公开(公告)号：WO2011068770A1

公开(公告)日：2011-06-09

申请号：PCT/US2010/058262

申请日：2010-11-30

Applicant: DOW GLOBAL TECHNOLOGIES INC. ,  COALTER, Joseph, N., III ,  LEUNG, Tak, W. ,  TAO, Tao ,  GAO, Kuanqiang

Inventor： COALTER, Joseph, N., III ,  LEUNG, Tak, W. ,  TAO, Tao ,  GAO, Kuanqiang

IPC: C08F4/651 ,  C08F110/06 ,  C07C68/02 ,  C07C69/96 ,  B01J31/02 ,  C08F4/646

CPC classification number: C07C69/96 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F110/06 ,  C08F210/06 ,  Y02P20/52 ,  C08F4/651 ,  C08F4/6465 ,  C08F210/16 ,  C08F2500/12

Abstract: A solid, hydrocarbon-insoluble, catalyst component useful in polymerizing olefins, said catalyst component containing magnesium, titanium, and halogen, and further containing an internal electron donor having a structure: [R 1 -O-C(O)-O-] x R 2 wherein R 1 is independently at each occurrence, an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms; x is 2-4; and R 2 is an aliphatic or aromatic hydrocarbon, or substituted hydrocarbon group containing from 1 to 20 carbon atoms, provided that there are 2 atoms in the shortest chain connecting a first R 1 O C(O)-O- group and a second R 1 -O-C(O)-O- group.

Abstract translation: 用于聚合烯烃的固体，不溶于烃的催化剂组分，所述催化剂组分含有镁，钛和卤素，并且还含有具有以下结构的内部电子给体：[R 1 -OC（O）-O-] x R 2，其中R 1 在每次出现时独立地为脂族或芳族烃，或含有1至20个碳原子的取代烃基; x为2-4; 并且R2是含有1至20个碳原子的脂族或芳族烃或取代的烃基，条件是在连接第一个R1 OC（O）-O-基团和第二个R1-OC（ O）-O-基。

公开(公告)号：WO2010072609A1

公开(公告)日：2010-07-01

申请号：PCT/EP2009/067069

申请日：2009-12-14

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  BRITA, Diego ,  COLLINA, Gianni

Inventor： BRITA, Diego ,  COLLINA, Gianni

IPC: C08F4/654 ,  C08F4/645 ,  C08F110/02 ,  B01J27/135 ,  B01J27/138

CPC classification number: C08F110/02 ,  B01J27/135 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0212 ,  B01J31/143 ,  B01J31/26 ,  B01J31/38 ,  C08F210/16 ,  C08F4/6455 ,  C08F4/6545 ,  C08F4/653 ,  C08F210/14 ,  C08F2500/18 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/04

Abstract: Catalyst component comprising Mg, Ti, Hf, a halogen and, optionally, -OR groups where R is a C1-C20 hydrocarbon group, characterized in that (a) the Mg atoms are present in an amount higher than 7% based on the total weight of the said catalyst component, (b) the amount of Mg, Ti, and Hf atoms is such that the Mg/Ti molar ratio ranges from (3) to (25) and the Hf/Ti molar ratio is lower than 1.5 and (c) when -OR groups are present their amount is such that the -OR/Ti molar ratio is lower than (2).

Abstract translation: 包含Mg，Ti，Hf，卤素和任选的-OR基团的催化剂组分，其中R是C1-C20烃基，其特征在于（a）Mg原子以高于7％的量存在， 所述催化剂组分的重量，（b）Mg，Ti和Hf原子的量使得Mg / Ti摩尔比范围为（3）至（25），Hf / Ti摩尔比低于1.5， （c）当-OR基团存在时，它们的量使得-OR / Ti摩尔比低于（2）。

公开(公告)号：WO2009126278A2

公开(公告)日：2009-10-15

申请号：PCT/US2009002204

申请日：2009-04-08

Applicant: EXXONMOBIL RES & ENG CO ,  MCCARTHY STEPHEN J ,  BAI CHUANSHENG ,  BORGHARD WILLIAM G ,  LEWIS WILLIAM ERNEST

Inventor： MCCARTHY STEPHEN J ,  BAI CHUANSHENG ,  BORGHARD WILLIAM G ,  LEWIS WILLIAM ERNEST

IPC: B01J23/85 ,  B01J23/90 ,  B01J23/94 ,  B01J37/02 ,  B01J38/00 ,  C10G45/08 ,  C10G45/10

CPC classification number: B01J23/85 ,  B01J21/04 ,  B01J23/882 ,  B01J23/94 ,  B01J31/0201 ,  B01J31/0235 ,  B01J37/0203 ,  B01J37/20 ,  B01J38/485 ,  C10G45/04 ,  C10G45/08 ,  C10G45/10

Abstract: Methods for rejuvenation of supported metallic catalysts comprised of a Group VIII metal, a Group VIB metal, making use of these metals, an organic complexing agent, and optionally an organic additive, are provided. The rejuvenation includes stripping and regeneration of a spent or partially spent catalyst, followed by impregnation with metals and at least one organic compound. The impregnated, regenerated catalysts are dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

Abstract translation: 提供了由VIII族金属，VIB族金属，使用这些金属，有机络合剂和任选的有机添加剂组成的复合载体金属催化剂的复兴方法。 复原包括废弃或部分废弃的催化剂的汽提和再生，然后用金属和至少一种有机化合物浸渍。 将浸渍的再生催化剂干燥，煅烧和硫化。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。

公开(公告)号：WO2009088596A1

公开(公告)日：2009-07-16

申请号：PCT/US2008/085334

申请日：2008-12-03

Applicant: BASF CATALYSTS LLC ,  SPENCER, Michael, Donald

Inventor： SPENCER, Michael, Donald

IPC: C08F4/651 ,  C08F110/06

CPC classification number: C08F110/06 ,  B01J27/138 ,  B01J31/0201 ,  B01J31/0212 ,  B01J31/0272 ,  B01J31/143 ,  B01J31/2208 ,  B01J2531/46 ,  C08F4/651 ,  C08F4/6543 ,  C08F2500/18 ,  C08F2500/15

Abstract: Disclosed are catalyst systems and methods of making the catalyst systems/supports for the polymerization of an olefin containing a solid titanium catalyst component having a substantially spherical shape and containing an internal electron donor, a support made by contacting substantially equal molar amounts of a magnesium compound and an epoxy compound in the presence of an aprotic solvent and subsequent treatment with a halogenating agent to provide a magnesium based catalyst support. The catalyst system can further contain an organoaluminum compound and an organosilicon compound. Also disclosed are methods of polymerizing or copolymerizing an alpha-olefin. The methods involve contacting an olefin with a catalyst system containing the solid titanium catalyst component.

Abstract translation: 公开了催化剂体系和制备催化剂体系/载体的方法，所述催化剂体系/载体用于聚合含有具有基本上球形的固体钛催化剂组分并含有内电子给体的烯烃，通过使基本相等摩尔量的镁化合物 和在非质子溶剂存在下的环氧化合物，随后用卤化剂处理以提供镁基催化剂载体。 催化剂体系还可以含有有机铝化合物和有机硅化合物。 还公开了聚合或共聚α-烯烃的方法。 该方法包括使烯烃与含有固体钛催化剂组分的催化剂体系接触。

公开(公告)号：WO2008090282A3

公开(公告)日：2008-10-02

申请号：PCT/FR2007002073

申请日：2007-12-14

Applicant: TOTAL FRANCE ,  ARKEMA FRANCE ,  BRUN CLAUDE ,  CHOLLEY THIERRY ,  DUPUY CAROLE ,  FREMY GEORGES ,  HUMBLOT FRANCIS

Inventor： BRUN CLAUDE ,  CHOLLEY THIERRY ,  DUPUY CAROLE ,  FREMY GEORGES ,  HUMBLOT FRANCIS

IPC: B01J31/02 ,  B01J31/28 ,  B01J31/34 ,  B01J37/20 ,  C10G45/08 ,  C10G47/16

CPC classification number: B01J31/28 ,  B01J23/85 ,  B01J23/882 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0208 ,  B01J31/0229 ,  B01J31/34 ,  B01J37/0203 ,  B01J37/20 ,  C10G45/08 ,  C10G47/12 ,  C10G2300/703

Abstract: The invention relates to a catalyst for hydroconversion of hydrocarbons, comprising a support made from at least one refractory oxide, at least one group VIII metal and at least one group VIB metal, characterised in further comprising at least one organic compound with at least two thiol functions separated by at least one oxygenated group of formula (I) : HS-CxHyOz-SH (I), where x =1 to 20, preferably 2 to 9 and for example x = 6, y = 2 to 60, preferably 4 to 12 and z = 1 to 10, preferably 1 to 6. The invention further relates to a method for preparation, a method for activation of said catalyst and use of the catalyst for the hydrotreatment and/or hydrocracking of hydrocarbons.

Abstract translation: 本发明涉及用于加氢转化烃的催化剂，其包括由至少一种难熔氧化物，至少一种第Ⅷ族金属和至少一种VIB族金属制成的载体，其特征在于还包含至少一种有机化合物与至少两种硫醇 由式（I）的至少一个氧化基团分离的功能：HS-CxHyOz-SH（I），其中x = 1〜20，优选2〜9，例如x = 6，y = 2〜60，优选4〜 12和z = 1至10，优选1至6.本发明还涉及一种制备方法，一种活化所述催化剂的方法和该催化剂用于烃的加氢处理和/或加氢裂化的用途。

公开(公告)号：WO2008079178A1

公开(公告)日：2008-07-03

申请号：PCT/US2007/021869

申请日：2007-10-11

Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY ,  BAI, Chuansheng ,  EL-MALKI, Ei-mekki ,  ELKS, Jeff ,  HOU, Zhigou ,  MCCONNACHIE, Jon, M. ,  VENKATARAMAN, Pallassana, S. ,  WU, Jason ,  JACOBS, Peter, W. ,  GIAQUINTA, Daniel ,  SOKOLOVSKII, Valery ,  HAN, Jun ,  HAGEMEYER, Alfred ,  LOWE, David, M. ,  VOLPE, Anthony, F., Jr.

Inventor： BAI, Chuansheng ,  EL-MALKI, Ei-mekki ,  ELKS, Jeff ,  HOU, Zhigou ,  MCCONNACHIE, Jon, M. ,  VENKATARAMAN, Pallassana, S. ,  WU, Jason ,  JACOBS, Peter, W. ,  GIAQUINTA, Daniel ,  SOKOLOVSKII, Valery ,  HAN, Jun ,  HAGEMEYER, Alfred ,  LOWE, David, M. ,  VOLPE, Anthony, F., Jr.

IPC: C10G47/02 ,  B01J37/00

CPC classification number: B01J37/20 ,  B01J21/04 ,  B01J23/85 ,  B01J23/882 ,  B01J23/883 ,  B01J23/885 ,  B01J23/8873 ,  B01J23/8898 ,  B01J31/0201 ,  B01J31/0254 ,  B01J31/2234 ,  B01J31/2239 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/08 ,  B01J37/084 ,  B01J2231/62 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/845 ,  B01J2531/847 ,  C10G45/08

Abstract: Supported metallic catalysts comprised of a Group VIII metal, a Group VIB metal, and an organic additive, and methods for synthesizing supported metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic additive, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.

Abstract translation: 提供了由VIII族金属，VIB族金属和有机添加剂组成的负载金属催化剂，以及用于合成负载型金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机添加剂相互作用，干燥，煅烧和硫化的方法制备。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。

公开(公告)号：WO2006072775A3

公开(公告)日：2007-04-26

申请号：PCT/GB2006000006

申请日：2006-01-04

Applicant: UNIV BELFAST ,  EARLE MARTYN JOHN ,  SEDDON KENNETH RICHARD ,  FORSYTH STEWART ,  FROHLICH UTE ,  GUNARATNE NIMAL ,  KATDARE SUHAS

Inventor： EARLE MARTYN JOHN ,  SEDDON KENNETH RICHARD ,  FORSYTH STEWART ,  FROHLICH UTE ,  GUNARATNE NIMAL ,  KATDARE SUHAS

IPC: B01J31/02 ,  B01J31/22 ,  C07B37/04 ,  C07B61/00 ,  C07C45/51 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/69 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C209/60 ,  C07C211/63 ,  C07C217/08 ,  C07D213/73 ,  C07D233/54 ,  C07D301/12 ,  C07D303/32

CPC classification number: C07C217/08 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0225 ,  B01J31/0234 ,  B01J31/0237 ,  B01J31/0277 ,  B01J31/0278 ,  B01J31/0282 ,  B01J31/0284 ,  B01J31/0287 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/0291 ,  B01J31/2208 ,  B01J2231/341 ,  B01J2231/342 ,  B01J2231/346 ,  B01J2231/348 ,  B01J2231/349 ,  B01J2231/4261 ,  B01J2231/645 ,  B01J2231/72 ,  B01J2531/824 ,  B01J2531/90 ,  C07B61/00 ,  C07C45/512 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C211/63 ,  C07D213/73 ,  C07D233/54 ,  C07D303/32 ,  Y02P20/542 ,  C07C47/228 ,  C07C49/603 ,  C07C49/647 ,  C07C49/637 ,  C07C49/203 ,  C07C49/597 ,  C07C49/497 ,  C07C49/707 ,  C07C49/17 ,  C07C49/403

Abstract: Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterised in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

Abstract translation: 在碱催化的化学反应中使用离子液体作为溶剂，其中离子液体由至少一种阳离子和至少一种阴离子组成，其特征在于离子液体的阳离子包含正电荷部分和碱性 部分，其中这种离子液体可以用作化学反应的促进剂或催化剂。

公开(公告)号：WO2006093170A1

公开(公告)日：2006-09-08

申请号：PCT/JP2006/303801

申请日：2006-02-28

Applicant: 独立行政法人産業技術総合研究所 ,  鳥羽 誠 ,  葭村 雄二 ,  松林 信行 ,  松井 高史

Inventor： 鳥羽 誠 ,  葭村 雄二 ,  松林 信行 ,  松井 高史

IPC: B01J27/228 ,  B01J27/22 ,  B01J32/00 ,  C10G45/08

CPC classification number: B01J23/882 ,  B01J23/88 ,  B01J27/22 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0203 ,  C10G2300/104 ,  C10G2400/02

Abstract: The invention relates to a porous inorganic oxide carrier supporting thereon an oxygen-containing carbonaceous substance, preferably a carbide of an oxygen-containing organic compound, wherein the mass ratio of carbon supported on the carrier for catalyst preparation to the carrier is 0.05 to 0.2, the atomic ratio of hydrogen supported on the carrier to carbon supported thereon is 0.4 to 1.0, and the atomic ratio of oxygen supported on the carrier to carbon supported thereon is 0.1 to 0.6. The invention relates also to a hydrotreating catalyst for catalytically cracked gasoline which is produced by making a catalyst containing a Group 8 metal of the periodic table, molybdenum (Mo), phosphorus, and sulfur supported on the above carrier. This catalyst depresses the hydrogenation of olefins even under the reaction conditions attaining high-degree desulfurization and minimizes the lowering in the octane value, thus being useful as a catalyst for hydrodesulfurizing catalytically cracked gasoline or the like to a super depth desulfurization level.

Abstract translation: 本发明涉及一种多孔无机氧化物载体，其上载有含氧碳质物质，优选含氧有机化合物的碳化物，其中负载在催化剂制备载体上的碳与载体的质量比为0.05至0.2， 负载在载体上的载体与负载在其上的碳的原子比为0.4〜1.0，负载在载体上的担载于载体上的碳的原子比为0.1〜0.6。 本发明还涉及通过制备含有周期表第8族金属的催化剂，载于上述载体上的钼（Mo），磷和硫而制备的催化裂化汽油加氢处理催化剂。 该催化剂即使在达到高度脱硫的反应条件下也能抑制烯烃的氢化，并使辛烷值的降低最小化，因此可用作催化裂化汽油等加氢脱硫至超深度脱硫水平的催化剂。

公开(公告)号：WO2006072775A2

公开(公告)日：2006-07-13

申请号：PCT/GB2006/000006

申请日：2006-01-04

Applicant: THE QUEEN'S UNIVERSITY OF BELFAST ,  EARLE, Martyn, John ,  SEDDON, Kenneth, Richard ,  FORSYTH, Stewart ,  FROHLICH, Ute ,  GUNARATNE, Nimal ,  KATDARE, Suhas

Inventor： EARLE, Martyn, John ,  SEDDON, Kenneth, Richard ,  FORSYTH, Stewart ,  FROHLICH, Ute ,  GUNARATNE, Nimal ,  KATDARE, Suhas

IPC: B01J31/02 ,  B01J31/22 ,  C07B61/00 ,  C07C45/51 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C211/63 ,  C07C217/08 ,  C07D213/73 ,  C07D233/54 ,  C07D303/32

CPC classification number: C07C217/08 ,  B01J31/0201 ,  B01J31/0204 ,  B01J31/0225 ,  B01J31/0234 ,  B01J31/0237 ,  B01J31/0277 ,  B01J31/0278 ,  B01J31/0282 ,  B01J31/0284 ,  B01J31/0287 ,  B01J31/0288 ,  B01J31/0289 ,  B01J31/0291 ,  B01J31/2208 ,  B01J2231/341 ,  B01J2231/342 ,  B01J2231/346 ,  B01J2231/348 ,  B01J2231/349 ,  B01J2231/4261 ,  B01J2231/645 ,  B01J2231/72 ,  B01J2531/824 ,  B01J2531/90 ,  C07B61/00 ,  C07C45/512 ,  C07C45/62 ,  C07C45/66 ,  C07C45/67 ,  C07C45/72 ,  C07C45/73 ,  C07C45/74 ,  C07C211/63 ,  C07D213/73 ,  C07D233/54 ,  C07D303/32 ,  Y02P20/542 ,  C07C47/228 ,  C07C49/603 ,  C07C49/647 ,  C07C49/637 ,  C07C49/203 ,  C07C49/597 ,  C07C49/497 ,  C07C49/707 ,  C07C49/17 ,  C07C49/403

Abstract: Use of ionic liquids as solvents in base-catalysed chemical reactions wherein the ionic liquid is composed of at least one species of cation and at least one species of anion, characterised in that a cation of the ionic liquid comprises a positively charge moiety and a basic moiety, and further wherein such ionic liquids may be used as promoters or catalysts for the chemical reactions.

Abstract translation: 在碱催化的化学反应中使用离子液体作为溶剂，其中离子液体由至少一种阳离子和至少一种阴离子组成，其特征在于离子液体的阳离子包含正电荷部分和碱性 部分，其中这种离子液体可以用作化学反应的促进剂或催化剂。

公开(公告)号：WO2004018097A1

公开(公告)日：2004-03-04

申请号：PCT/JP2003/010457

申请日：2003-08-19

Applicant: 独立行政法人産業技術総合研究所 ,  葭村 雄二 ,  鳥羽 誠 ,  佐藤 利夫

Inventor： 葭村 雄二 ,  鳥羽 誠 ,  佐藤 利夫

IPC: B01J31/34

CPC classification number: C10G45/08 ,  B01J23/85 ,  B01J31/0201 ,  B01J37/0203

Abstract: An impregnant solution for hydrocarbon hydrodesulfurization catalysts which comprises at least one Group 6 metal of the Periodic Table, at least one Group 8 metal of the Periodic Table, and/or a phosphorus compound, and a sugar derivative; and a catalyst for the hydrodesulfurization of hydrocarbons which is obtained by impregnating a support with the impregnant solution and then drying the impregnation. The impregnant solution is stable over a wide pH range. The hydrodesulfurization catalyst has excellent hydrodesulfurization performance, especially in the desulfurization of compounds difficult to desulfurize. It is inhibited from functioning to hydrogenate unsaturated hydrocarbons and does not cause the isomerization/decomposition attributable to the function of solid acids. The catalyst is hence extremely useful as a catalyst for the superdeep hydrodesulfurization of gas-oil fractions, etc.

Abstract translation: 用于烃加氢脱硫催化剂的浸渍剂溶液，其包含至少一种周期表第6族金属，至少一种第8族金属元素周期表和/或磷化合物和糖衍生物; 以及通过用浸渍剂浸渍载体然后干燥浸渍而获得的烃的加氢脱硫催化剂。 浸渍剂溶液在宽pH范围内是稳定的。 加氢脱硫催化剂具有优异的加氢脱硫性能，特别是在难以脱硫的化合物的脱硫中。 抑制不饱和烃的氢化作用，不会由于固体酸的功能而引起异构化/分解。 因此，催化剂作为用于瓦斯油馏分等的超级加氢脱硫的催化剂非常有用。