公开(公告)号：JP6012691B2

公开(公告)日：2016-10-25

申请号：JP2014228521

申请日：2014-11-11

Applicant: プロイオニック ゲーエムベーハー

Inventor： カーブ,ローランド

IPC: C07F5/02 ,  C01B3/00

CPC classification number: C01B3/08 ,  B01J41/09 ,  C01B3/001 ,  C01B3/065 ,  C07C211/63 ,  C07F9/5407 ,  H01M8/0606 ,  C01B6/23 ,  Y02E60/324 ,  Y02E60/327 ,  Y02E60/362

公开(公告)号：US20160347758A1

公开(公告)日：2016-12-01

申请号：US15170677

申请日：2016-06-01

Applicant: INDIANA UNIVERSITY RESEARCH & TECHNOLOGY CORPORATION

Inventor： Amar Flood ,  Brandon E. Hirsch ,  Semin Lee ,  Steven L. Tait ,  James Dobscha

IPC: C07D487/22 ,  C02F1/42 ,  B01D15/36 ,  B01J41/04 ,  B01J41/08

CPC classification number: C07D487/22 ,  B01D15/363 ,  B01J20/22 ,  B01J41/04 ,  B01J41/09 ,  B01J45/00 ,  B01J47/12 ,  C02F1/42 ,  C02F1/683 ,  C02F2001/422 ,  C02F2101/12 ,  C02F2103/007

Abstract: Disclosed herein are compositions of tricarbazole triazolophane (tricarb) of Formulas (I), (II) and (III): wherein R of Formula (I) is selected from a group consisting of alkyl (for example, C6-C18), alkyl-substituted phenyl derivatives, and substituted glycol derivatives, among others, or a combination thereof, and R, R′ and R″ of Formulas (II) and (III) are independently selected from a group consisting of alkyl (for example, C6 to C18), alkyl-substituted phenyl derivatives, and substituted glycol derivatives, or a combination thereof. The disclosure presents examples of thin films composed of the same as well as methods of binding anions from the same.

Abstract translation: 其中式（I）的R选自烷基（例如C 6 -C 18），烷基取代的苯基衍生物和取代的二醇衍生物等，或其组合，R，R'和R 式（II）和（III）的化合物独立地选自烷基（例如C 6至C 18），烷基取代的苯基衍生物和取代的二醇衍生物或其组合。 本发明公开了由相同的薄膜组成的实例以及从其组合阴离子的方法。

公开(公告)号：US09486799B2

公开(公告)日：2016-11-08

申请号：US13610495

申请日：2012-09-11

Applicant: Christopher A. Pohl

Inventor： Christopher A. Pohl

IPC: B01J41/08 ,  B01J20/32 ,  B01J41/20 ,  B01D15/36 ,  B01J20/288

CPC classification number: B01J41/20 ,  B01D15/363 ,  B01J20/288 ,  B01J20/3251 ,  B01J20/3289 ,  B01J41/09

Abstract: Treatment of anion exchange materials containing hydroxyl containing moieties in the beta position relative to the quaternary center in the hydroxide form with glycidol substantially alters the selectivity of the anion exchange material. Furthermore, sequential treatments of first a hydroxide containing solution to put the anion exchange material in the hydroxide form followed by treatment with glycidol in an alternating sequence progressively changes selectivity in a predictable manner allowing facile manipulation of selectivity. Unique to the selectivities achievable with this chemistry is the ability to reverse the elution order of sulfate and carbonate. With all other known systems, carbonate elutes ahead of sulfate and sometimes compromises the ability to quantitate sulfate. With glycidol treatment, carbonate can be moved after sulfate which eliminates interference issues for samples containing significantly more carbonate than sulfate. This modification is useful for columns operated with a hydroxide or carbonate eluent system.

Abstract translation: 含有羟基的阴离子交换材料相对于具有缩水甘油的氢氧化物形式的季中心的β位置的处理基本上改变了阴离子交换材料的选择性。 此外，首先连续处理含氢氧化物溶液以将阴离子交换材料置于氢氧化物形式，然后以交替的顺序用缩水甘油处理，以可预测的方式逐渐改变选择性，从而容易地操纵选择性。 通过该化学可以实现的选择性独特的是反转硫酸盐和碳酸盐的洗脱顺序的能力。 使用所有其他已知的系统，碳酸盐在硫酸盐之前洗脱，有时会损害硫酸盐的定量能力。 通过缩水甘油处理，碳酸盐可以在硫酸盐之后移动，消除了含有比硫酸盐显着更多的碳酸盐的样品的干扰问题。 该修饰对于用氢氧化物或碳酸盐洗脱液系统操作的柱是有用的。

公开(公告)号：US09139533B2

公开(公告)日：2015-09-22

申请号：US13980988

申请日：2012-01-26

Applicant: Mitsuru Kondo

Inventor： Mitsuru Kondo

IPC: C02F1/42 ,  C07D235/20 ,  C07F1/00

CPC classification number: C07D235/20 ,  B01J41/09 ,  B01J47/018 ,  C02F1/42 ,  C02F2001/422 ,  C07F1/005

Abstract: The present invention provides a capsule-type compound consisting of: a capsule-type divalent cation consisting of a capsule framework represented by the following formula (1) and a sulfate ion (SO42−) encapsulated in the capsule framework; and a sulfate ion (SO42−) as a counter ion to the capsule-type divalent cation. In the formula (1), R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12, and R13 each independently represent a hydrogen atom or a methyl group; and M1 and M2 each independently represent Cu2+, Fe2+, Ni2+, Co2+, or Zn2+.

Abstract translation: 本发明提供一种胶囊型化合物，其由以下通式（1）所示的胶囊骨架和胶囊框架内的硫酸根离子（SO42-）构成的胶囊型二价阳离子， 和作为胶囊型二价阳离子的抗衡离子的硫酸根离子（SO42-）。 式（1）中，R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11，R 12和R 13各自独立地表示氢原子或甲基。 M1和M2各自独立地表示Cu2 +，Fe2 +，Ni2 +，Co2 +或Zn2 +。

公开(公告)号：US20130237692A1

公开(公告)日：2013-09-12

申请号：US13785632

申请日：2013-03-05

Applicant: Jiali Liao ,  Russell Frost

Inventor： Jiali Liao ,  Russell Frost

IPC: B01J41/20 ,  C07K1/16

CPC classification number: B01J41/20 ,  B01D15/265 ,  B01D15/30 ,  B01D15/327 ,  B01D15/363 ,  B01D15/3847 ,  B01J20/22 ,  B01J20/267 ,  B01J20/28016 ,  B01J20/281 ,  B01J20/286 ,  B01J20/288 ,  B01J20/289 ,  B01J20/3208 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3253 ,  B01J20/3265 ,  B01J20/3293 ,  B01J41/04 ,  B01J41/09 ,  B01J2220/52 ,  C07K1/14 ,  C07K1/16 ,  C07K1/165 ,  C07K16/00 ,  G01N30/482

Abstract: Anion exchange-hydrophobic mixed mode ligands and methods of their use are provided.

Abstract translation: 提供了阴离子交换 - 疏水混合模式配体及其使用方法。

公开(公告)号：US3672131A

公开(公告)日：1972-06-27

申请号：US3672131D

申请日：1970-01-15

Applicant: HALASZ ISTVAN

Inventor： HALASZ ISTVAN

IPC: B01J20/22 ,  B01J20/32 ,  B01J31/02 ,  B01J39/16 ,  B01J41/08 ,  C01B33/113 ,  C01G49/02 ,  B01D15/08

CPC classification number: C01G49/02 ,  B01J20/103 ,  B01J20/22 ,  B01J20/28004 ,  B01J20/28019 ,  B01J20/28057 ,  B01J20/286 ,  B01J20/29 ,  B01J20/3071 ,  B01J20/3078 ,  B01J20/3092 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3248 ,  B01J20/3251 ,  B01J20/3272 ,  B01J20/3289 ,  B01J31/02 ,  B01J31/0229 ,  B01J31/0232 ,  B01J31/0235 ,  B01J31/0237 ,  B01J31/0259 ,  B01J31/0271 ,  B01J39/17 ,  B01J41/09 ,  B01J2220/54 ,  B01J2220/58 ,  C01B33/113 ,  C01P2006/12

Abstract: Stationary phases for chromatographic ion exchange or catalysis produced by esterification of solid substances having acidic OH groups at the surface as Components I with organic compounds as Components II. The specific surface area of Components I is above 100 cm2/g and Components II each have at least one hetero atom in their molecules, disregarding the oxygen connected to a carbon atom in the molecule for esterification with the acid OH group in Component I. By hetero-atoms is meant an atom other than carbon and hydrogen.

Abstract translation: 通过酯化具有酸性OH基团的固体物质在表面作为组分I与有机化合物作为组分II产生的色谱离子交换或催化的固定相。 组分I的比表面积高于100cm 2 / g，组分II在其分子中各自具有至少一个杂原子，而不考虑与分子中与碳原子连接的氧，以与组分I中的酸OH基进行酯化。通过 杂原子是指碳和氢以外的原子。

公开(公告)号：US3426073A

公开(公告)日：1969-02-04

申请号：US3426073D

申请日：1966-03-30

Applicant: MONSANTO CO

Inventor： BIRUM GAIL H ,  MATTHEWS CLIFFORD N

IPC: B01J41/08 ,  C07F9/535 ,  C07F9/54 ,  C08K5/50 ,  C08K5/5397 ,  D06M13/285 ,  C07F9/50 ,  A61K27/00 ,  C11D1/60

CPC classification number: C07F9/54 ,  B01J41/09 ,  C07F9/5352 ,  C07F9/5449 ,  C08K5/50 ,  C08K5/5397 ,  D06M13/285

公开(公告)号：WO0138227A3

公开(公告)日：2001-11-15

申请号：PCT/EP0011605

申请日：2000-11-22

Applicant: AMERSHAM PHARM BIOTECH AB ,  JOHANSSON BO LENNART ,  ANDERSSON MIKAEL ,  GUSTAVSSON JAN ,  BELEW MAKONNEN ,  MALOISEL JEAN LUC

Inventor： JOHANSSON BO-LENNART ,  ANDERSSON MIKAEL ,  GUSTAVSSON JAN ,  BELEW MAKONNEN ,  MALOISEL JEAN-LUC

IPC: B01J20/281 ,  B01D15/32 ,  B01J20/34 ,  B01J41/04 ,  B01J41/08 ,  B01J41/12 ,  B01J41/20 ,  B01J49/00 ,  C02F1/28 ,  C02F1/42 ,  C07K1/18 ,  B01J41/00

CPC classification number: B01J41/20 ,  B01D15/327 ,  B01J41/09 ,  C02F1/42

Abstract: A method for the removal of a substance carrying a negative charge and being present in an aqueous liquid (I). The method comprises the steps of: (i) contacting the liquid with a matrix carrying a plurality of ligands comprising a positively charged structure and a hydrophobic structure, and (ii) desorbing the substance. The characterizing feature is that (I) each of said ligands together with a spacer has the formula: -- SP---[Ar-R1-N (R2R3R4)] where (A) [Ar-R1-N (R2R3R4)] represents a ligand a) Ar is an aromatic ring, b) R1 is [(L)nR'1]m where n and m are integers selected amongst zero or 1; L is amino nitrogen, ether oxygen or thioether sulphur; R'1 is a linker selected among 1) hydrocarbon groups; 2) -C(=NH)-; c) R2-4 are selected among hydrogen and alkyls; (B) SP is a spacer providing a carbon or a heteroatom directly attached to Ar-R1-N (R2R3R4); (C) --- represents that SP replaces a hydrogen in (Ar-R1-N (R2R3R4); (D) -- represents binding to the matrix; and (II) desorption. There is also described (a) anion-exchangers having high breakthrough capacities, (b) a screening method and (c) a desalting protocol.

Abstract translation: 一种用于去除携带负电荷并存在于水性液体（I）中的物质的方法。 该方法包括以下步骤：（i）使液体与承载包含带正电结构和疏水结构的多个配体的基质接触，和（ii）解吸该物质。 其特征在于，（I）每个所述配位体与间隔基一起具有下式：-SP --- [Ar-R 1 -N +（R 2 R 3 R 4）]其中（A）[Ar-R 1 -N +（R2R3R4）]表示配体a）Ar是芳香环，b）R1是[（L）nR'1] m，其中n和m是选自零或1的整数; L为氨基氮，醚氧或硫醚硫; R'1是选自1）烃基的连接体; 2）-C（= NH） - ; c）R2-4选自氢和烷基; （B）SP是提供直接与Ar-R 1 -N +（R 2 R 3 R 4）连接的碳或杂原子的间隔基; （C）---表示SP替代（Ar-R1-N +（R2R3R4）中的氢;（D） - 表示与基质的结合;和（II）解吸，还描述了（a） 具有高突破能力的阴离子交换剂，（b）筛选方法和（c）脱盐方案。

公开(公告)号：WO1991000145A1

公开(公告)日：1991-01-10

申请号：PCT/SE1990000415

申请日：1990-06-14

Applicant: PHARMACIA AB ,  ENGSTRÖM, Björn

Inventor： PHARMACIA AB

IPC: B01J39/06

CPC classification number: B01J41/20 ,  B01J20/3212 ,  B01J20/3255 ,  B01J41/09

Abstract: Anion exchangers for chromatographic separation, containing two positive charges at a distance of two atoms from each other. The invention contemplates in particular anion exchangers containing two quaternary amino groups.

Abstract translation: 用于色谱分离的阴离子交换剂，在两个原子的距离处包含两个正电荷。 本发明尤其涉及含有两个季氨基的阴离子交换剂。

公开(公告)号：US12128394B2

公开(公告)日：2024-10-29

申请号：US16768344

申请日：2018-12-04

Applicant: The University of North Carolina at Charlotte

Inventor： Jordan Poler ,  James E. Amburgey ,  Abhispa Sahu ,  Tim B. Eldred

IPC: B01J41/09 ,  B01J41/05 ,  B01J41/07 ,  B01J41/10 ,  B01J47/016 ,  B01J49/07 ,  B01J49/57 ,  C02F1/42 ,  C02F101/34 ,  C02F101/36

CPC classification number: B01J41/09 ,  B01J41/05 ,  B01J41/07 ,  B01J41/10 ,  B01J47/016 ,  B01J49/07 ,  B01J49/57 ,  C02F1/42 ,  C02F2001/422 ,  C02F2101/34 ,  C02F2101/36

Abstract: In one aspect, separation media are described herein operable for removing one or more water contaminants, including NOM, fluorinated chemicals, and/or derivatives thereof. Briefly, a separation medium comprises a silica-containing granular support; and an oligomeric stationary phase forming a film on individual grains of the granular support. In some embodiments, the oligomeric stationary phase comprises oligomeric chains covalently bound to the individual grains.