chains each having 7 to 25 carbon atoms per polar hydrophilic group.
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公开(公告)号:DE59008861D1
公开(公告)日:1995-05-11
申请号:DE59008861
申请日:1990-01-12
Applicant: HOECHST AG
Inventor: ERDELEN CHRISTIAN , RINGSDORF HELMUT , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B05D3/06 , C08F12/00 , C08F16/02 , C08F16/16 , C08F20/32 , C08F20/52 , C08F212/08 , C08F216/04 , C08F216/16 , C08F220/32 , C08F220/58 , C08J5/18 , C08J7/00 , C08L33/16 , G03F7/038 , G03F7/095
Abstract: PCT No. PCT/EP90/00069 Sec. 371 Date Sep. 13, 1991 Sec. 102(e) Date Sep. 13, 1991 PCT Filed Jan. 12, 1990 PCT Pub. No. WO90/08346 PCT Pub. Date Jul. 26, 1990.Radiation-sensitive film composed of at least one monomolecular layer of fluorine-containing amphiphiles. If a vinyl monomer containing fluoroalkyl side groups is copolymerized with a vinyl monomer containing oxirane groups, an amphiphilic polymer is obtained. To prepare a sandwich, a polymer is dissolved in a volatile organic solvent which is immiscible with water, the solution is spread on the water/air boundary surface, the resultant layer is compressed after the solvent has evaporated and transferred to a solid layer support by the Langmuir-Blodgett technique. The oxirane rings are cleaved and the film crosslinked by the action of high-energy radiation on the film.
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公开(公告)号:CA2104316A1
公开(公告)日:1994-02-20
申请号:CA2104316
申请日:1993-08-18
Applicant: HOECHST AG
Inventor: APPEL GUNTHER , BAUER JACQUELINE , HICKEL WERNER , LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
Abstract: of the disclosure: "Process and device for producing ultrathin layers and layer elements" In order to continuously produce an ultrathin, ordered layer of amphiphilic molecules on the surface of a polar liquid a directed flow of the polar liquid is produced in a duct which contains the amphiphilic molecules in dissolved or undissolved form on the surface in spread form. In the duct, a duct section having a relatively high flow rate on the surface and comprising a ramp which is arranged at the bottom of the duct and washed over by the polar liquid is provided. This is followed by a duct section having a relatively low flow rate on the surface, in which the flow is dammed up at an obstacle at a liquid level constant with time, so that an ultrathin, ordered layer of amphiphilic molecules is continuously formed in these duct sections at the polar liquid/air interface by compression of the flow. The washed over ramp is movable.
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公开(公告)号:FI921076A0
公开(公告)日:1992-03-12
申请号:FI921076
申请日:1992-03-12
Applicant: HOECHST AG
Inventor: HICKEL WERNER , LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE , WILHARM PETER
IPC: B05D1/20 , C08F20/52 , C08F30/08 , C08F220/10 , C08F220/52 , C08F230/08 , C08F
Abstract: Amphiphilic copolymers containing silanyl groups and composed of derivatives of acrylic and/or methacrylic acid are described, which copolymers are suitable for the production of layer elements by the Langmuir-Blodgett method. Layer elements of this type can be used for optical waveguide systems and for the production of optical filters and for lithographic purposes.
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