公开(公告)号：US20170335057A1

公开(公告)日：2017-11-23

申请号：US15522801

申请日：2015-10-27

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Kevin Anthony Rogers ,  Matthew James Beatty ,  Woo-Sung Bae ,  Jack Rogers Kovsky ,  Michael Robert Christy

IPC: C08G63/66 ,  C09D175/06 ,  C08G18/08 ,  C08G18/76 ,  C08G18/48 ,  C08G18/42 ,  C09J175/06 ,  C08G101/00

CPC classification number: C08G63/66 ,  C08G18/14 ,  C08G18/4244 ,  C08G18/4252 ,  C08G18/4837 ,  C08G18/7621 ,  C08G63/60 ,  C08G2101/0008 ,  C08G2101/0083 ,  C08J11/24 ,  C08J2367/02 ,  C09D175/06 ,  C09J175/06 ,  Y02P20/582 ,  Y02W30/706

Abstract: Polyester polyols, processes for making them, and applications for the polyols are disclosed. In some aspects, the polyols comprise recurring units from a thermoplastic polyester or an aromatic polyacid source, a glycol, and a hydroxy-functional ketal acid, ester or amide. Optionally, the polyols incorporate recurring units of a hydrophobe. The polyols are made in one or multiple steps; in some aspects, the thermoplastic polyester or aromatic polyacid source and the glycol are reacted first, followed by reaction with the hydroxy-functional ketal acid, ester or amide. The resulting polyols have good transparency and little or no particulate settling or phase separation. High-recycle-content polyols having desirable properties and attributes for formulating polyurethane products, including aqueous polyurethane dispersions, flexible and rigid foams, coatings, adhesives, sealants, and elastomers can be made. The polyols provide a sustainable alternative to bio- or petrochemical-based polyols.

公开(公告)号：US20170260353A1

公开(公告)日：2017-09-14

申请号：US15602566

申请日：2017-05-23

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Shakti L. Mukerjee ,  Kevin Anthony Rogers ,  Adam W. Emerson ,  Eric David Vrabel ,  Brian Douglas Phillips

IPC: C08J11/24 ,  C08G63/91 ,  C08G18/08 ,  C08K5/12 ,  C08G18/42 ,  C08J5/24 ,  C08G18/36

CPC classification number: C08J11/24 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/36 ,  C08G18/42 ,  C08G18/4288 ,  C08G18/7664 ,  C08G63/16 ,  C08G63/916 ,  C08J5/24 ,  C08J2367/02 ,  C08J2375/04 ,  C08J2375/06 ,  C08J2423/02 ,  C08J2467/02 ,  C08J2475/04 ,  C08K5/12 ,  Y02P20/125

Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

公开(公告)号：US20170226310A1

公开(公告)日：2017-08-10

申请号：US15497288

申请日：2017-04-26

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Shakti L. Mukerjee ,  Kevin Anthony Rogers ,  Eric David Vrabel ,  Brian Chermside ,  Adam W. Emerson ,  Brian Douglas Phillips

IPC: C08J11/24 ,  C08G18/42 ,  C08G18/76 ,  C08G63/16

CPC classification number: C08J11/24 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/36 ,  C08G18/42 ,  C08G18/4288 ,  C08G18/7664 ,  C08G63/16 ,  C08G63/916 ,  C08J5/24 ,  C08J2367/02 ,  C08J2375/04 ,  C08J2375/06 ,  C08J2423/02 ,  C08J2467/02 ,  C08J2475/04 ,  C08K5/12 ,  Y02P20/125

Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

公开(公告)号：US09714334B2

公开(公告)日：2017-07-25

申请号：US15099807

申请日：2016-04-15

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Shakti L. Mukerjee ,  Kevin Rogers ,  Eric David Vrabel ,  Adam W. Emerson ,  Brian Douglas Phillips

IPC: C08J11/24 ,  C08J5/24 ,  C08G63/91 ,  C08G18/08 ,  C08G18/36 ,  C08G18/42 ,  C08K5/12

CPC classification number: C08J11/24 ,  C08G18/0823 ,  C08G18/10 ,  C08G18/36 ,  C08G18/42 ,  C08G18/4288 ,  C08G63/916 ,  C08J5/24 ,  C08J2367/02 ,  C08J2375/06 ,  C08J2423/02 ,  C08K5/12 ,  Y02P20/125

Abstract: A process for producing a polyester polyol comprising reacting a recycle stream selected from recycled PET carpet, carpet fiber, containers, textiles, articles or mixtures thereof, with a glycol in a reactor, thereby forming a digested product stream comprising polyols, and an undigested stream; and then reacting the digested product stream with a hydrophobe selected from dimer fatty acids, trimer fatty acids, oleic acid, ricinoleic acid, tung oil, corn oil, canola oil, soybean oil, sunflower oil, bacterial oil, yeast oil, algae oil, castor oil, triglycerides or alkyl carboxylate esters having saturated or unsaturated C6-C36 fatty acid units, saturated or unsaturated C6-C36 fatty acids, alkoxylated castor oil, saturated or unsaturated C9-C18 dicarboxylic acids or diols, cardanol-based products, recycled cooking oil, branched or linear C6-C36 fatty alcohols, hydroxy-functional materials derived from epoxidized, ozonized, or hydroformylated fatty esters or acids, or mixtures thereof.

公开(公告)号：US20170051103A1

公开(公告)日：2017-02-23

申请号：US15306774

申请日：2015-04-30

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric D. Vrabel ,  Kevin Anthony Rogers ,  Shakti L. Mukerjee ,  Matthew J. Beatty ,  Adam William Emerson ,  Matthew T. Brown ,  Jack Rogers Kovsky ,  Michael D. Kellerman ,  Michael Robert Christy

IPC: C08G63/87 ,  C08G18/42 ,  C08G18/72 ,  C08G63/183

CPC classification number: C08G63/87 ,  C07C67/03 ,  C08G18/42 ,  C08G18/4213 ,  C08G18/72 ,  C08G63/183 ,  C08G63/553 ,  C08J11/24 ,  C08J2367/02 ,  Y02P20/582 ,  Y02W30/706 ,  C07C69/82

Abstract: Polyester polyols made from recycled polyethylene terephthalate (rPET) and processes for making them are disclosed. The rPET is heated with a C3-C10 glycol reactant to give a digested intermediate comprising glycols and a terephthalate component, which comprises 45 to 70 wt. % of bis(hydroxyalkyl)terephthalates, and preferably lesser amounts of terephthalate dimers and trimers. Treatment of the digested intermediate with activated carbon gives a polyester polyol having a color index less than 20. The polyols have desirable hydroxyl numbers, viscosities, appearance, and other attributes for formulating polyurethane products and are a sustainable alternative to bio- or petrochemical-based polyols.

Abstract translation: 公开了由回收聚对苯二甲酸乙二醇酯（rPET）制成的聚酯多元醇及其制备方法。 用C 3 -C 10二醇反应物加热rPET，得到包含二醇和对苯二甲酸酯组分的消化的中间体，其包含45至70重量％ ％的双（羟烷基）对苯二甲酸酯，优选较少量的对苯二甲酸酯二聚体和三聚体。 用活性炭处理消化的中间体可得到颜色指数小于20的聚酯多元醇。多元醇具有理想的羟基数，粘度，外观和其他配方聚氨酯产品的特性，是生物或石油化学品的可持续替代品 多元醇。

公开(公告)号：US20170029551A1

公开(公告)日：2017-02-02

申请号：US15084737

申请日：2016-03-30

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Jack Rogers Kovsky

IPC: C08G18/28 ,  C08J9/14 ,  C09D175/04 ,  C08G18/08 ,  C07C29/09 ,  C07C31/18

CPC classification number: C08G63/916 ,  C07C29/09 ,  C07C31/18 ,  C08F20/10 ,  C08F291/08 ,  C08G18/14 ,  C08G18/28 ,  C08G18/4213 ,  C08G18/664 ,  C08G18/722 ,  C08G18/7671 ,  C08G63/183 ,  C08G2101/00 ,  C08G2101/0025 ,  C08G2150/20 ,  C08J9/141 ,  C08J11/24 ,  C08J2203/14 ,  C08J2205/10 ,  C08J2367/02 ,  C08J2375/04 ,  C09D5/03 ,  C09D167/00 ,  C09D175/04 ,  C09D175/06 ,  Y02W30/706

Abstract: The present invention relates to the chemical digestion of keratin, such as avian feathers and wool. The digestion product is made by heating the feathers or wool with a solvent selected from glycols, alkanolamines, polyamines, and combinations thereof. The resulting digested keratin product is a keratin-derived polyol useful for making polymeric materials such as polyurethanes. The digestion products provide a sustainable alternative to petrochemical based intermediates.

Abstract translation: 本发明涉及角蛋白的化学消化，例如禽类羽毛和羊毛。 消化产物通过用选自二醇，烷醇胺，多胺及其组合的溶剂加热羽毛或羊毛制成。 所得消化的角蛋白产品是用于制备聚合物材料如聚氨酯的角蛋白衍生的多元醇。 消化产品为石化基中间体提供了可持续的替代方案。

公开(公告)号：US20160272756A1

公开(公告)日：2016-09-22

申请号：US15083491

申请日：2016-03-29

Applicant: RESINATE MATERIALS GROUP, INC.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew Beatty

IPC: C08G63/91 ,  C09D175/06 ,  C08G18/42

CPC classification number: C08G63/916 ,  C08G18/242 ,  C08G18/246 ,  C08G18/34 ,  C08G18/4202 ,  C08G18/423 ,  C08G18/4233 ,  C08G18/4238 ,  C08G18/722 ,  C08G18/73 ,  C08G18/755 ,  C09D175/06

Abstract: Cycloaliphatic polyester polyols and processes for making them from thermoplastic polyesters are disclosed. One process comprises heating a thermoplastic polyester with a glycol to give a digested intermediate and hydrogenating aromatic rings in the digested intermediate to produce the cycloaliphatic polyester polyol. Optionally, the digested intermediate is reacted with a hydrophobe to give a modified polyol prior to hydrogenation, and the modified polyol is hydrogenated to give the cycloaliphatic polyester polyol. The high-recycle-content cycloaliphatic polyester polyols have desirable attributes for formulating polyurethane dispersions, two-component polyurethane coatings, mono- or poly(meth)acrylates, polyisocyanurates, flexible and rigid foams, coatings, adhesives, sealants, and elastomers, and they provide a sustainable alternative to petrochemical-based polyols.

Abstract translation: 公开了环脂族聚酯多元醇及其由热塑性聚酯制备它们的方法。 一种方法包括用二醇加热热塑性聚酯以在消化的中间体中产生消化的中间体和氢化芳环以制备脂环族聚酯多元醇。 任选地，将消化的中间体与疏水物反应以在氢化之前得到改性的多元醇，并将改性的多元醇氢化得到环脂族聚酯多元醇。 高回收含量的脂环族聚酯多元醇具有用于配制聚氨酯分散体，双组分聚氨酯涂料，单或多（甲基）丙烯酸酯，聚异氰脲酸酯，柔性和刚性泡沫，涂料，粘合剂，密封剂和弹性体的所需属性，并且它们 为石化多元醇提供可持续的替代方案。

公开(公告)号：US20160122471A1

公开(公告)日：2016-05-05

申请号：US14959499

申请日：2015-12-04

Applicant: Resinate Materials Group, Inc.

Inventor： Woo-Sung Bae ,  Rick Tabor ,  Kevin Anthony Rogers ,  Shakti L. Mukerjee

IPC: C08G63/91 ,  C08K5/09 ,  C08J3/18 ,  C08L67/03 ,  C08L27/06 ,  C08K5/00 ,  C08K5/092

CPC classification number: C08G63/916 ,  C08J3/18 ,  C08J2300/22 ,  C08J2327/06 ,  C08J2367/02 ,  C08J2367/03 ,  C08J2467/02 ,  C08J2467/03 ,  C08J2469/00 ,  C08J2471/02 ,  C08K5/0016 ,  C08K5/09 ,  C08K5/092 ,  C08L27/06 ,  C08L67/02 ,  C08L67/03 ,  C08L69/00 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2207/04 ,  C08L2207/20

Abstract: The present invention relates to polymeric plasticizer compositions made from an aromatic acid source, a glycol, and a C4-C36 monocarboxylic acid, or ester or anhydride thereof. The aromatic acid source can include polymeric materials such as recycled polyethylene terephthalate (PET). The present invention also relates to methods for making the polymeric plasticizer compositions, to methods of plasticizing polymeric materials, and to plasticized polymeric compositions. The polymeric plasticizers are useful for plasticizing various polymers, such as thermoplastic polymers, including, for example, polyvinyl chloride (PVC). The polymeric plasticizers provide a sustainable alternative to conventional phthalate ester plasticizers, such as diisooctyl phthalate (DOP).

Abstract translation: 本发明涉及由芳族酸源，二醇和C 4 -C 36单羧酸或其酯或酸酐制成的聚合物增塑剂组合物。 芳族酸源可以包括聚合物材料，例如再循环的聚对苯二甲酸乙二醇酯（PET）。 本发明还涉及制备聚合物增塑剂组合物，聚合物材料增塑方法和增塑聚合物组合物的方法。 聚合物增塑剂可用于增塑各种聚合物，例如热塑性聚合物，包括例如聚氯乙烯（PVC）。 聚合物增塑剂提供了常规邻苯二甲酸酯增塑剂的可持续替代方法，如邻苯二甲酸二异辛酯（DOP）。

公开(公告)号：US20160052844A1

公开(公告)日：2016-02-25

申请号：US14882569

申请日：2015-10-14

Applicant: Resinate Materials Group, Inc.

Inventor： Rick Tabor ,  Eric David Vrabel ,  Matthew J. Beatty ,  Jack Rogers Kovsky

IPC: C07C29/128 ,  C09D175/04 ,  C08F20/02 ,  C07C31/00 ,  C08G18/32 ,  C07C57/04

CPC classification number: C09D175/04 ,  C08G18/3203 ,  C08G18/3206 ,  C08G18/6446 ,  C08G18/6511 ,  C08G18/7664 ,  C08G2101/0025 ,  C08G2105/02 ,  C08J9/141 ,  C08J2201/022 ,  C08J2203/14 ,  C08J2205/06 ,  C08J2205/10 ,  C08J2375/04

Abstract: The present invention relates to the chemical digestion of keratin, such as avian feathers and wool. The digestion product is made by heating the feathers or wool with a solvent selected from glycols, alkanolamines, polyamines, and combinations thereof. The resulting digested keratin product is a keratin-derived polyol useful for making polymeric materials such as polyurethanes. The digestion products provide a sustainable alternative to petrochemical based intermediates.

Abstract translation: 本发明涉及角蛋白的化学消化，例如禽类羽毛和羊毛。 消化产物通过用选自二醇，烷醇胺，多胺及其组合的溶剂加热羽毛或羊毛制成。 所得消化的角蛋白产品是用于制备聚合物材料如聚氨酯的角蛋白衍生的多元醇。 消化产品为石化基中间体提供了可持续的替代方案。

公开(公告)号：US10745585B2

公开(公告)日：2020-08-18

申请号：US15279557

申请日：2016-09-29

Applicant: Resinate Materials Group, Inc.

Inventor： Gary Spilman ,  Michael Christy ,  Eric Vrabel ,  Gage Fryz ,  Rick Tabor ,  Brian T. Comstock-Reid

IPC: C09D175/06 ,  C08L67/02 ,  C09D175/04 ,  C09D169/00 ,  C08G64/14 ,  C08G63/64 ,  C09D167/02 ,  C08L69/00 ,  C08J11/24 ,  C08G18/44 ,  C08G18/42 ,  C08G18/66 ,  C08G18/73 ,  C08G18/75 ,  C08G18/24 ,  C08G18/72 ,  C08G18/80 ,  C08G18/22 ,  C09D5/08 ,  C08K5/13 ,  C08G101/00 ,  C09D7/40 ,  C09D7/61 ,  C09D167/03 ,  C09D161/28 ,  C09D167/00 ,  C09D7/65 ,  C08K5/09 ,  C08K5/00 ,  C08J3/24 ,  C08K3/22 ,  C08K3/34 ,  C08K3/32 ,  C08K3/01 ,  C08K5/29 ,  C08K5/3492 ,  C08K3/38 ,  C08K3/36 ,  C08L75/06 ,  C08L67/03 ,  C08L61/28 ,  C08L67/00 ,  B05D7/00 ,  B32B15/09 ,  B32B15/095 ,  B32B15/04

Abstract: The present invention relates to coatings, particularly high performance coatings, containing a polyester polyol comprising recurring units derived from a polyacid source, poly(bisphenol-A carbonate) (PBAC), and a glycol. The PBAC is preferably recycled poly(bisphenol-A carbonate) (rPBAC). These coatings provide improved salt spray and stain resistance along with a variety of other coating performance attributes. The polyols can contain a significant recycle and biobased content, making them sustainable alternatives to petroleum based polyols.