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    Hydrotreatment catalyst, method for production and use thereof
    301.
    发明授权
    Hydrotreatment catalyst, method for production and use thereof 有权
    加氢处理催化剂，其制备方法及其应用

    公开(公告)号：US08318628B2

    公开(公告)日：2012-11-27

    申请号：US12519971

    申请日：2007-12-14

    Applicant: Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    Inventor： Claude Brun ,  Thierry Cholley ,  Carole Dupuy ,  Georges Fremy ,  Francis Humblot

    IPC: B01J31/02

    CPC classification number: B01J31/28 ,  B01J23/85 ,  B01J23/882 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0208 ,  B01J31/0229 ,  B01J31/34 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G47/12 ,  C10G2300/703

    Abstract: The invention relates to a catalyst for hydroconversion of hydrocarbons, comprising a support made from at least one refractory oxide, at least one group VIII metal and at least one group VIB metal, characterized in further comprising at least one organic compound with at least two thiol functions separated by at least one oxygenated group of formula (I): HS—CxHyOz—SH (I), where x=1 to 20, preferably 2 to 9 and for example x=6, y=2 to 60, preferably 4 to 12 and z=1 to 10, preferably 1 to 6. The invention further relates to a method for preparation, a method for activation of said catalyst and use of the catalyst for the hydrotreatment and/or hydrocracking of hydrocarbons.

    Abstract translation: 本发明涉及用于加氢转化烃的催化剂，其包括由至少一种难熔氧化物，至少一种第Ⅷ族金属和至少一种VIB族金属制成的载体，其特征在于还包含至少一种有机化合物与至少两种硫醇 由式（I）的至少一个氧化基团分离的功能：HS-CxHyOz-SH（I），其中x = 1至20，优选2至9，例如x = 6，y = 2至60，优选4至 12和z = 1至10，优选1至6.本发明还涉及一种制备方法，一种活化所述催化剂的方法和该催化剂用于烃的加氢处理和/或加氢裂化的用途。

    Catalyst composition for ethylene oligomerization and the use thereof
    309.
    发明授权
    Catalyst composition for ethylene oligomerization and the use thereof 有权
    用于乙烯低聚的催化剂组合物及其用途

    公开(公告)号：US07786336B2

    公开(公告)日：2010-08-31

    申请号：US11716540

    申请日：2007-03-09

    Applicant: Baojun Zhang ,  Tao Jiang ,  Jianzhong Li ,  Lihua Xing ,  Yingnan Ning ,  Shukun Sun ,  Dongting Kuang ,  Yongcheng Sun ,  Yunguang Han ,  Qian Chen ,  Hongxia Chen ,  Deshun Zhang ,  Yulong Li ,  Yongjun Zhang ,  Huimin Yuan ,  Sihan Wang ,  Guizhi Wang ,  Jingyuan Zhang

    Inventor： Baojun Zhang ,  Tao Jiang ,  Jianzhong Li ,  Lihua Xing ,  Yingnan Ning ,  Shukun Sun ,  Dongting Kuang ,  Yongcheng Sun ,  Yunguang Han ,  Qian Chen ,  Hongxia Chen ,  Deshun Zhang ,  Yulong Li ,  Yongjun Zhang ,  Huimin Yuan ,  Sihan Wang ,  Guizhi Wang ,  Jingyuan Zhang

    IPC: C07C2/26 ,  C07C2/32 ,  B01J31/14 ,  B01J31/18 ,  B01J31/22

    CPC classification number: C07C2/32 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0231 ,  B01J31/188 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2531/14 ,  C07C2531/22 ,  C08F110/02 ,  Y02P20/52 ,  C08F2500/02

    Abstract: The present invention relates to a catalyst composition for ethylene oligomerization and the use thereof. Such catalyst composition includes chromium compound, ligand containing P and N, activator and accelerator; wherein the chromium compound is selected from the group consisting of acetyl acetone chromium, THF-chromium chloride and Cr(2-ethylhecanoate)3; general formula of the ligand containing P and N is shown as: in which R1, R2, R3 and R4 are phenyl, benzyl, or naphthyl. R5 is isopropyl, butyl, cyclopropyl, cyclopentyl, cyclohexyl or fluorenyl; the activatior is methyl aluminoxane, ethyl aluminoxane, propyl aluminoxane and/or butyl aluminoxane; the accelerator is selected from the group consisting of 1,1,2,2,-tetrachloroethane, 1,1,2,2-tetrabromoethane, 1,1,2,2-tetrafluoroethane, and compounds having a formula of X1R6X2, in which X1 and X2 are F, Cl, Br, I or alkoxyl, R6 is alkylene or arylene group; the molar ratio of chromium compound, ligand containing P and N, activator and accelerator is 1:0.5˜10:50˜3000:0.5˜10. After mixing the four components mentioned previously under nitrogen atmosphere for 10 minutes, they are incorporated to the reactor, or these four components are incorporated directly into the reactor. Then ethylene is introduced for oligomerization. Such catalyst can be used in producing 1-octene through ethylene oligomerization. It is advantageous in high catalysing activity, high 1-octene selectivity, etc. The catalytic activity is more than 1.0×106 g product·ma−1 Cr·h−1, the fraction of C8 linear α-olefin is more than 70% by mass.

    Abstract translation: 本发明涉及一种用于乙烯低聚的催化剂组合物及其用途。 这种催化剂组合物包括铬化合物，含有P和N的配体，活化剂和促进剂; 其中铬化合物选自乙酰丙酮铬，THF-氯化铬和Cr（2-乙基庚酸酯）3; 含有P和N的配体的通式为：其中R 1，R 2，R 3和R 4为苯基，苄基或萘基。 R5是异丙基，丁基，环丙基，环戊基，环己基或芴基; 活性物质是甲基铝氧烷，乙基铝氧烷，丙基铝氧烷和/或丁基铝氧烷; 促进剂选自1,1,2,2-四氯乙烷，1,1,2,2-四溴乙烷，1,1,2,2-四氟乙烷和具有式X1R6X2的化合物，其中 X 1和X 2是F，Cl，Br，I或烷氧基，R 6是亚烷基或亚芳基; 铬化合物，含P和N的配体，活化剂和促进剂的摩尔比为1:0.5〜10:50〜3000:0.5〜10。 在氮气氛下将上述四种组分混合10分钟后，将它们并入反应器中，或将这四种组分直接并入反应器中。 然后引入乙烯用于低聚。 这种催化剂可用于通过乙烯低聚制备1-辛烯。 高催化活性，1-辛烯选择性高等优点。催化活性大于1.0×106 g产物·ma-1 Cr·h-1，C8线性α-烯烃的分数大于70％ 的质量。

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