Abstract:
Disclosed is a composition for surface conditioning which enables to form a chemical conversion coating of sufficient amount even when it is applied to a metal material such as a high tension steel sheet which is hardly chemically converted. The composition for surface conditioning can be stored as a dispersion for a long time, in which dispersion a titanium phosphate compound stably exists. In addition, the composition exhibits good stability in a bath. Specifically disclosed is a composition for surface conditioning, which contains a titanium phosphate compound while having a specific pH. By blending an amine compound having a specific structure, an aromatic organic acid, a phenol compound, a phenol resin and the like into the composition for surface conditioning, the composition attains good dispersibility and enables to form a chemical conversion coating of sufficient amount.
Abstract:
The invention relates to compatibilized release compositions useful in release layers of release articles (e.g., release liners) and adhesive articles (e.g., pressure sensitive adhesive tapes). The compatibilized release compositions comprise a mixture of a thermoplastic olefin-based polymer comprising an acid or a base functionality and a polymeric release material comprising an acid or a base functionality. The functionality of the thermoplastic olefin-based polymer and the functionality of the polymeric release material are selected to provide an acid-base interaction.
Abstract:
An aqueous coating composition containing: (a) an aqueous carrier medium; (b) pigment having a pH below 7.0; (c) an AB block copolymer pigment dispersant resin of 1) an A block of a hydrophobic polymer having amine groups and 2) a B block of a hydrophilic polymer having hydroxyl groups and carboxyl groups; the AB block copolymer has a number average molecular weight of 5,000-20,000 and contains 20-80 % by weight of a polymeric A segment and correspondingly 80-20 % by weight of a polymeric B segment; wherein the pigment and the dispersant are present in a pigment to dispersant weight ratio of 0.1/1 20/1; (d) a film forming polymeric binder containing carboxyl groups and (e) a crosslinking agent which on curing of the coating composition will react with the carboxyl and hydroxyl groups of the AB block copolymer and the carboxyl groups of the film forming polymeric binder. Pigment dispersions of the AB block copolymer and process for forming the dispersions also are part of this invention.
Abstract:
The invention relates to a bonding agent with barrier properties, comprising: A) at least one compound which is fluid in a range of 18 °C to 100 °C, preferably 20 °C to 80 °C, with at least one reactive functional group which may be hardened by radiation as component (A), B) at least one compound with at least one reactive functional group which may be hardened by radiation and with at least one COOH-group as component (B) and C) at least one nanoscale filler as component (C), preferably selected from the group of oxides, nitrides, halides, sulphides, carbides, tellurides, selenides of the second to fourth main group, transition elements, lanthanides and/or the group of polyorganosiloxanes. The bonding agent is used as a radiation-hardening bonding agent in coating agents, fillers, sealers or adhesives. The invention further relates to a method for the production of composite films with barrier properties against CO2, O2, N2, water vapour and flavourings using said bonding agents and composite films made by said method.
excellent antifouling paint films exhibiting such a preferable film-erosion property and superior antifouling activity that can steadily be maintained for a very long period of time even from the beginning when used in sea-water and having outstanding basic paint-film properties and high water-resistance can be provided; antifouling paint by using of which such excellent antifouling paint films can be formed, which can stably be preserved for long, can be provided; structures used in or in contact with water such as sea-warter, having an antifouling paint film(s) formed by using the antifouling paint of this invention on its surface(s), by using of which such antifouling paint films which can easily prevent the attachment of marine organisms, such as barnacles and the like, to their surface(s) can be provided; and methods for preventing from fouling to prevent the attachment of marine organisms, such as barnacles and the like, to the surface(s) of the hull of ships or structures immersed in or in contact with sea-water can be provided.
Abstract:
An organic solvent-based heat-curable high solid coating composition comprising:
(A) a carboxyl-containing compound having an acid value of 50 to 500 mg KOH/g wherein 20 mol% or more of the carboxyl groups are silylated carboxyl groups, (B) at least one epoxide selected from (B-1) an epoxy-, hydroxyl- and hydrolyzable alkoxysilyl-containing vinyl polymer, (B-2) the vinyl polymer (B-1) wherein 20 mol% or more of the hydroxyl groups are silylated hydroxyl groups, and (B-3) an epoxy compound having a number average molecular weight less than 1,000, and (C) a crosslinked particulate polymer, the composition having a solid content of 65 wt.% or more; and a method for forming a topcoat using the composition. The composition of the invention has a sufficiently high solid content, is capable of forming a coating film with high resistance to acids and the like, and is excellent in low-temperature curability, storage stability and recoat adhesion.
Abstract:
A process for esterifying a polymer containing carboxyl(ate) groups, by maintaining the polymer at 0 °C to 200 °C, where the counterion for the carboxylate groups is a selected ammonium or sulfoxonium ions. Such processes are useful for preparing improved films and coatings, particularly automotive coatings.
Abstract:
This invention relates to an aqueous correction fluid which prevents bleeding of aqueous ink dyes during correction of writing errors. The correction fluid contains an acid-functional polymer modified with an amino functional silane. The aminosilane-modified correction fluid may be substituted for solvent-based fluids, without adversely affecting other properties such as water resistance, opacity and curing.
Abstract:
Beschrieben werden eine Bindemittelzusammensetzung, diese enthaltende Überzugsmittel, Verfahren zu deren Herstellung und die Verwendung der Überzugsmittel zur Herstellung ein ein- oder mehrschichtigen Lackierungen, insbesondere auf dem Kraftfahrzeugsektor. Die Bindemittelzusammensetzung enthält:
A) 25 bis 75 Gew.-% eines oder mehrerer carboxylgruppenhaltiger Harze, die alpha,beta-ungesättigte Gruppen enthalten können, mit einem Zahlenmittel des Molekulargewichts (Mn) von 500 bis 10000 g/Mol und einer Säurezahl von 15 bis 200 mg KOH/g, B) 25 bis 75 Gew.-% eines oder mehrerer Polyether, Polyester, Polyether/Polyester und/oder (Meth)acrylcopolymerer mit mindestens einer alpha,beta-ungesättigten Gruppe und mindestens einer Epoxidgruppe im Molekül, wobei die alpha,beta-ungesättigten Gruppen und Epoxidgruppen im Zahlenverhältnis 20 : 80 bis 80 : 20 vorliegen, mit einem Zahlenmittel des Molgewichts (Mn) von bis zu 10000 g/Mol, C) 0 bis 30 Gew. -% eines oder mehrerer Polyole mit mindestens zwei Hydroxyfunktionen im Molekül,
D₁) 0 bis 20 Gew.-% eines oder mehrerer Melaminharze, D₂) 0 bis 40 Gew.-% eines oder mehrerer verkappter Polyisocyante, wobei sich die Summe der Gew.-% der Komponenten A), B), C), D₁) und D₂) auf 100 Gew.-% addiert, sowie E) 0 bis 10 Gew. -% eines oder mehrerer Katalysatoren zur Katalyse der Reaktion von Carboxyl- und Epoxidgruppen, bezogen auf die Summe der Gewichte der Komponenten A) bis D₂), und F) 0,1 bis 10 Gew.-% eines oder mehrerer thermisch und/oder photochemisch aktivierbarer Radikalinitiatoren, bezogen auf das Gesamtgewicht der Komponenten A) und B).
Abstract:
Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.