公开(公告)号：US2241492A

公开(公告)日：1941-05-13

申请号：US26593839

申请日：1939-04-04

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M

IPC: C10L1/23

CPC classification number: C10L1/231

公开(公告)号：US2225893A

公开(公告)日：1940-12-24

申请号：US26497939

申请日：1939-03-30

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M

IPC: C07C201/02 ,  C10L1/23

CPC classification number: C10L1/231 ,  C07C201/02 ,  C07C203/04

Abstract: 538,446. Ethereal nitrates. STANDARD OIL DEVELOPMENT CO. Feb. 8, 1940, No. 2476. Convention date, March 30, 1939. [Class 2 (iii)] Secondary aliphatic nitrates are produced by nitrating compounds containing a secondary alcohol group at a temperature not above -10‹C. using a nitration mixture containing at least 50 per cent. excess of nitric acid and also sulphuric acid and water, the molecular ratio of water to sulphuric acid being not greater than 1.6 + .004 (E-50) where E is the percentage excess of nitric acid. A part of the sulphuric acid may be replaced by an acid of phosphorus or a water-soluble fatty acid, such as phosphoric or acteic acid, in which case the lower limit of nitric acid may be used ; otherwise the excess of nitric acid should be at least 100 per cent. Examples describe the production of the nitrate of secondary amyl alcohol, and it is stated that other alcohols that may be used are substituted and unsubstituted mono- and polyhydric alcohols such as isopropyl alcohol, 2 hydroxyhexane, 2-3 dihydroxybutane, 2-3 dihydroxypentane, 2-methyl-2-nitro-1:3-dihydroxybutane, 3-chloro-2-hydroxybutane, the secondary alcohols prepared by hydration of olefines containing up to 12 or 14 carbon atoms (from the cracking of paraffin wax) and 1-12-dihydroxyoctadecane.

公开(公告)号：CA485957A

公开(公告)日：1952-08-19

申请号：CA485957D

Applicant: STANDARD OIL DEV CO

Inventor： BASCOM FRANCES ,  VANDERBILT BYRON M

公开(公告)号：CA507256A

公开(公告)日：1954-11-09

申请号：CA507256D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M ,  GLEASON ANTHONY H

公开(公告)号：CA505512A

公开(公告)日：1954-08-31

申请号：CA505512D

Applicant: STANDARD OIL DEV CO

Inventor： NEWBERG RAYMOND G ,  SLOTTERBECK OBER C ,  VANDERBILT BYRON M

公开(公告)号：CA474855A

公开(公告)日：1951-06-26

申请号：CA474855D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M ,  SWANEY MILLER W ,  FROLICH PER K

公开(公告)号：CA466409A

公开(公告)日：1950-07-04

申请号：CA466409D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M

公开(公告)号：CA464225A

公开(公告)日：1950-04-04

申请号：CA464225D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M ,  BASCOM FRANCES

公开(公告)号：CA464224A

公开(公告)日：1950-04-04

申请号：CA464224D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M ,  BASCOM FRANCES

公开(公告)号：CA462559A

公开(公告)日：1950-01-17

申请号：CA462559D

Applicant: STANDARD OIL DEV CO

Inventor： VANDERBILT BYRON M ,  HOWE RALPH F