公开(公告)号：US06555603B1

公开(公告)日：2003-04-29

申请号：US09869955

申请日：2001-08-30

Applicant: Kazumi Kikkawa ,  Tsutomu Matsuura ,  Naoko Dai ,  Toshinori Yukino

Inventor： Kazumi Kikkawa ,  Tsutomu Matsuura ,  Naoko Dai ,  Toshinori Yukino

IPC: C08K534

CPC classification number: C08J5/18 ,  C08F8/30 ,  C08J2323/06 ,  C08L23/04 ,  C08L23/36 ,  C08L2201/08 ,  C08L2666/04 ,  C08F110/02 ,  C08F210/18

Abstract: A resin composition for agricultural film, which composition contains 100 parts by mass of a synthetic resin (A) and the below-specified amount of a polymer stabilizer (B). Polymer stabilizer (B): an adduct obtained by adding a compound (b1) represented by the following formula (I) to a polymer (b2) having a molecular weight of at least 300: (wherein n represents an integer of 1-4; X represents —O— or —NH—; and R represents a hydrogen atom, a C1-C20 aliphatic acyl group, a C1-C20 aliphatic polyacyl group, a C1-C20 aromatic acyl group, or a C1-C20 aromatic polyacyl group). Amount of polymer stabilizer (B): such an amount that makes the amount of nitrogen atoms contained in the polymer stabilizer (B) 0.0005-1 part by mass.

Abstract translation: 一种农用薄膜用树脂组合物，其组合物含有100质量份合成树脂（A）和低于规定量的聚合物稳定剂（B）。聚合物稳定剂（B）：将化合物（b1） ）表示为分子量为300以上的聚合物（b2）（式中，n表示1-4的整数，X表示-O-或-NH-，R表示氢原子） 原子，C1-C20脂族酰基，C1-C20脂族聚酰基，C1-C20芳族酰基或C1-C20芳族聚酰基）。聚合物稳定剂（B）的量：使 聚合物稳定剂（B）中所含的氮原子的量为0.0005〜1质量份。

公开(公告)号：US06172153B2

公开(公告)日：2001-01-09

申请号：US09097281

申请日：1998-06-12

Applicant: Michael E. Starsinic

Inventor： Michael E. Starsinic

IPC: C08J510

CPC classification number: C08K5/526 ,  C08K3/22 ,  C08K3/34 ,  C08K5/098 ,  C08K5/32 ,  C08K5/5353 ,  C08L23/10 ,  C08L2201/08 ,  C08L23/02

Abstract: A polymer composition and fiber, film and fabric prepared therefrom. The composition contains (i) an acid neutralizing agent other than a metallic salt of a saturated or unsaturated fatty acid, (ii) a processing aid comprising a metallic salt of a saturated or unsaturated fatty acid, the metallic salt of a saturated or unsaturated being present in a maximum amount of 200 ppm, a stabilizer system containing (a) a phosphite selected from the group consisting of 2,2′,2″-nitrilo[triethyl-tris(3,3′,5,5′-tetra-tert.butyl-1, 1-biphenyl-2,2′-diyl)phosphite] and tris(2,4-di-tert-butylphenyl) phosphite; and (b) a N,N-dialkylhydroxylamine. Also disclosed is a method for preparing a polyolefin fiber, film or fabric which includes (A) incorporating the above additives into an olefin polymer, thereby producing a stabilized polyolefin polymer; and (B) extruding the stabilized olefin polymer through a die, thereby producing a olefin polymer fiber or film. A woven or non-woven fabric may be prepared from the olefin polymer fiber or film.

Abstract translation: 聚合物组合物和由其制备的纤维，膜和织物。 该组合物含有（i）除饱和或不饱和脂肪酸的金属盐以外的酸中和剂，（ii）加工助剂，其包含饱和或不饱和脂肪酸的金属盐，饱和或不饱和脂肪酸的金属盐 存在最大量为200ppm的稳定剂体系，其包含（a）选自2,2'，2“ - 次氮基[三乙基 - 三（3,3'，5,5'-四 - 叔丁基-1,1'-联苯-2,2'-二基）亚磷酸酯]和三（2,4-二叔丁基苯基）亚磷酸酯; 和（b）N，N-二烷基羟胺。 还公开了一种制备聚烯烃纤维，膜或织物的方法，其包括（A）将上述添加剂并入烯烃聚合物中，从而制备稳定的聚烯烃聚合物; 和（B）通过模头挤出稳定的烯烃聚合物，由此制备烯烃聚合物纤维或膜。 编织或无纺布可以由烯烃聚合物纤维或薄膜制备。

公开(公告)号：US6147148A

公开(公告)日：2000-11-14

申请号：US141733

申请日：1998-08-27

Applicant: Hiroyuki Tanaka ,  Naoki Yasuda

Inventor： Hiroyuki Tanaka ,  Naoki Yasuda

IPC: C08K5/103 ,  C08K5/11 ,  C08L23/10 ,  C08L23/14 ,  C08L67/00 ,  C08L67/03 ,  C08K5/10

CPC classification number: C08K5/11 ,  C08K5/103 ,  C08L23/10 ,  C08L23/142 ,  C08L2201/08 ,  C08L67/00 ,  C08L67/03 ,  C08L71/02

Abstract: A thermoplastic resin composition comprising a thermoplastic resin, a dibasic acid erythritol ester, a filler and optionally an antioxidant. The dibasic acid erythritol ester, having a degree of esterification of not more than 50%, is added in an amount less than 1 part by weight, per 100 parts by weight of the thermoplastic resin, to improve the thermal aging resistance of the resin.

Abstract translation: 一种热塑性树脂组合物，其包含热塑性树脂，二元酸赤藓糖醇酯，填料和任选的抗氧化剂。 相对于热塑性树脂100重量份，酯化度不超过50％的二元酸赤藓糖醇酯的添加量小于1重量份，以提高树脂的耐热老化性。

公开(公告)号：US5578665A

公开(公告)日：1996-11-26

申请号：US399666

申请日：1995-03-07

Applicant: Primo Carrozza ,  Valerio Borzatta

Inventor： Primo Carrozza ,  Valerio Borzatta

IPC: C07F7/12 ,  C07F7/08 ,  C07F7/18 ,  C07F7/21 ,  C08G77/26 ,  C08G77/38 ,  C08G77/388 ,  C08K5/54 ,  C08K5/5419 ,  C08K5/544 ,  C08K5/55 ,  C08L83/04 ,  C08L83/08 ,  C08L101/00 ,  C07F7/10

CPC classification number: C08K5/5442 ,  C07F7/0854 ,  C07F7/0896 ,  C07F7/184 ,  C08G77/26 ,  C08G77/388 ,  C08L101/00 ,  C08L2201/08

Abstract: The present invention relates to novel piperidine compounds of the formula (I) ##STR1## in which A is e.g. a group of the formula ##STR2## where R.sub.4 is e.g. hydrogen or methyl, X.sub.3 is e.g. --O-- or --NH-- and R.sub.5 ' is e.g. ethylene, propylene or decamethylene, R.sub.1 is e.g. methyl, methoxy, ethoxy or OH, R.sub.2 and R.sub.3 are e.g. methyl, m+n is e.g. a number from 1 to 40, n varies e.g. from zero to 50% of the sum m+n, X.sub.1 is e.g. as defined for R.sub.1 or is a group (CH.sub.3).sub.3 SiO-- and X.sub.2 is e.g. hydrogen, methyl, ethyl, a group (CH.sub.3).sub.3 Si-- or a group ##STR3## and, when m+n is a number from 3 to 10, X.sub.1 and X.sub.2 together also form a direct bond. The compounds of the formula (I) are effective in stabilizing an organic material against thermal, oxidative and light-induced degradation.

公开(公告)号：US5314950A

公开(公告)日：1994-05-24

申请号：US7225

申请日：1993-01-22

Applicant: Balwant Singh ,  Robert J. Tynik

Inventor： Balwant Singh ,  Robert J. Tynik

IPC: C08F22/36 ,  C08F22/40 ,  C08F291/00 ,  C08F291/02 ,  C08L33/24 ,  C08L35/00 ,  C08L35/06 ,  C08L51/04 ,  C08F122/40 ,  C08F222/40

CPC classification number: C08L35/00 ,  C08L35/06 ,  C08L51/04 ,  C08L2201/08

Abstract: Novel resin compositions are provided which possess excellent heat resistance and thermal color stability, alone, or in admixture with bulk resins. The claimed resin compositions comprise homo- and/or copolymers of N-(2,3-dimethylphenyl) maleimide, alone, or in further combination with resins composed of copolymer components, such as vinyl copolymers and rubber-grafted vinyl copolymer resins. The resin compositions have improved heat resistance and produce molded articles with desirably light colors. Also provided is an improved process to make maleimide monomers by using selected polar solvents whereby the amount of uncyclizable trans-amic acid is held at tolerable levels and the desired maleimide is obtained in high yields, free from by-products.

Abstract translation: 提供了新的树脂组合物，它们单独具有优异的耐热性和热色稳定性，或与本体树脂混合。 所要求保护的树脂组合物包含单独的N-（2,3-二甲基苯基）马来酰亚胺或与由共聚物组分如乙烯基共聚物和橡胶接枝的乙烯基共聚物树脂组成的树脂的进一步组合的均聚物和/或共聚物。 树脂组合物具有改善的耐热性，并且生产具有期望的浅色的模塑制品。 还提供了通过使用选择的极性溶剂制备马来酰亚胺单体的改进方法，由此使可循环的反式氨基酸的量保持在可耐受水平，并且以高产率获得所需的马来酰亚胺，不含副产物。

公开(公告)号：US5079281A

公开(公告)日：1992-01-07

申请号：US442185

申请日：1989-11-28

Applicant: Junji Takeuchi ,  Masahiro Takimoto

Inventor： Junji Takeuchi ,  Masahiro Takimoto

IPC: C08K3/04 ,  C08K3/30 ,  C08K3/32 ,  C08K7/00 ,  C08K7/02 ,  C08K7/14 ,  C08K9/00 ,  C08K9/06 ,  C08K13/06 ,  C08L23/00 ,  C08L23/10 ,  C08L23/12 ,  C08L23/26 ,  C08L51/06 ,  C08L91/06

CPC classification number: C08K9/06 ,  C08K3/04 ,  C08K3/30 ,  C08L23/12 ,  C08K7/14 ,  C08L2201/08 ,  C08L51/06 ,  C08L91/06

Abstract: A fiber-reinforced polypropylene resin composition is disclosed, comprising (1) a mixed polymer of polypropylene and carboxyl group containing polypropylene, (2) a silane treated reinforcing fiber, and (3) a coloring component of zinc sulfide and carbon black with a dispersing agent compounded thereto, said dispersing agent is polyethylene wax and the amount of said dispersing agent added to 20 to 50 parts by weight per 100 parts by weight of the zinc sulfide and carbon black.

Abstract translation: 公开了一种纤维增强聚丙烯树脂组合物，其包括（1）聚丙烯和含羧基的聚丙烯的混合聚合物，（2）硅烷处理的增强纤维，和（3）硫化锌和炭黑的着色组分，其分散 所述分散剂为聚乙烯蜡，所述分散剂的添加量相对于硫化锌和炭黑为100重量份为20〜50重量份。

公开(公告)号：US4469829A

公开(公告)日：1984-09-04

申请号：US524360

申请日：1983-08-18

Applicant: Alfred Konietzny ,  Hans-Dieter Zagefka ,  Konrad Rombusch ,  Hanns-Jorg Bax

Inventor： Alfred Konietzny ,  Hans-Dieter Zagefka ,  Konrad Rombusch ,  Hanns-Jorg Bax

IPC: C08C19/40 ,  C08F8/00 ,  C08F8/32 ,  C08L1/00 ,  C08L7/00 ,  C08L9/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  C08K5/34 ,  C07D211/00 ,  C08G59/50 ,  C08K5/51

CPC classification number: C08C19/40 ,  C08L101/00 ,  C08L2201/08

Abstract: Amino-group bearing, low molecular weight 1,3-butadiene polymers used as stabilizers for molded or unshaped plastics in amounts of 0.01 to 2.0 weight percent referred to the plastic, where the amino-group bearing component is derived from a substituted piperidine having the general formula: ##STR1## where R represents similar or different alkyl groups having 1 to 3 carbon atoms.

Abstract translation: 含有氨基的轴承，低分子量1,3-丁二烯聚合物，用作模塑或非塑性塑料的稳定剂，其量为0.01至2.0重量％，指的是塑料，其中含氨基的组分衍生自具有 通式：其中R代表相同或不同的具有1至3个碳原子的烷基。

公开(公告)号：US3661822A

公开(公告)日：1972-05-09

申请号：US3661822D

申请日：1970-04-30

Applicant: UNIROYAL INC

Inventor： LEE CHARLES W

IPC: C08K5/372 ,  C08L23/16 ,  C08F29/10 ,  C08F45/58

CPC classification number: C08K5/372 ,  C08L23/16 ,  C08L63/00 ,  C08L2201/08 ,  C08L2666/22

Abstract: STABILIZATION OF ETHYLENE-PROPYLENE-NON-CONJUGATED DIENE TERPOLYMER (EPDM) ELASTOMERS AGAINST HEAT AGING BY INCORPORATION OF AN EPOXIDE AND AN ORGANIC SULFIDE (E.G., AN OLEFIN OXIDE AND N-OCTYL DISULFIDE).

公开(公告)号：US12129374B2

公开(公告)日：2024-10-29

申请号：US17415690

申请日：2020-09-11

Applicant: LG CHEM, LTD.

Inventor： Bong Keun Ahn ,  Yong Yeon Hwang ,  Min Jung Kim ,  Jang Won Park ,  Jiyoon Jeon ,  Eunji Lee ,  Seyong Kim

IPC: C08L51/00 ,  C08L51/04

CPC classification number: C08L51/003 ,  C08L51/04 ,  C08L2201/08 ,  C08L2207/53

Abstract: The present invention relates to an acrylic graft copolymer, a method of preparing the same, and a thermoplastic resin composition including the same. More specifically, the acrylic graft copolymer of the present invention includes a seed, a core, and a graft shell. In this case, the graft shell includes 0.05 to 2 parts by weight of a reactive ultraviolet stabilizer based on 100 parts by weight of the acrylic graft copolymer, and the graft shell has an average particle diameter of 80 to 140 nm (greater than the average particle diameter of the core). The acrylic graft copolymer of the present invention has excellent impact strength, tensile strength, weather resistance, and surface gloss. In addition, when the acrylic graft copolymer is used, mold deposits may be reduced.

公开(公告)号：US12110385B2

公开(公告)日：2024-10-08

申请号：US17436910

申请日：2020-03-27

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kenichi Matsumura ,  Norikazu Mashino ,  Kento Murakami ,  Nami Nakajima ,  Yasunari Kusaka ,  Takehisa Sugaya ,  Masahiko Yamagata

IPC: C08F8/22 ,  C08L27/24

CPC classification number: C08L27/24 ,  C08F8/22 ,  C08L2201/08 ,  C08L2203/30 ,  C08F8/22 ,  C08F114/06 ,  C08K7/14 ,  C08L27/24 ,  C08L27/24 ,  C08L51/04

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that not only has high heat resistance and high mechanical strength but also is excellent in molding processability and is very easy to soften and additionally enables production of a molded article with high gloss. The present invention relates to a chlorinated polyvinyl chloride resin, containing three components including a A150 component, a B150 component, and a C150 component, and having a percentage of the C150 component (C150 component/(A150 component+B150 component+C150 component)) of 8.0% or more and 30.0% or less, the three components being identified by measuring the chlorinated polyvinyl chloride resin by a solid echo method using pulse NMR at 150° C. to give a free induction decay curve of 1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into three curves derived from the A150 component, the B150 component, and the C150 component in order of shorter relaxation time using the least square method.