公开(公告)号：CA754670A

公开(公告)日：1967-03-14

申请号：CA754670D

Applicant: PHILLIPS PETROLEUM CO

Inventor： DIETZ RICHARD E

公开(公告)号：CA1188671A

公开(公告)日：1985-06-11

申请号：CA416506

申请日：1982-11-26

Applicant: PHILLIPS PETROLEUM CO ,  DIETZ RICHARD E ,  CAPSHEW CHARLES E ,  MARTIN JOEL L

Inventor： WELCH M BRUCE ,  DIETZ RICHARD E ,  CAPSHEW CHARLES E ,  MARTIN JOEL L

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/62 ,  C08F4/64 ,  C08F4/658 ,  C08F10/00 ,  B01J31/38 ,  C08F4/66

Abstract: Catalysts effective for the polymerization of olefins at high productivity formed upon mixing (1) a solution of a titanium tetrahydrocarbyloxide or a zirconium tetrahydrocarbyloxide and an organoaluminum halide with (2) a dihydrocarbylmagnesium compound alone or admixed with a minor amount of a trialhylaluminum and (3) combining the product obtained in (2) with a metal halide selected from a silicon tetrahalide and a titanium tetrahalide. The catalyst component thus produced can be combined with an organoaluminum compound as a cocatalyst component.

公开(公告)号：CA1166234A

公开(公告)日：1984-04-24

申请号：CA381269

申请日：1981-07-07

Applicant: PHILLIPS PETROLEUM CO

Inventor： CAPSHEW CHARLES E ,  SHORT JAMES N ,  WELCH M BRUCE ,  DIETZ RICHARD E

IPC: C08F4/628 ,  C08F4/02 ,  C08F4/60 ,  C08F4/62 ,  C08F10/00 ,  C08F12/06 ,  C08F36/04

Abstract: A transition metal compound and a metal halide compound are chemically combined to form a composition of matter. The composition of matter is rapidly mixed with a precipitating agent to form an active olefin polymerization catalyst under an olefin atmosphere and prepolymer is formed on said catalyst to yield a catalyst capable of producing low fines content polymer.

公开(公告)号：CA1135247A

公开(公告)日：1982-11-09

申请号：CA343703

申请日：1980-01-15

Applicant: PHILLIPS PETROLEUM CO

Inventor： DIETZ RICHARD E

IPC: C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

Abstract: 27831 A process for polymerizing alpha-olefins in the presence of a catalyst comprising two components. Component A is obtained by mixing a milled mixture of magnesium and particulate inorganic solid with an alcohol and then contacting the resultant product with a tetravalent halogenated titanium compound. Component B comprises a metallic hydride or an organometallic compound, e.g., an organoaluminum compound.

公开(公告)号：CA1096363A

公开(公告)日：1981-02-24

申请号：CA271167

申请日：1977-02-07

Applicant: PHILLIPS PETROLEUM CO

Inventor： DIETZ RICHARD E ,  NOWLIN OSCAR D

IPC: C08F4/00 ,  C08F4/60 ,  C08F10/00 ,  C08F4/02 ,  C08F10/02

Abstract: An organic halide is added dropwise to magnesium metal in the absence of an ether or other complexing diluent, preferably in the absence of any extraneous diluent produce a magnesium reducing agent. The resulting magnesium reducing agent is then washed with an unreactive liquid hydrocarbon. An organoaluminum compound is mixed with the magnesium reducing agent either before or after the washing. The resulting cocatalyst produced by contacting the magnesium reducing agent with the organoaluminum compound is contacted with a titanium tetrahalide to give a catalyst. This catalyst is useful in the polymerization of 1-olefins and is of particular utility in the polymerization of ethylene at high productivity rates.

公开(公告)号：CA979419A

公开(公告)日：1975-12-09

申请号：CA116816

申请日：1971-06-28

Applicant: PHILLIPS PETROLEUM CO

Inventor： DIETZ RICHARD E

IPC: B01J23/26 ,  C08F4/24 ,  C08F10/00 ,  C08F210/16