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公开(公告)号:US11745158B2
公开(公告)日:2023-09-05
申请号:US17424382
申请日:2020-01-21
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Tiziana Caputo , Antonio Mazzucco , Nicolo Arich De Finetti , Marco Bocchino
CPC classification number: B01J19/0033 , B01J19/2435 , C08F2/01 , B01J2208/00044 , B01J2208/0061 , B01J2208/00672
Abstract: A method for monitoring and controlling the polymerization in a polymerization vessel by using a camera viewing unit to (a) detect features of the polymer particles, or the particles' environment, (b) compare the features to pre-defined acceptable values of these features or the environment, and (c) if a variation from the pre-defined values is detected, act on process parameters to reduce or eliminate the variation.
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公开(公告)号:US11673981B2
公开(公告)日:2023-06-13
申请号:US17311071
申请日:2019-12-02
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Diego Brita
IPC: C08F110/06 , C08F4/654 , C08F4/651 , C08F2/44 , C08F4/646
CPC classification number: C08F110/06 , C08F2/44 , C08F4/6465 , C08F4/651 , C08F4/6545
Abstract: A process for the preparation of a solid catalyst component made from or containing a Ti compound, a coloring agent and optionally an electron donor on a Mg chloride based support, including step (a), carried out at a temperature ranging from 0 to 150° C., wherein (i) a Mg-based compound of formula (MgClmX2-m).nLB, wherein m ranges from 0 to 2, n ranges from 0 to 6, X is, independently halogen, R1, OR1, —OCOR1 or O—C(O)—OR1 group, wherein R1 is a C1-C20 hydrocarbon group and LB is a Lewis base, is reacted with (ii) a liquid medium made from or containing a Ti compound having at least a Ti—Cl bond in an amount such that the Ti/Mg molar ratio is greater than 3; and an organic coloring agent is present either associated to the Mg-based compound or dispersed in the liquid medium made from or containing the titanium compound.
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公开(公告)号:US20230095189A1
公开(公告)日:2023-03-30
申请号:US17908333
申请日:2021-02-23
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: GIANPIERO FERRARO , MARCO CIARAFONI , CLAUDIO CAVALIERI , CAROLINE CATHELIN , GIANSIRO PRINI
IPC: C08F210/06 , B29C45/00
Abstract: A propylene/1-hexene copolymer having i) the content of 1-hexene derived units, measured by C13-NMR, ranging from 1.5 wt % to 2.5 wt % and the content of propylene derived units ranging from 97.5 to 98.5 wt. %; ii) a melting temperature, measured by DSC, ranging from 148 to 153° C.; iii) an amount of fraction insoluble in xylene at 25° C. higher than 97.0%; and iv) a melt flow rate (MFR), measured according to ISO 1133, 230° C., 2.16 kg, ranging from 35 to 65 g/10 min.
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公开(公告)号:US20220403059A1
公开(公告)日:2022-12-22
申请号:US17777365
申请日:2020-11-05
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: DIEGO BRITA , GIANNI COLLINA , DANIELE EVANGELISTI , BENEDETTA GADDI , PIERO GESSI , GIAMPIERO MORINI , SILVIA SOFFRITTI , PAOLO VINCENZI
IPC: C08F4/602
Abstract: A process for preparing a catalyst component made from or containing Mg, Ti, and at least an electron donor compound (ID), including the steps of: (a) reacting a Mg based compound with a Ti compound, having at least a Ti—Cl bond, in an amount such that the Ti/Mg molar ratio is greater than 3 and at a temperature ranging from 0 to 150° C., thereby yielding an intermediate solid catalyst component containing Mg and Ti; and (b) contacting the intermediate solid catalyst component with a gaseous stream containing the electron donor compound (ID) in a gaseous dispersing medium, thereby yielding a final solid catalyst component having an ID/Ti molar ratio ranging from 0.5:1 to 20:1.
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公开(公告)号:US20220396649A1
公开(公告)日:2022-12-15
申请号:US17776117
申请日:2020-11-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: NICOLO ARICH DE FINETTI , PIETRO BAITA , ANTONIO MAZZUCCO , ROBERTA PICA
IPC: C08F210/16
Abstract: A process for the continuous solution polymerization including the step of polymerizing a first olefin monomer of formula CH2═CHR1, wherein R1 is hydrogen or a hydrocarbon radical having from 1 to 8 carbon atoms with a second olefin monomer of formula CH2═CHR2, wherein R2 is a hydrocarbon radical having from 3 to 8 carbon atoms, in the presence of a polymerization catalyst and in the absence of an inert solvent, at a polymerization temperature (Tp) satisfying the following relationship: Tp≥Tm+20° C. wherein Tm is the melting temperature of the obtained polymer.
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公开(公告)号:US11466107B2
公开(公告)日:2022-10-11
申请号:US16967587
申请日:2019-01-25
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Simona Guidotti , Dario Liguori , Giampiero Morini , Gianni Vitale
IPC: C08F4/02 , C08F4/20 , C08F4/646 , C08F110/06 , C08F4/657
Abstract: A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.
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公开(公告)号:US20220298343A1
公开(公告)日:2022-09-22
申请号:US17642277
申请日:2020-08-31
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: FABRIZIO PIEMONTESI , ALESSANDRO MIGNOGNA , DARIO LIGUORI , GIAMPIERO MORINI , GIANNI VITALE
IPC: C08L23/12
Abstract: A polypropylene composition made from or containing: A) from 60 to 90 wt %, based upon the total weight of the polypropylene composition, of a fraction insoluble in xylene at 25° C., is made from or containing more than 80% wt of propylene units, and B) from 10 to 40 wt %, based upon the total weight of the polypropylene composition, of a fraction soluble in xylene at 25° C. is made from or containing a copolymer of propylene and ethylene having an average content of ethylene derived units from 30.0 wt % to 55.0 wt %, wherein the fraction when subjected to GPC fractionation and continuous IR analysis for determining the ethylene content of the eluted fractions (GPC-IR analysis), shows that the content of ethylene increases along with the Mw for fractions having Mw higher than the average.
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公开(公告)号:US20220298272A1
公开(公告)日:2022-09-22
申请号:US17642460
申请日:2020-08-27
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: FABRIZIO PIEMONTESI , ALESSANDRO MIGNOGNA , DARIO LIGUORI , GIAMPIERO MORINI , TIZIANO DALL'OCCO , GIANNI VITALE
Abstract: A solid catalyst component for the polymerization of olefins made from or containing a magnesium halide, a titanium compound having at least a Ti-halogen bond, a first electron donor compound selected from 1,3 diethers (DE), and a second electron donor compound selected from dicarbamates (DC), wherein the first and second electron donor compounds are present in a molar ratio DE:DC ranging from 4.5:1 to 20:1.
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公开(公告)号:US11407844B2
公开(公告)日:2022-08-09
申请号:US17312264
申请日:2019-12-03
Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
Inventor: Alessandro Mignogna , Dario Liguori , Giampiero Morini , Gianni Vitale
Abstract: A solid catalyst component for the polymerization of olefins made from or containing Mg, Ti, Cl and at least an electron donor compound which is the reaction product obtained by bringing into contact a Mg compound and a Ti compound having at least a Ti-halogen bond with an electron donor selected from diphenol derivatives.
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公开(公告)号:US20220170162A1
公开(公告)日:2022-06-02
申请号:US17602369
申请日:2020-03-23
Applicant: Basell Poliolefine Italia S.r.l.
Inventor: Luca Lunghi , Maria Aranzazu Lujan Abarca , Alberto Foguet Roca
Abstract: A method for the production of metal-plated articles, including the step of depositing an electrically-conductive metallic layer on a surface of an article comprising a polymer composition comprising by weight: a) 40-60% of a propylene homopolymer, or propylene copolymer containing up to 5% by weight of ethylene and/or another C4-C10 α-olefin, and having a melting temperature of 155° C. or higher and/or a fraction soluble in xylene at 25° C. of 10% by weight or less; b) 10-20% of an ethylene-based elastoplastic copolymer, optionally, a copolymer of ethylene with C4-C10 α-olefin; c) 2-6% of a styrene block copolymer; d) optionally, up to 3% of a propylene homopolymer having a Melt Flow Rate (230° C./2.16 kg) of 500 g/10 min. or more; e) 15-50% of a filler; and f) optionally, up to 6% of a color pigment.
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