公开(公告)号：EP2633008B1

公开(公告)日：2019-03-20

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

公开(公告)号：EP2729009A2

公开(公告)日：2014-05-14

申请号：EP12807881.3

申请日：2012-07-09

Applicant: Stepan Company

Inventor： MALEC, Andrew, D.

IPC: A01N57/20 ,  A01N25/30 ,  A01P13/00

CPC classification number: A01N57/20 ,  A01N25/30 ,  A01N2300/00

Abstract: Aqueous alkali metal glyphosate compositions are disclosed. The compositions comprise an aqueous concentrate of an alkali metal glyphosate, a surfactant blend comprising an etheramine component, and an optional water- miscible solvent. A mixture of the surfactant blend and solvent is gel-free and monophasic. Adjusting the pH of the aqueous concentrate to be within the range of 4.0 to 4.5 surprisingly enables preparation of a highly concentrated aqueous alkali metal glyphosate composition having good elevated temperature stability and a high cloud point. For instance, a 540 g.a.e/L formulation comprising the composition exhibits good stability at 54 °C. Gel-free, monophasic surfactant blends useful in the glyphosate compositions are also disclosed.

公开(公告)号：EP2633008A1

公开(公告)日：2013-09-04

申请号：EP11838497.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C10L1/18

CPC classification number: C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

公开(公告)号：EP2632893A1

公开(公告)日：2013-09-04

申请号：EP11838498.1

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave R. ,  BERNHARDT, Randal J. ,  BROWN, Aaron ,  DAMESHEK, Anatoliy A. ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  NEPRAS, Marshall, J. ,  SKELTON, Patti ,  WHITLOCK, Laura Lee ,  WOLFE, Patrick Shane

IPC: C07C229/00

CPC classification number: C07C219/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K8/922 ,  A61K2800/805 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C231/12 ,  C07C237/16 ,  C07C237/18 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Esteramine compositions and their derivatives are disclosed. The esteramines comprise a reaction product of a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with a tertiary alkanolamine. Derivatives made by quaternizing, sulfonating, alkoxylating, sulfating, and/or sulfitating the esteramines are also disclosed. In one aspect, the ester derivative of the C
10 -C
17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The esteramines and derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

公开(公告)号：EP2576635A1

公开(公告)日：2013-04-10

申请号：EP11787187.1

申请日：2011-05-23

Applicant: Stepan Company

Inventor： LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  TERRY, Michael, R. ,  WOLFE, Patrick, Shane

IPC: C08F8/30

CPC classification number: C09D133/12 ,  C08J5/18 ,  C09D7/63 ,  C09D167/08 ,  C09J167/08 ,  C08K5/20

Abstract: A film may be formed from film forming compositions which comprise at least one carboxamide based coalescing solvent. These coalescing solvents impart equivalent or improved wet-scrub resistance, block resistance, gloss, dirt pick-up resistance and leveling characteristics to the films on a substrate, without contributing to total VOC levels, when replacing conventional coalescing solvents. The present invention also includes a method for forming a film comprising applying a film forming composition comprising polyunsaturated reactive carboxamides to a substrate and curing the film under ambient conditions. The coalescing carboxamide solvents are suitable for paint, latex based caulk, adhesives and floor care applications.

公开(公告)号：EP2841468B1

公开(公告)日：2020-08-26

申请号：EP13781311.9

申请日：2013-03-13

Applicant: Stepan Company

Inventor： ALLEN, David, R. ,  ALONSO, Marcos ,  BEDDAOUI, Mary ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  DONG, Xue, Min ,  GORMAN, Wilma ,  HUTCHISON, John, C. ,  LUEBKE, Gary ,  LUKA, Renee ,  LUXEM, Franz ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  SPAULDING, Chris ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C08F18/20

公开(公告)号：EP2729009B1

公开(公告)日：2019-09-04

申请号：EP12807881.3

申请日：2012-07-09

Applicant: Stepan Company

Inventor： MALEC, Andrew, D.

IPC: C07F9/22 ,  A01N25/30 ,  A01N57/20

公开(公告)号：EP2632271B1

公开(公告)日：2018-12-05

申请号：EP11838510.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  MALEC, Andrew, D. ,  WOLFE, Patrick, Shane

IPC: A01N25/30 ,  A01N57/20 ,  A01P13/00 ,  A01N25/02 ,  A62D1/02 ,  B01F17/00 ,  C07C69/593 ,  C07C231/12 ,  C09K8/00 ,  C07C69/533 ,  C07C303/18 ,  C07C209/12 ,  C11D1/28 ,  C11D1/74 ,  C08G65/26

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous glyphosate formulations comprising a surfactant derived from metathesized natural oil feedstocks are disclosed. The formulations comprise a glyphosate salt, water, and a surfactant derived from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. The surfactant is selected from C10 or C12 amine oxides, C10 or C12 quats, C10, C12, or C16 amidoamines, C10 or C12 amidoamine oxides, C10 imidazoline quats, C10 or C12 amidoamine quats, C10, C12, or C16 betaines, C16 amidoamine betaines, C18 diamidoamines, C18 diamidoamine oxides, C18 diamidoamine diquats, C18 diamidoamine oxide quats, C18 diamidoamine oxide betaines, Cis diamidoamine monobetaines, C18 diamidoamine monobetaine quats, C18 ester amidoamine quats, and amidoamines and their oxidized or quaternized derivatives made from self- or cross-metathesized palm or soybean oil. The surfactants noted above impart substantial stability to highly concentrated glyphosate formulations at, above, and below room temperature and perform as well or better than commercial alternatives.

公开(公告)号：EP3164004A1

公开(公告)日：2017-05-10

申请号：EP15730032.8

申请日：2015-06-09

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  MALEC, Andrew, D.

IPC: A01N25/30 ,  A01P13/00 ,  A01N57/20

Abstract: Agricultural compositions having reduced aquatic toxicity are disclosed. The compositions comprise an agricultural active, a monounsaturated C10-C12 fatty amine ethoxylate, and optionally water. The compositions may further comprise an auxiliary surfactant, a solvent, or both. In certain preferred aspects, the agricultural active is a glyphosate salt. Agricultural compositions comprising a monounsaturated C10-C12 fatty amine ethoxylate have good herbicidal efficacy. Unexpectedly, the monounsaturated C10-C12 fatty amine ethoxylates have reduced aquatic toxicity when compared with their saturated analogs.

Abstract translation: 公开了具有降低的水生毒性的农业组合物。 该组合物包含农用活性成分，单不饱和C10-C12脂肪胺乙氧基化物和任选的水。 该组合物可以进一步包含辅助表面活性剂，溶剂或两者。 在某些优选的方面，农业活性成分是草甘膦盐。 包含单不饱和C10-C12脂肪胺乙氧基化物的农业组合物具有良好的除草效力。 出乎意料的是，与其饱和类似物相比，单不饱和C10-C12脂肪胺乙氧基化物具有降低的水生毒性。

公开(公告)号：EP2632890B8

公开(公告)日：2017-04-12

申请号：EP11838500.4

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C69/533 ,  C07C69/593 ,  C11D1/28 ,  C11D1/74 ,  B01F17/00

CPC classification number: C11D1/66 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A01N57/20 ,  A61K8/41 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C04B28/02 ,  C04B28/14 ,  C04B38/10 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/69 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/17 ,  C08K5/20 ,  C08K5/32 ,  C08K5/42 ,  C09D5/00 ,  C09D7/63 ,  C09K8/00 ,  C09K8/54 ,  C09K8/584 ,  C09K15/28 ,  C09K2208/32 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C11/02

Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.

Abstract translation: 公开了由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物制成的脂肪胺组合物。 在另一方面，公开了通过使由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与氨基烷基取代的叔胺反应制得的脂肪酰氨基胺。 脂肪胺或酰胺胺有利地被磺化，硫酸化，氧化或还原。 在其它方面，酯衍生物是通过天然油或通过天然油与烯烃的交叉复分解制备的不饱和甘油三酯的自分解制备的改性甘油三酯。