公开(公告)号：US20160339416A1

公开(公告)日：2016-11-24

申请号：US15227190

申请日：2016-08-03

Applicant: SK INNOVATION CO., LTD.

Inventor： Sang Il LEE ,  Do Woan KIM ,  Jae Hyun KOH ,  Seung Hoon OH ,  Hee Jung JEON ,  Sang Heup MOON ,  A Ra CHO ,  Young Moo PARK

IPC: B01J31/02 ,  B01J31/34 ,  C10G45/08 ,  B01J23/882 ,  B01J37/02 ,  B01J37/08 ,  B01J31/38 ,  B01J31/28

CPC classification number: B01J31/0209 ,  B01J23/88 ,  B01J23/882 ,  B01J23/888 ,  B01J31/0201 ,  B01J31/0207 ,  B01J31/0208 ,  B01J31/12 ,  B01J31/2208 ,  B01J31/2213 ,  B01J31/2234 ,  B01J31/34 ,  B01J31/38 ,  B01J35/023 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0219 ,  B01J37/024 ,  B01J37/06 ,  B01J37/088 ,  B01J37/18 ,  B01J37/20 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  C10G45/08

Abstract: Embodiments of the invention relate to a hydroprocessing catalyst including (i) one or more hydrogenation metal components selected from a group consisting of a VIB group metal, a VIIB group metal, and a VIII group metal, and (ii) an organic compound expressed by the formula: R1COCH2COR2 (wherein, R1 and R2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy), or an organometallic compound expressed by the formula: X(R1COCH1COR2)n (wherein, X is selected from a group consisting of VIB group metal, VIIB group metal and VIII group metal, R1 and R2 are the same or different from each other, and are one or more groups selected from a group consisting of C1 to C12 alkyl, C6 to C12 allyl, C1 to C12 alkoxy and hydroxy, and n is an integer of 1 to 6).

Abstract translation: 本发明的实施方案涉及一种加氢处理催化剂，其包括（i）一种或多种选自由VIB族金属，VIIB族金属和VIII族金属组成的组的氢化金属组分，和（ii）由 R 1 COCH 2 COR 2（其中，R 1和R 2彼此相同或不同，并且是选自C 1至C 12烷基，C 6至C 12烯丙基，C 1至C 12烷氧基和羟基的一个或多个基团），或 由下式表示的有机金属化合物：X（R1COCH1COR2）n（其中，X选自VIB族金属，VIIB族金属和VIII族金属，R1和R2相同或不同，分别为 一个或多个选自C 1至C 12烷基，C 6至C 12烯丙基，C 1至C 12烷氧基和羟基的基团，n为1至6的整数。

公开(公告)号：US09453088B2

公开(公告)日：2016-09-27

申请号：US12735278

申请日：2008-12-22

Applicant: Gianni Collina ,  Ofelia Fusco

Inventor： Gianni Collina ,  Ofelia Fusco

IPC: C08F4/20 ,  C08F110/06 ,  B01J27/135 ,  B01J27/138 ,  B01J31/02 ,  B01J31/14 ,  B01J31/26 ,  B01J31/38

CPC classification number: C08F110/06 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F4/651 ,  C08F4/6492 ,  C08F2500/12 ,  C08F2500/18

Abstract: Prepolymerized catalyst component for the polymerization of olefins CH2═CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, having average particle size equal to or lower than 30 μm comprising a solid catalyst component comprising magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other one being selected from esters of aromatic mono or dicarboxylic acids, said solid catalyst component being prepolymerized with an olefin, having from 2 to 10 carbon atoms, to such an extent that the amount of the olefin prepolymer is equal to or lower than 50 g per g of solid catalyst component.

Abstract translation: 用于烯烃CH 2 = CHR聚合的预聚合催化剂组分，其中R是氢或具有1-12个碳原子的烃基，平均粒度等于或小于30μm，包括包含卤化镁的固体催化剂组分，钛化合物 具有至少一个Ti-卤键和至少两个电子给体化合物，其中一个选自1,3-二醚，另一个选自芳族单或二羧酸的酯，所述固体催化剂组分与烯烃预聚合 具有2至10个碳原子的烯烃预聚物的量等于或低于每克固体催化剂组分50克的程度。

公开(公告)号：US20150337221A1

公开(公告)日：2015-11-26

申请号：US14816531

申请日：2015-08-03

Applicant: SHELL OIL COMPANY

Inventor： Alexei Grigorievich GABRIELOV ,  Ed GANJA ,  Theofiel MEURIS ,  Maxim Vasilievich OVCHINNIKOV

IPC: C10G45/08

CPC classification number: C10G45/08 ,  B01J21/04 ,  B01J23/75 ,  B01J23/755 ,  B01J23/88 ,  B01J23/882 ,  B01J23/883 ,  B01J27/19 ,  B01J31/02 ,  B01J31/0201 ,  B01J31/0235 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1066 ,  B01J37/0203 ,  B01J37/0207 ,  C10G45/06 ,  C10G2300/1044 ,  C10G2300/1051 ,  C10G2300/1055 ,  C10G2300/1059 ,  C10G2300/1088 ,  C10G2300/301

Abstract: A composition having a substantial or material absence of or no phosphorous and comprising a support material, a metal compound and either a hydrocarbon oil or a polar additive or a combination of both a hydrocarbon oil and polar additive. The polar additive has particularly defined properties including having a dipole moment of at least 0.45. The composition is useful in the hydroprocessing of hydrocarbon feedstocks, and it is especially useful in the hydrotreating of vacuum gas oils and petroleum resid feedstocks.

Abstract translation: 具有实质上或物质上不存在或不含磷的组合物，并且包含载体材料，金属化合物和烃油或极性添加剂或烃油和极性添加剂的组合。 极性添加剂具有特别限定的性质，包括偶极矩至少为0.45。 该组合物可用于烃类原料的加氢处理，特别适用于真空瓦斯油和石油渣油原料的加氢处理。

公开(公告)号：US20150306587A1

公开(公告)日：2015-10-29

申请号：US14442988

申请日：2013-09-27

Applicant: AGILENT TECHNOLOGIES, INC.

Inventor： Ta-Chen Wei ,  William E. Barber ,  Kunqiang Jiang

IPC: B01J31/02 ,  B01J20/28 ,  B01J37/08 ,  B01J20/30 ,  B01J35/10 ,  B01J20/10 ,  B01J20/22

CPC classification number: B01J31/0201 ,  B01J20/103 ,  B01J20/22 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/28059 ,  B01J20/28061 ,  B01J20/28083 ,  B01J20/28085 ,  B01J20/28088 ,  B01J20/283 ,  B01J20/3078 ,  B01J35/1009 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/08 ,  C01B37/005 ,  C01B37/02 ,  C04B35/14 ,  C04B38/00 ,  C04B2111/0081 ,  C04B2235/483 ,  C04B38/0645

Abstract: The invention provides superficially porous metal oxide or hybrid metal oxide monoliths with ordered pore structures. The superficially porous hybrid silica monoliths of the invention provide several major advantages over existing silica monoliths. When used in chromatography, the superficially porous hybrid silica monoliths of the invention deliver fast separation at very low back pressure and possess superb pH stability and much improved mechanical strength.

Abstract translation: 本发明提供具有有序孔结构的表面多孔金属氧化物或混合金属氧化物整料。 本发明的表面多孔的混合二极石整体提供了优于现有二氧化硅整料的几个主要优点。 当用于色谱法时，本发明的表面多孔混合二氧化硅整体在非常低的背压下提供快速分离并且具有极好的pH稳定性和大大提高的机械强度。

公开(公告)号：US20150087863A1

公开(公告)日：2015-03-26

申请号：US14561800

申请日：2014-12-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Werner M.A. Grootaert ,  Kim M. Vogel ,  Dennis E. Vogel

IPC: C08F4/00

CPC classification number: C08F4/00 ,  B01J27/14 ,  B01J31/0201 ,  B01J31/0205 ,  B01J31/0234 ,  B01J31/0239 ,  B01J31/0268 ,  B01J2231/14 ,  C07C259/06 ,  C08F214/18 ,  C08F214/184 ,  C08K5/0025 ,  C08K5/05 ,  C08K5/19 ,  C08K5/29 ,  C08K5/315 ,  C08K5/50 ,  C08L27/12 ,  C08L27/18 ,  C08L2205/02

Abstract: Provided is a catalyst composition suitable for curing a fluoroelastomer, the catalyst composition comprising an anion of Formula III: wherein each Rf independently is selected from R—CF2 and a perfluoroalkyl group having from 1 to 8 carbon atoms. R is selected from H, a halogen, an alkyl group having up to 8 carbon atoms, an aryl group having up to 8 carbon atoms, and a cycloalkyl group having up to 8 carbon atoms. The subscript n is a positive integer. The catalyst composition is free of hydrocarbon containing alcohol. In specific instances, Rf may be CF3.

Abstract translation: 提供了适用于固化含氟弹性体的催化剂组合物，该催化剂组合物包含式III的阴离子：其中每个Rf独立地选自R-CF2和具有1至8个碳原子的全氟烷基。 R选自H，卤素，具有至多8个碳原子的烷基，具有至多8个碳原子的芳基和具有至多8个碳原子的环烷基。 下标n为正整数。 催化剂组合物不含含烃的醇。 在具体情况下，Rf可以是CF 3。

公开(公告)号：US08835587B2

公开(公告)日：2014-09-16

申请号：US14049558

申请日：2013-10-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Donna J. Crowthers ,  Peijun Jiang ,  Rainer Kolb

IPC: C08F210/02 ,  C08F210/06 ,  B01J31/22 ,  B01J31/16 ,  C08F210/16 ,  C08F10/06 ,  B01J31/14 ,  C08F4/6592 ,  B01J31/02 ,  C08F4/659 ,  C08F110/06

CPC classification number: C08F210/06 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0255 ,  B01J31/146 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2231/122 ,  B01J2531/0269 ,  B01J2531/0297 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/06 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  Y10S526/943 ,  Y10T442/60 ,  C08F4/65908 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/03 ,  C08F2500/17

Abstract: Provided are catalyst systems, processes for polymerizing one or more olefins, polymers resulting therefrom, and articles prepared from such polymers. The processes comprise contacting under polymerization conditions one or more olefin monomers, preferably propylene, with a catalyst system comprising a transition metal compound and an activator of the formula (1) or (2) as described herein. The polymer compositions described herein exhibit advantageously narrow composition distributions and high melting points in comparison to conventional polymers having the same comonomer content. The polymers described herein exhibit improved properties, e.g., pellet stability, impact properties, heat seal properties, and structural integrity in film and fabricated parts applications.

Abstract translation: 提供催化剂体系，聚合一种或多种烯烃的方法，由此产生的聚合物和由这些聚合物制备的制品。 该方法包括在聚合条件下使一种或多种烯烃单体，优选丙烯与包含如本文所述的过渡金属化合物和式（1）或（2）的活化剂的催化剂体系接触。 与具有相同共聚单体含量的常规聚合物相比，本文所述的聚合物组合物显示出有限的组成分布和高熔点。 本文所述的聚合物表现出改进的性能，例如膜和制造零件应用中的颗粒稳定性，冲击性能，热封性能和结构完整性。

公开(公告)号：US08609572B2

公开(公告)日：2013-12-17

申请号：US11794772

申请日：2006-01-04

Applicant: Martyn J. Earl ,  Kenneth R. Seddon ,  Stewart Forsyth ,  Ute Frohlich ,  Nimal Gunaratne ,  Suhas Katdare

Inventor： Martyn J. Earl ,  Kenneth R. Seddon ,  Stewart Forsyth ,  Ute Frohlich ,  Nimal Gunaratne ,  Suhas Katdare

IPC: B01J31/00

CPC classification number: C07C217/08 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0225 ,  B01J31/0234 ,  B01J31/0237 ,  B01J31/0277 ,  B01J31/0278 ,  B01J31/0282 ,  B01J31/0284 ,  B01J31/0287 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/0291 ,  B01J31/2208 ,  B01J2231/341 ,  B01J2231/342 ,  B01J2231/346 ,  B01J2231/348 ,  B01J2231/349 ,  B01J2231/4261 ,  B01J2231/645 ,  B01J2231/72 ,  B01J2531/824 ,  B01J2531/90 ,  C07B61/00 ,  C07C45/512 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C211/63 ,  C07D213/73 ,  C07D233/54 ,  C07D303/32 ,  Y02P20/542 ,  C07C47/228 ,  C07C49/603 ,  C07C49/647 ,  C07C49/637 ,  C07C49/203 ,  C07C49/597 ,  C07C49/497 ,  C07C49/707 ,  C07C49/17 ,  C07C49/403

Abstract: Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterized in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

Abstract translation: 在碱催化的化学反应中使用离子液体作为溶剂，其中离子液体由至少一种阳离子和至少一种阴离子组成，其特征在于离子液体的阳离子包含正电荷部分和碱性 部分，其中这种离子液体可以用作化学反应的促进剂或催化剂。

公开(公告)号：US08580902B2

公开(公告)日：2013-11-12

申请号：US12541752

申请日：2009-08-14

Applicant: Donna J. Crowther ,  Peijun Jiang ,  Rainer Kolb

Inventor： Donna J. Crowther ,  Peijun Jiang ,  Rainer Kolb

IPC: C08F4/6592 ,  C08F4/643 ,  C08F210/06

CPC classification number: C08F210/06 ,  B01J31/0201 ,  B01J31/0235 ,  B01J31/0239 ,  B01J31/0254 ,  B01J31/0255 ,  B01J31/146 ,  B01J31/1608 ,  B01J31/1616 ,  B01J31/2295 ,  B01J2231/122 ,  B01J2531/0269 ,  B01J2531/0297 ,  B01J2531/40 ,  B01J2531/48 ,  B01J2531/49 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65927 ,  C08F10/06 ,  C08F110/06 ,  C08F210/02 ,  C08F210/16 ,  Y10S526/943 ,  Y10T442/60 ,  C08F4/65908 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/03 ,  C08F2500/17

Abstract: Provided are catalyst systems, processes for polymerizing one or more olefins, polymers resulting therefrom, and articles prepared from such polymers. The processes comprise contacting under polymerization conditions one or more olefin monomers, preferably propylene, with a catalyst system comprising a transition metal compound and an activator of the formula (1) or (2) as described herein. The polymer compositions described herein exhibit advantageously narrow composition distributions and high melting points in comparison to conventional polymers having the same comonomer content. The polymers described herein exhibit improved properties, e.g., pellet stability, impact properties, heat seal properties, and structural integrity in film and fabricated parts applications.

Abstract translation: 提供催化剂体系，聚合一种或多种烯烃的方法，由此产生的聚合物和由这些聚合物制备的制品。 该方法包括在聚合条件下使一种或多种烯烃单体，优选丙烯与包含如本文所述的过渡金属化合物和式（1）或（2）的活化剂的催化剂体系接触。 与具有相同共聚单体含量的常规聚合物相比，本文所述的聚合物组合物显示出有限的组成分布和高熔点。 本文所述的聚合物表现出改进的性能，例如膜和制造零件应用中的颗粒稳定性，冲击性能，热封性能和结构完整性。

公开(公告)号：US20130165316A1

公开(公告)日：2013-06-27

申请号：US13720026

申请日：2012-12-19

Applicant: Total Raffinage Marketing ,  IFP Energies Nouvelles

Inventor： Bertrand GUICHARD ,  Laurent SIMON ,  Sylvie LOPEZ ,  Valentina DE GRANDI ,  Delphine MINOUX ,  Jean-Pierre DATH

IPC: B01J31/34 ,  C07C5/10 ,  C10G45/12

CPC classification number: B01J37/0205 ,  B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/85 ,  B01J23/882 ,  B01J23/90 ,  B01J27/14 ,  B01J27/19 ,  B01J29/076 ,  B01J31/0201 ,  B01J31/0209 ,  B01J35/002 ,  B01J37/0203 ,  B01J37/20 ,  B01J37/28 ,  B01J38/52 ,  B01J38/62 ,  C07C5/10 ,  C07C2601/14 ,  C10G45/08 ,  C10G45/50 ,  Y02P20/584 ,  C07C13/18

Abstract: A process for the preparation of a catalyst from a catalytic precursor comprising a support based on alumina and/or silica-alumina and/or zeolite and comprising at least one element of group VIB and optionally at least one element of group VIII, by impregnation of said precursor with a solution of a C1-C4 dialkyl succinate. An impregnation step for impregnation of said precursor which is dried, calcined or regenerated, with at least one solution containing at least one carboxylic acid other than acetic acid, then maturing and drying at a temperature less than or equal to 200° C., optionally a heat treatment at a temperature lower than 350° C., followed by an impregnation step with a solution containing at least one C1-C4 dialkyl succinate followed by maturing and drying at a temperature less than 200° C. without subsequent calcination step. The catalyst is used in hydrotreatment and/or hydroconversion.

Abstract translation: 一种从催化前体制备催化剂的方法，其包含基于氧化铝和/或二氧化硅 - 氧化铝和/或沸石的载体，并且包含至少一种VIB族元素和任选的至少一种VIII族元素，通过浸渍 所述前体与C1-C4二烷基琥珀酸酯的溶液。 浸渍步骤，用于用至少一种含有至少一种不同于乙酸的羧酸的溶液干燥，煅烧或再生的所述前体浸渍，然后在小于或等于200℃的温度下熟化和干燥，任选地 在低于350℃的温度下进行热处理，随后用含有至少一种C 1 -C 4二烷基琥珀酸酯的溶液进行浸渍步骤，然后在低于200℃的温度下熟化和干燥，而无需随后的煅烧步骤。 催化剂用于加氢处理和/或加氢转化。

公开(公告)号：US08367865B2

公开(公告)日：2013-02-05

申请号：US12627681

申请日：2009-11-30

Applicant: Tung-Han Tsai ,  Cheng-Fa Hsieh ,  Chi-Yuan Chen

Inventor： Tung-Han Tsai ,  Cheng-Fa Hsieh ,  Chi-Yuan Chen

IPC: C07C231/04 ,  B01J31/04

CPC classification number: C07C231/10 ,  B01J31/0201 ,  B01J31/0202 ,  B01J31/0209 ,  B01J31/0217 ,  B01J31/0218 ,  B01J31/0222 ,  B01J31/0238 ,  B01J31/0247 ,  B01J31/0251 ,  B01J31/0279 ,  B01J31/0285 ,  C07B43/06 ,  C07C229/24 ,  C07D201/04 ,  C07D223/10

Abstract: The present invention provides a catalyst composition for preparing an amide, including an amino acid ionic liquid having a cation of formula (I) and an anion selected from the group consisting of an inorganic acid group, an organic acid group and a combination thereof, wherein the numbers of the anion and the cation are such that the amino acid ionic liquid is electroneutral; and a Bronsted acid. The present invention also provides a method for preparing an amide in the presence of the catalyst composition, and the method has advantages such as decreasing viscosity of ionic liquid, and increasing conversion rate of ketoximes and selectivity of amides.

Abstract translation: 本发明提供一种制备酰胺的催化剂组合物，其包括具有式（I）的阳离子的氨基酸离子液体和选自无机酸基，有机酸基及其组合的阴离子，其中 阴离子和阳离子的数量使得氨基酸离子液体是电中性的; 和布朗斯台德酸。 本发明还提供了在催化剂组合物存在下制备酰胺的方法，该方法具有降低离子液体的粘度，提高酮肟的转化率和酰胺选择性的优点。