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    Verfahren und Mittel zur Phosphorylierung
    23.
    发明授权
    Verfahren und Mittel zur Phosphorylierung 失效

    公开(公告)号：EP0195277B1

    公开(公告)日：1989-06-21

    申请号：EP86102311.7

    申请日：1986-02-22

    Applicant: HOECHST AKTIENGESELLSCHAFT

    Inventor： Engels, Joachim, Prof. Dr. ,  Uhlmann, Eugen, Dr.

    IPC: C07F9/24 ,  C07F9/141 ,  C07F9/201 ,  C07F9/65

    CPC classification number: C07H21/00 ,  C07F9/146 ,  C07F9/2408 ,  C07F9/2429 ,  C07F9/26

    Abstract: for the Contracting States : BE, CH, DE, FR, GB, IT, LI, LU, NL, SE 1. A process for the preparation of compounds of the formula I see diagramm : EP0195277,P15,F1 in which Kat represents one molar equivalent of a cation, R is an organic radical which carrier no further phosphorylatable hydrogen atoms, X represents oxygen, sulfur or selenium, Z represents oxygen, sulfur or -NH- and n denotes at least 1, by phosphorylating a compound of the formula II R-(-Z-H)n with at least n moles of a phosphorylating reagent, oxidizing the resulting compound and liberating the compound of the formula I by means of bases, characterized by employing, in the presence of a weak acid, a phosphorylating reagent of the formula III see diagramm : EP0195277,P15,F2 in which R**1 represents a group ofthe formula IIIa or IIIb see diagramm : EP0195277,P15,F3 R**5, R**6 and R**7, which can be identical or different, denote hydrogen or methyl, R**8 denotes a group of the formula IIIc, IIId or IIIe or cyano or Ar see diagramm : EP0195277,P15,F4 R**10 denotes lower alkyl or Ar, G, which can be identical or different, denotes C or N, but at least one G represents N, Ar denotes phenyl which can be substituted by 1 to 5 identical or different substituents belonging to the series chlorine, fluorine, nitro and cyano or, in addition to the electron-withdrawing substituents, can be substituted by one or two lipophilic radicals, y is 0,1 or 2, R**9 denotes a group of the formula IIIf or IIIg see diagramm : EP0195277,P16,F5 Y denotes identical or different substituents belonging to the series chlorine, bromine or iodine, R**2 can have a meaning of R**1 and is then identical or different or denotes alkylhaving 1 to 4 carbon atoms, a group of the formula IIIh -CH2 -Ar or Ar, if the latter can be split off more readily than R**1 by alkalis, R**5 and R**8 together represent a group of the formula IIIi see diagramm : EP0195277,P16,F6 and R**1 also represents methyl if R**2 is also methyl, and R**3 and R**4, which can be identical or different, denote alkyl having 1 to 8 carbon atoms, cycloakyl having 5 to 12 carbon atoms, benzyl or phenyl or, together with the nitrogen atom to which they are attached, denote a saturated or unsaturated heterocyclic ring which can, if appropriate, contain further heteroatoms and substituents, and oxidizing the resulting compound ofthe formula IV see diagramm : EP0195277,P16,F7 in which R**1, R**2, R, Z and n have the meanings mentioned to give the compound of the formula V see diagramm : EP0195277,P16,F8 in which n, R**1, R**2, X, Z and R have the meanings mentioned. for the Contracting State : Austria 1. A process for the preparation of compounds of the formula I see diagramm : EP0195277,P17,F1 in which Kat represents one molar equivalent of a cation, R is an organic radical which carrier no further phosphorylatable hydrogen atoms, X represents oxygen, sulfur or selenium, Z represents oxygen, sulfur or -NH- and n denotes at least 1, by phosphorylating a compound of the formula II R-(-Z-H)n with at least n moles of a phosphorylating reagent, oxidizing the resulting compound and liberating the compound of the formula I by means of bases, characterized by employing, in the presence of a weak acid, a phosphorylating reagent of the formula III see diagramm : EP0195277,P17,F2 in which R**1 represents a group of the formula IIIa or IIIb see diagramm : EP0195277,P17,F3 R**5, R**6 and R**7, which can be identical or different, denote hydrogen or methyl, R**8 denotes a group of the formula IIIc, IIId or IIIe or cyano or Ar see diagramm : EP0195277,P17,F4 R**10 denotes alkyl having 1 to 4 carbon atoms or Ar, G, which can be identical or different, denotes C or N, but at least one G represents N, AR denotes phenyl which can be substituted by 1 to 5 identical or different substituents belonging to the series chlorine, fluorine, nitro and cyano or, in addition to the electron-withdrawing substituents, can be substituted by one or two lipophilic radicals, y is 0, 1 or 2, R**9 denotes a group of the formula IIIf or IIIg see diagramm : EP0195277,P18,F5 Y denotes identical or different substituents belonging to the series chlorine, bromine or iodine, R**2 can have a meaning of R**1 and is then identical or different, or denotes alkyl having 1 to 4 carbon atoms, a group of the formula IIIh -CH2 -Ar or Ar, if the latter can be split off more readily than R**1 by alkal is, R**5 and R**8 together represent a group of the formula IIIi see diagramm : EP0195277,P18,F6 and R**1 also represents methyl if R**2 is also methyl, and R**3 and R**4, which can be identical or different, denote alkyl having 1 to 8 carbon atoms, cycloalkyl having 5 to 12 carbon atoms, benzyl or phenyl or, together with the nitrogen atom to which they are attached, denote a saturated or unsaturated heterocyclic ring which can, if appropriate, contain further heteroatoms and substituents, and oxidizing the resulting compound of the formula IV see diagramm : EP0195277,P18,F7 in which R**1, R**2, R, Z and n have the meanings mentioned to give the compound of the formula V see diagramm : EP0195277,P18,F8 in which n, R**1, R**2, X, Z and R have the meanings mentioned.

    ASYMMETRIC SILOXY COMPOUND
    25.
    发明专利
    ASYMMETRIC SILOXY COMPOUND 失效

    公开(公告)号：JPH107682A

    公开(公告)日：1998-01-13

    申请号：JP5155497

    申请日：1997-03-06

    Applicant: GOODYEAR TIRE & RUBBER

    Inventor： AGOSTINI GIORGIO ,  THIERRY FLORENT EDME MATERNE ,  MARC JUNIO ,  VISEL FRIEDRICH ,  FRANK UWE ERNST

    IPC: B60C1/00 ,  C07F7/02 ,  C07F7/18 ,  C07F7/28 ,  C07F9/165 ,  C07F9/201 ,  C07F9/535 ,  C08K3/36 ,  C08K5/54 ,  C08K5/548 ,  C08K5/56 ,  C08L9/06

    Abstract: PROBLEM TO BE SOLVED: To obtain the subject new asymmetric siloxy compound capable of giving improved physical properties to rubbers as a reactive coupling agent used between the rubbers and silica filler, etc., and useful for producing tires, belts, hoses, etc. SOLUTION: A new siloxy compound of formula I [R -R are each a 1-8C alkoxy; R is a 1-15C alkylene, a (substituted) 6-10C arylene; R is a 1-15C alkylene, a (substituted) 6-10C arylene; (y) is 2-8; X is a group of formula II, etc.] or formula III [(z) is 1-8; W is a group of formula IV, etc.]. The compound of formula I or III is useful as a reactive coupling agent used between rubbers and silica filler, etc., and can give improved physical properties to the rubbers. The siloxy compound is obtained by condensing a trialkoxysilyl compound of formula V with a compound of formula VI or a compound of formula VII (Z is Ti, Al, Zr).

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