公开(公告)号：US4119548A

公开(公告)日：1978-10-10

申请号：US846308

申请日：1977-10-28

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C09K15/32 ,  C07F15/04 ,  C10L1/24 ,  C10M159/18 ,  C10M163/00 ,  C10M1/54 ,  C07F15/02 ,  C10M3/48

CPC classification number: C10L1/2412 ,  C07F15/045 ,  C10M159/18 ,  C10M163/00 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/024 ,  C10M2207/026 ,  C10M2207/04 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2209/00 ,  C10M2209/02 ,  C10M2209/10 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2211/02 ,  C10M2215/06 ,  C10M2215/062 ,  C10M2215/064 ,  C10M2215/065 ,  C10M2215/102 ,  C10M2219/086 ,  C10M2219/087 ,  C10M2219/089 ,  C10M2219/108 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2227/02 ,  C10M2227/04 ,  C10M2227/081 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2210/08 ,  C10N2240/08 ,  C10N2250/10

Abstract: Nickel (II) thiobis(alkylphenolate) complex with thiobis(alkylphenol) forms novel complexes having improved antioxidant properties which are useful in a wide range of organic media such as lubricants and plastics. These novel complexes also provide energy quenching characteristics to such organic compositions.

Abstract translation: 具有硫代双（烷基酚）的PG，1镍（II）硫代双（烷基酚盐）络合物形成具有改进的抗氧化性能的新配合物，其可用于广泛的有机介质如润滑剂和塑料。 这些新型配合物还提供了这种有机组合物的能量淬灭特性。

公开(公告)号：US4519928A

公开(公告)日：1985-05-28

申请号：US295918

申请日：1981-08-24

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C07D249/18 ,  C10M133/44 ,  C10M1/32

CPC classification number: C10M133/44 ,  C07D249/18

Abstract: Lubricant compositions containing oleaginous materials and, in amounts sufficient to impart oxidation, and corrosion resistance properties thereto, N-t-alkylated benzotriazoles.

Abstract translation: 含有油性材料的润滑剂组合物，其用量足以赋予其N-氧化的抗氧化性和耐腐蚀性的N-叔烷基化苯并三唑。

公开(公告)号：US4443381A

公开(公告)日：1984-04-17

申请号：US166662

申请日：1980-07-07

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C10M159/18 ,  C10M159/22 ,  C10M169/00 ,  C10M1/54 ,  C07F15/02 ,  C07F15/04 ,  C10M3/48

CPC classification number: C07C323/00 ,  C10M159/18 ,  C10M159/22 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089 ,  C10N2210/08

Abstract: A direct exchange process wherein compounds are prepared by replacing calcium in neutral and overbased calcium phenol sulfides with transition metals by reaction with transition metal salts in the presence of an accelerator or promoter provides useful stabilizer-detergent additives for lubricating compositions.

Abstract translation: 通过在促进剂或促进剂的存在下与过渡金属盐反应，通过用过渡金属代替中性和高碱性酚钙硫化物中的钙制备化合物提供了有用的用于润滑组合物的稳定剂 - 洗涤剂添加剂。

公开(公告)号：US4427562A

公开(公告)日：1984-01-24

申请号：US375413

申请日：1982-05-06

Applicant: Andrew G. Horodysky ,  Milton Braid

Inventor： Andrew G. Horodysky ,  Milton Braid

IPC: C10L1/22 ,  C10L1/224 ,  C10L10/08 ,  C10M20060101 ,  C10M133/16 ,  C10N30/06 ,  C10N30/10 ,  C10N30/12 ,  C10N40/25 ,  C10N50/10 ,  C10M1/32

CPC classification number: C10L10/08 ,  C10L1/224 ,  C10L10/04 ,  C10M133/16 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/28 ,  C10M2219/086 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/104 ,  C10N2240/106

Abstract: N-alkoxyalkyl amides may be formed by the reaction of primary alkoxyalkylamines with carboxylic acids such as formic acid, or alternatively by ammonolysis of the appropriate formate ester. The resultant amides exhibit friction reducing properties when incorporated in additive amounts in lubricants and fuels. Extremely low concentrations of such additives, i.e. N-alkoxyalkyl formamides in lubricating oils result in vastly improved, i.e. lowered coefficients of friction. By virtue of the friction reducing characteristics and lubricity properties, the additive compositions of the present invention exhibit reduced wear on rubbing surfaces.

Abstract translation: N-烷氧基烷基酰胺可以通过伯烷氧基烷基胺与羧酸如甲酸的反应形成，或者通过合适的甲酸酯的氨解反应形成。 当加入到润滑剂和燃料中的添加量时，所得到的酰胺显示摩擦降低性能。 这些添加剂，即N-烷氧基烷基甲酰胺在润滑油中的极低浓度导致大大改善，即降低的摩擦系数。 由于摩擦降低特性和润滑性能，本发明的添加剂组合物在摩擦表面上显示出减少的磨损。

公开(公告)号：US4330421A

公开(公告)日：1982-05-18

申请号：US167612

申请日：1980-07-11

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C10M135/30 ,  C10M159/22 ,  C10M1/54

CPC classification number: C10M159/22 ,  C10M135/30 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089 ,  C10N2210/07 ,  C10N2210/08 ,  C10N2250/10

Abstract: Lubricant compositions containing minor effective amounts of calcium phenol sulfides containing controlled amounts of a transition metal wherein the transition metal is derived by a direct exchange reaction for calcium provide stabilizer/detergent properties thereto and protect the compositions thereof against oxidative deterioration.

Abstract translation: 含有少量有效量的含有受控量的过渡金属的钙苯酚硫化物的润滑剂组合物，其中过渡金属通过钙的直接交换反应得到，从而提供稳定剂/洗涤剂的性质并保护其组合物免受氧化劣化。

公开(公告)号：US4305832A

公开(公告)日：1981-12-15

申请号：US102098

申请日：1979-12-10

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C09K15/14 ,  C10M135/30 ,  C10M169/00 ,  C10M3/36 ,  C07C149/32 ,  C07C149/36

CPC classification number: C07C323/00 ,  C09K15/14 ,  C10M135/30 ,  C10M2219/087 ,  C10M2219/088 ,  C10M2219/089

Abstract: Phenol sulfides, disulfides, polysulfides and oligomers thereof when reacted with alkyl vinyl ethers provide addition products substantially comprised of novel acetal derivatives which are effective oxidation inhibitors when incorporated into organic media normally susceptible to oxidative degradation.

Abstract translation: 当与烷基乙烯基醚反应时，苯酚硫化物，二硫化物，多硫化物和其低聚物提供基本上由新型缩醛衍生物组成的添加产物，当被掺入通常易于氧化降解的有机介质中时，这些产物是有效的氧化抑制剂。

公开(公告)号：US4187186A

公开(公告)日：1980-02-05

申请号：US895677

申请日：1978-04-12

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C07D249/18 ,  C10M113/16 ,  C10M1/32

CPC classification number: C10M113/16 ,  C07D249/18 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/04 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2209/00 ,  C10M2209/02 ,  C10M2209/10 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2211/02 ,  C10M2215/102 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/30 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2227/02 ,  C10M2227/04 ,  C10M2227/081 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2240/02 ,  C10N2240/08 ,  C10N2250/10

Abstract: Lubricant compositions containing oleagineous materials and, in amounts sufficient to impart thereto resistance to oxidation, wear and metal corrosion, esters of alkylbenzotriazolecarboxylic acid having the formula: ##STR1## where R is selected from the group consisting of alkyl containing from 1 to about 12 carbon atoms, aralkyl containing from 7 to about 12 carbon atoms and cycloalkyl and alkyl-substituted cycloalkyl containing from about 5 to about 12 carbon atoms; and R' is hydrogen or an alkyl group containing from 1 to about 8 carbon atoms.

Abstract translation: 含有含油材料的润滑剂组合物，其用量足以赋予其抗氧化，耐磨和金属腐蚀的能力，具有下式的烷基苯并三唑羧酸的酯：其中R选自含有1至约12个碳原子的烷基 原子，含有7至约12个碳原子的芳烷基和含有约5至约12个碳原子的环烷基和烷基取代的环烷基; 并且R'是氢或含有1至约8个碳原子的烷基。

公开(公告)号：US4162225A

公开(公告)日：1979-07-24

申请号：US897078

申请日：1978-04-17

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C07D249/18 ,  C10M133/44 ,  C10M1/32

CPC classification number: C07D249/18 ,  C10M133/44 ,  C10M2205/00 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/04 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2211/02 ,  C10M2215/102 ,  C10M2215/22 ,  C10M2215/221 ,  C10M2215/225 ,  C10M2215/226 ,  C10M2215/30 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2227/02 ,  C10M2227/04 ,  C10M2227/081 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2240/08 ,  C10N2250/10

Abstract: Lubricant compositions containing oleaginous materials and, in amounts sufficient to impart resistance to oxidation thereto, adducts of benzotriazole compounds and substituted acrylonitrile.

Abstract translation: 含有油质材料的润滑剂组合物，其量足以赋予其氧化抗性，苯并三唑化合物和取代的丙烯腈的加合物。

公开(公告)号：US4052324A

公开(公告)日：1977-10-04

申请号：US738762

申请日：1976-11-04

Applicant: Milton Braid

Inventor： Milton Braid

IPC: C10M159/12 ,  C07D233/14 ,  C10M137/12 ,  C10N30/06 ,  C10N40/08 ,  C10M1/44 ,  C10M3/38 ,  C10M5/24 ,  C10M7/24

CPC classification number: C10M137/12 ,  C10M2201/14 ,  C10M2205/00 ,  C10M2205/026 ,  C10M2205/028 ,  C10M2207/04 ,  C10M2207/125 ,  C10M2207/129 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2207/34 ,  C10M2209/00 ,  C10M2209/02 ,  C10M2209/10 ,  C10M2209/104 ,  C10M2209/105 ,  C10M2211/02 ,  C10M2215/102 ,  C10M2223/04 ,  C10M2223/042 ,  C10M2223/063 ,  C10M2227/02 ,  C10M2227/04 ,  C10M2227/081 ,  C10M2229/02 ,  C10M2229/05 ,  C10N2210/02 ,  C10N2240/08

Abstract: Lubricant compositions are provided which contain: oleaginous media, and an antiwear and water tolerance improving amount of a product formed by reacting (a) a compound having the formula: ##STR1## where R' is a substantially unbranched paraffinic alkyl group containing from about 10 to about 36 carbon atoms, and R is a hydrocarbyl group containing from 1 to about 4 carbon atoms with at least one hydrogen atom present on the carbon atom which is bonded to the oxygen; (b) a substituted imidazoline of the formula: ##STR2## where one of the R.sup.2 and R.sup.3 substituents must be a substantially unbranched paraffinic or olefinic hydrocarbyl group containing from about 12 to about 35 carbon atoms; and the other R.sup.2 or R.sup.3 substituent is selected from the group consisting of: paraffinic alkyl containing from 1 to about 35 carbon atoms, alkenyl containing from 1 to about 35 carbon atoms, and hydroxy-, alkyoxy-, alkoxymethoxy-, and oxo-substituted alkyl and alkenyl containing from 1 to about 20 carbon atoms; and (c) water; at proportions which are most preferably stoichiometric and at temperatures of from about 130.degree. to about 170.degree. C. Particularly contemplated are compositions in the form of lubricating oils and greases.

公开(公告)号：USRE32295E

公开(公告)日：1986-11-25

申请号：US679517

申请日：1984-12-07

Applicant: Milton Braid ,  Andrew G. Horodysky

Inventor： Milton Braid ,  Andrew G. Horodysky

IPC: C07F5/04 ,  C10L1/30 ,  C10M137/10 ,  C10M139/00 ,  C10M141/12

CPC classification number: C07F5/04 ,  C10L1/303 ,  C10M137/10 ,  C10M139/00 ,  C10M141/12 ,  C10M2227/061 ,  C10M2227/062 ,  C10N2250/10

Abstract: New reaction products obtained by reacting (1) a hindered phenol, (2) a boron compound and (3) an amine together are described. Preferred reaction sequences are:(a)(2)+(1), then this product with (3); and(b)(2)+(3), then this product with (1).Also described are lubricant compositions containing the reaction products and a method of reducing fuel consumption in an internal combustion engine by lubricating the engine with a lubricant containing the reaction product.