公开(公告)号：EP1092421B1

公开(公告)日：2007-03-21

申请号：EP00308702.0

申请日：2000-10-03

Applicant: ROHM AND HAAS COMPANY

Inventor： Chang, Ching-Jen ,  Jones, Charles Elwood ,  Weinstein, Barry

IPC: A61K8/04 ,  A61Q17/04 ,  A61K8/81

CPC classification number: B82Y5/00 ,  A61K8/0279 ,  A61K8/11 ,  A61K8/72 ,  A61K8/8147 ,  A61K2800/413 ,  A61Q17/04 ,  C08F265/04 ,  C08F265/06 ,  C08F285/00 ,  C08L51/003 ,  C08L2666/02

公开(公告)号：EP1506977B1

公开(公告)日：2006-12-27

申请号：EP04254650.7

申请日：2004-08-02

Applicant: ROHM AND HAAS COMPANY

Inventor： Blankenship, Robert Mitchell ,  Bromm, Karl Allen ,  Gappert, Griffin Melaney ,  Tang, Xun ,  Weinstein, Barry

IPC: C08J3/24 ,  C09J129/02 ,  C09J133/00 ,  C08G81/02

CPC classification number: C09D133/08 ,  C08L33/066 ,  C09D129/02 ,  C09D129/06 ,  Y10T428/31504 ,  Y10T428/31855

公开(公告)号：EP1288337A3

公开(公告)日：2004-02-25

申请号：EP02255835.7

申请日：2002-08-21

Applicant: ROHM AND HAAS COMPANY

Inventor： Ghosh, Tirthankar ,  Hann, William M. ,  Weinstein, Barry

IPC: C23F11/173

CPC classification number: C08F22/40 ,  C23F11/173

Abstract: The use of polymeric corrosion inhibiting compositions incorporating heterocyclic groups is disclosed. The polymers form a protective barrier on metallic components to aqueous systems and remain substantive on metallic surfaces over a wide pH range. Moreover, the polymers are resistant to oxidizing biocides, and are substantially impervious to repeated or prolonged exposure to corrosive agents.

公开(公告)号：EP1288232A2

公开(公告)日：2003-03-05

申请号：EP02255833.2

申请日：2002-08-21

Applicant: ROHM AND HAAS COMPANY

Inventor： Ghosh, Tirthankar ,  Hann, William M. ,  Weinstein, Barry

IPC: C08F22/40 ,  C23F11/173

CPC classification number: C23F11/173 ,  C08F22/40

Abstract: A new class of polymeric corrosion inhibiting compositions incorporating pendant heterocyclic groups which are surprisingly effective copper corrosion inhibitors are disclosed. The polymers form a protective barrier on metallic components to aqueous systems and remain substantive on metallic surfaces over a wide pH range. Moreover, the polymers are resistant to oxidizing biocides, and are substantially impervious to repeated or prolonged exposure to corrosive agents.

Abstract translation: 公开了一类具有令人吃惊的有效铜腐蚀抑制剂的并入侧链杂环基团的聚合物腐蚀抑制组合物。 聚合物在金属组分上形成对含水体系的保护屏障，并且在宽pH范围内保持金属表面上的实质性。 而且，聚合物对抗氧化杀生物剂具有抗性，并且基本上不会重复或长时间暴露于腐蚀剂。

公开(公告)号：EP0792890B1

公开(公告)日：1999-12-29

申请号：EP97301238.8

申请日：1997-02-25

Applicant: ROHM AND HAAS COMPANY

Inventor： McCallum, Thomas Francis, III ,  Weinstein, Barry

IPC: C08F2/38 ,  C08F20/04

CPC classification number: C08F2/38 ,  C08F20/04

公开(公告)号：EP0877076A3

公开(公告)日：1999-06-16

申请号：EP98303437.2

申请日：1998-05-01

Applicant: ROHM AND HAAS COMPANY

Inventor： Gauthier, Francois ,  Weinstein, Barry ,  Duccini, Yves ,  Porter, Raymond ,  Witiak, David

IPC: C11D3/37

CPC classification number: C11D3/3784 ,  C11D3/3749

Abstract: The invention provides a detergent formulations comprising at least one water soluble polymer, or salt thereof, bearing at least one phosphonate group. Suitable polymers comprise:
wherein X is H, Na, K or A; and A is a polymer, copolymer, or water soluble salt thereof, comprising, one or more of the following monomers in polymerised form:-
carboxylic acids of the formula
wherein
R 1 is H, OH, C 1 -C 9 alkyl or alkoxy or acetoxy or acetate R 2 is H, C 1 -C 3 alkyl or alkoxy, COOR 3 R 3 is H, Na, K or C 1 -C 10 alkyl; hydroxypropyl acrylate, propyl methacrylate, 2-acrylamido-2-propane sulphonic acid, sodium styrene sulphonate, sodium allylsulphonate, sodium methyl sulphonate, vinyl sulphonic acid, and salts thereof; acrylamide, methacrylamide, tert-butylacrylamide, (meth)acrylonitrile, styrene, vinyl acetate allyloxy-2-hydroxypropyl sulphonate and dialkylacrylamide. Machine dish washing detergents and laundry detergents are also provided which comprise detergent formulations of the present invention.

公开(公告)号：EP0770673A2

公开(公告)日：1997-05-02

申请号：EP96307660.9

申请日：1996-10-23

Applicant: ROHM AND HAAS COMPANY

Inventor： Keenan, Andrea Claudette ,  Kirk, Thomas Cleveland ,  McCallum, Thomas Francis, III ,  Shulman, Jan Edward ,  Tallent, Richard James ,  Weinstein, Barry

IPC: C11D3/37

CPC classification number: C11D3/3757

Abstract: Polycarboxylate additives suitable for use in automatic dishwasher detergent compositions are prepared by polymerizing three or more monomers including monoethylenically unsaturated C 3 to C 6 monocarboxylic acids such as acrylic acid, monoethylenically unsaturated C 4 to C 6 dicarboxylic acids such as maleic acid, and monoethylenically unsaturated esters of acrylic or methacrylic acid. Automatic dishwasher detergents prepared from these additives produce low filming and spotting on washed glassware.

Abstract translation: 适用于自动洗碗机洗涤剂组合物的多羧酸盐添加剂通过聚合三种或更多种包括单烯键式不饱和C3-C6单羧酸如丙烯酸，单烯属不饱和C4-C6二羧酸如马来酸和丙烯酸单烯属不饱和酯 甲基丙烯酸。 由这些添加剂制备的自动洗碗机洗涤剂在洗涤的玻璃器皿上产生低成膜和斑点。

公开(公告)号：EP0611031A3

公开(公告)日：1995-03-22

申请号：EP94300103.2

申请日：1994-01-07

Applicant: ROHM AND HAAS COMPANY

Inventor： McCallum, Thomas Francis III ,  Weinstein, Barry

IPC: C08F222/04 ,  C08F222/02 ,  C02F1/56 ,  C11D3/37

CPC classification number: C08F222/04 ,  C08F222/00

Abstract: The present invention provides an aqueous process for preparing water-soluble addition copolymers of containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof, and (b) from about 5 to about 97 percent by weight of one or more monomers C₄-C₆ monoethylenically unsaturated dicarboxylic acids and the alkali metal and ammonium salts thereof. These copolymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.

Abstract translation: 制备方法。 的水溶性共聚物包括聚合混合物。 3-95重量％的环己烯酐（I）或其碱金属或铵盐和5-97重量％的4-6C单烯属不饱和的。 二羧酸（II）或其酸酐或碱金属或铵盐在水和聚合物的存在下反应。 引发剂在高温下 单体混合物 是pref。 存在于反应器中，引发剂在5分钟内进料到反应器中。 至5小时。 温度 的聚合。 是25-110摄氏度 单体混合物 至少部分用碱水中和。 氢氧化钠。 县。 （I）是1,2,3,6-四氢邻苯二甲酸酐; 3,6-环氧-1,2,3,6-四氢邻苯二甲酸酐; 5-降冰片烯-2,3-二羧酸酐; （2.2.2）-5-辛烯-2,3-二羧酸酐; 或2-或3-甲基-1,2,3,6-四氢邻苯二甲酸酐。 单体混合物 包括10-85重量％（I）。

公开(公告)号：EP0611031A2

公开(公告)日：1994-08-17

申请号：EP94300103.2

申请日：1994-01-07

Applicant: ROHM AND HAAS COMPANY

Inventor： McCallum, Thomas Francis III ,  Weinstein, Barry

IPC: C08F222/04 ,  C08F222/02 ,  C02F1/56 ,  C11D3/37

CPC classification number: C08F222/04 ,  C08F222/00

Abstract: The present invention provides an aqueous process for preparing water-soluble addition copolymers of containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof, and (b) from about 5 to about 97 percent by weight of one or more monomers C₄-C₆ monoethylenically unsaturated dicarboxylic acids and the alkali metal and ammonium salts thereof. These copolymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.

公开(公告)号：EP0560519A2

公开(公告)日：1993-09-15

申请号：EP93301511.7

申请日：1993-02-26

Applicant: ROHM AND HAAS COMPANY

Inventor： Adler, David Elliott ,  Shulman, Jan Edward ,  McCallum III, Thomas Francis ,  Weinstein, Barry

IPC: C11D3/37

CPC classification number: C11D3/378 ,  C11D3/3769 ,  C11D3/3773

Abstract: The invention provides a method of enhancing the filming and spotting characteristics of cleaning compositions, for example hard surface cleaners and automatic machine dishwashing formulations, by incorporating into the compositions polymers containing, as polymerized units, (a) one or more monomer selected from C 3 -C 6 monoethylenically unsaturated carboxylic acids and alkali metal and ammonium salts thereof, (b) one or more an-aminoacryloyl derivative, and (c) optionally, one or more monoethylenically unsaturated monomer polymerisable with (a) and (b). The invention also provides polymers suitable for use in such method.

Abstract translation: 本发明提供了提高成膜和斑点清洁组合物的特性的方法，例如硬表面清洁剂，自动洗餐具机用式蒸发散，通过掺入到含有作为聚合单元的组合物的聚合物中，（a）从C3的一个或多个单体中选择 C6单烯属不饱和羧酸和碱金属和铵的盐，（b）一种或多种衍生物-aminoacryloyl，和（c）任选地，一种或多种单烯属不饱和单体的可聚合用的（a）和（b）。 因此本发明提供了适合于在搜索方法中使用的聚合物。