Manufacture of glass from metallic alcoholate
    291.
    发明专利
    Manufacture of glass from metallic alcoholate 失效
    从金属醇制成玻璃

    公开(公告)号:JPS5777044A

    公开(公告)日:1982-05-14

    申请号:JP15134780

    申请日:1980-10-30

    Abstract: PURPOSE: To obtain glass having a uniform film thickness and uniform physical properties by hydrolyzing metallic alcoholate contg. silicon alkoxide as a principal component in the presence of water or an org. solvent after adding a viscosity regulator so as to regulate the viscosity of the resulting soln. to the desired value.
    CONSTITUTION: To silicon alkoxide is added metallic alcoholate of Ti, Zr or the like, and to this added alcoholate are added a viscosity regulator having a superior thickening effect such as aqueous cellulose ether and water or an org. solvent such as methanol. By agitating them, the alcoholate is hydrolyzed to prepare a viscous soln. with about 5W30cps viscosity. By this viscosity regulation molded glass products having various shapes such as separate films, fibers, substrate coating and lump glass can be obtd.
    COPYRIGHT: (C)1982,JPO&Japio

    Abstract translation: 目的:通过水解金属醇化物获得具有均匀膜厚度和均匀物理性能的玻璃。 在水或有机溶剂存在下,作为主要成分的硅醇盐。 添加粘度调节剂以调节所得溶胶的粘度。 达到所需值。 构成:向烷氧基硅烷中加入Ti,Zr等的金属醇化物,向该添加的醇化物中加入具有优异增稠效果的粘度调节剂,例如水性纤维素醚和水或有机溶剂。 溶剂如甲醇。 通过搅拌它们,将醇化物水解以制备粘稠的溶胶。 约5-30cps粘度。 通过该粘度调节,可以得到具有各种形状的成型玻璃制品,例如分离的膜,纤维,基底涂层和块状玻璃。

    Process for the production of monoliths by means of the sol-gel process
    297.
    发明公开
    Process for the production of monoliths by means of the sol-gel process 有权
    Verfahren zur Herstellung von Monolithen durch ein Sol-Gel Verfahren

    公开(公告)号:EP1700831A1

    公开(公告)日:2006-09-13

    申请号:EP05005096.2

    申请日:2005-03-09

    Abstract: Process for the production of monoliths by means of the sol-gel process, comprising the following steps:

    a. hydrolysis of an alkoxide in aqueous solution to form a hydrolysate and optionally evaporation to optimum concentration of the same,
    b. addition of an oxide prepared by the pyrogenic route,
    c. mixing of the hydrolysate of the alkoxide with the oxide prepared by the pyrogenic route to form a colloidal sol,
    d. optional removal of coarse contents from the colloidal sol,
    e. gelling of the colloidal sol in a mould,
    f. optional replacement of the water contained in the resulting aerogel by an organic solvent,
    g. drying of the aerogel,
    h. heat treatment of the dried aerogel, the coarse content being removed from the colloidal sol.

    Abstract translation: 通过溶胶 - 凝胶法生产整料的方法,包括以下步骤:a。 在水溶液中水解醇盐以形成水解产物,并任选地蒸发至最佳浓度,b。 加入通过热解法制备的氧化物,c。 将醇盐的水解产物与通过热解法制备的氧化物混合以形成胶体溶胶,d。 可选地从胶体溶胶中除去粗含量, 胶体胶体在模具中凝胶化,f。 用有机溶剂任选地替代所得气凝胶中所含的水,g。 干燥气凝胶,h。 干燥的气凝胶的热处理,从胶体溶胶中除去粗含量。

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