公开(公告)号：US07569161B2

公开(公告)日：2009-08-04

申请号：US10570140

申请日：2004-09-01

Applicant: Yuji Nagao ,  Ryuji Yamamoto ,  Toshio Morita

Inventor： Yuji Nagao ,  Ryuji Yamamoto ,  Toshio Morita

IPC: H01B1/24

CPC classification number: C08K7/06 ,  C08J3/201 ,  C08K3/04 ,  C08K2201/016 ,  C08L101/12 ,  H01B1/24

Abstract: The invention provides a production method of a conductive polymer, comprising a step of blending a polymer in a state of a melt viscosity of 600 Pa·s or less at a shear rate of 100 s−1 with a vapor grown carbon fiber in 1 to 15 mass at a mixing energy of 1,000 mJ/m3 or less, and a conductive polymer obtained thereby. Preferably, a vapor grown carbon fiber used has an outer fiber diameter of 80 to 500 nm, an aspect ratio of 40 to 1,000, a BET specific surface area of 4: to 30 m2/g, a do02 of 0.345 nm or less according to an X-ray diffraction method, and a ratio (Id/Ig) of 0.1 to 2 wherein Id and Ig each represent peak heights of a band ranging from 1,341 to 1,349 cm−1 and a band ranging from 1,570 to 1,578 cm−1 respectively, according to a Raman scattering spectrum. According to the invention, an excellent conductivity can be attained by compounding vapor grown carbon fiber in a smaller amount than in a conventional method.

Abstract translation: 本发明提供一种导电聚合物的制造方法，包括以100s -1的剪切速度将熔融粘度为600Pa·s以下的聚合物与气相生长碳纤维在1〜 15质量份，混合能量为1,000mJ / m 3以下，由此得到的导电性聚合物。 优选使用的气相生长碳纤维的外纤维直径为80〜500nm，纵横比为40〜1000，BET比表面积为4〜30m 2 / g，do02为0.345nm以下，根据 X射线衍射法和0.1〜2的比（Id / Ig），其中Id和Ig分别表示1,341〜1349cm -1的谱带的峰高和1,570〜1578cm -1的谱带 ，根据拉曼散射光谱。 根据本发明，可以通过以比常规方法更少的量将气相生长的碳纤维复合而获得优异的导电性。

公开(公告)号：US20090170987A1

公开(公告)日：2009-07-02

申请号：US12078625

申请日：2008-04-02

Applicant: Kenji Kimura ,  Ryoji Soma

Inventor： Kenji Kimura ,  Ryoji Soma

IPC: C08K5/527

CPC classification number: C08J3/201 ,  C08J2323/12 ,  C08K5/098 ,  C08K5/527

Abstract: An object of the present invention is to provide a process for producing a thermoplastic resin composition with a further improved hue, containing a neutralizing agent, and a compound (I).There is provided a process for producing a thermoplastic resin composition, comprising a second step of melting-kneading a melting-kneaded product obtained in a first step, and a compound (I). (wherein two R1s, two R2s, R4 and R5 each represent independently a hydrogen atom, an alkyl group etc., two R3s each represent independently a hydrogen atom or an alkyl group, X represents a single bond, a sulfur atom or a —CHR6— group, wherein R6 represents a hydrogen atom, an alkyl group etc., A represents an alkylene group or a *—COR7— group, wherein R7 represents a single bond or an alkylene group, and a symbol * represents a bond with an oxygen atom of a >P—O— portion,one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group, and the other of Y and Z represents a hydrogen atom, or an alkyl group.)

Abstract translation: 本发明的目的是提供一种具有进一步改善的色调，含有中和剂和化合物（I）的热塑性树脂组合物的制备方法。 提供了一种热塑性树脂组合物的制造方法，包括对第一工序中得到的熔融混炼物进行熔融捏合的第二工序和化合物（I）。 （其中两个R 1，两个R 2，R 4和R 5各自独立地表示氢原子，烷基等，两个R 3各自独立地表示氢原子或烷基，X表示单键，硫原子或-CHR 6 - 基，其中R6表示氢原子，烷基等，A表示亚烷基或* -COR7-基团，其中R7表示单键或亚烷基，符号*表示与氧的键 原子的一个PO-部分，Y和Z之一表示羟基，烷氧基或芳烷氧基，Y和Z中的另一个表示氢原子或烷基。

公开(公告)号：US20090108488A1

公开(公告)日：2009-04-30

申请号：US11988311

申请日：2006-08-03

Applicant: Kazuaki Matsumoto

Inventor： Kazuaki Matsumoto

IPC: B29C47/50 ,  C08K3/10 ,  C08K3/22 ,  B29C47/38 ,  C08K3/34

CPC classification number: C08K5/5415 ,  B29C48/40 ,  C08J3/201

Abstract: Provided is a process for continuous production of an organic-inorganic hybrid polymeric material in which inorganic substances are finely dispersed in a resin on a nanometer order, on an industrial scale without using any organic solvent or the like by using a simple apparatus. In the process, a thermoplastic resin having an acid number falling within a range from 1 to 200 mgKOH/g is melted and incorporated, to produce a composite composition, with an inorganic component formed from a metal alkoxide compound and/or a partial condensate thereof in the absence of an organic solvent capable of dissolving a thermoplastic resin. It is preferable to melt-knead by using as a production apparatus a continuous kneading apparatus including a twin screw extruder.

Abstract translation: 本发明提供一种连续制造有机 - 无机复合聚合材料的方法，其中通过使用简单的装置，无机物质以工业规模以纳米级细分散在树脂中而不使用任何有机溶剂等。 在该方法中，将酸值在1〜200mgKOH / g范围内的热塑性树脂熔融并合并，制成复合组合物，其中由无机成分由金属醇盐化合物和/或其部分缩合物形成 在不存在能够溶解热塑性树脂的有机溶剂的情况下。 优选使用包括双螺杆挤出机的连续捏和装置作为生产设备进行熔融捏合。

公开(公告)号：US07465387B2

公开(公告)日：2008-12-16

申请号：US11388238

申请日：2006-03-22

Applicant: Thomas A. Golubic ,  Kenneth C. Krupinski ,  William E. Saver ,  David R. Snyder ,  Robert H. Wombles

Inventor： Thomas A. Golubic ,  Kenneth C. Krupinski ,  William E. Saver ,  David R. Snyder ,  Robert H. Wombles

IPC: C10C3/06

CPC classification number: C10L1/322 ,  B29C47/0004 ,  B29C47/0009 ,  B29C47/92 ,  B29C2947/92704 ,  C04B35/522 ,  C04B35/532 ,  C04B35/83 ,  C04B2235/6021 ,  C04B2235/614 ,  C04B2235/77 ,  C04B2235/96 ,  C08J3/201 ,  C08J2395/00 ,  C08L95/00 ,  C08L2555/54 ,  C10C1/16 ,  C10C3/002 ,  C10C3/06 ,  F16D69/023

Abstract: A method of making a carbon/graphite product using a coal tar pitch having a softening point in the range of about 150° C. to 250° C. Also, a carbon/graphite product having a softening point in the range of about 150° C. to 250° C. A method of making mesophase pitch is formed from quinoline insoluble free coal tar pitch distillate from a high efficiency evaporative distillation process.

Abstract translation: 使用软化点在约150℃至250℃范围内的煤焦油沥青制备碳/石墨产品的方法。此外，软化点在约150℃范围内的碳/石墨产品 C.至250℃。从喹啉不溶性游离煤焦油沥青馏出物由高效蒸发蒸馏过程形成中间相沥青的方法。

公开(公告)号：US20080237914A1

公开(公告)日：2008-10-02

申请号：US12079340

申请日：2008-03-26

Applicant: Arnold Lustiger ,  Jennifer Harting Ward ,  Patrick Bormann ,  David Jon Starz ,  Alan J. Oshinski

Inventor： Arnold Lustiger ,  Jennifer Harting Ward ,  Patrick Bormann ,  David Jon Starz ,  Alan J. Oshinski

IPC: B29B9/06 ,  B29C47/60

CPC classification number: C08F255/02 ,  B29C48/39 ,  B29C48/535 ,  B29C48/57 ,  C08J3/201 ,  C08J5/046 ,  C08J5/047 ,  C08J2323/10 ,  C08K3/01 ,  C08K5/00 ,  C08L23/10 ,  C08L23/12 ,  C08L33/20 ,  C08L51/06 ,  C08L67/00 ,  C08L2205/16 ,  C08L2666/20 ,  C08L2666/06 ,  C08L2666/02 ,  C08L2666/18 ,  C08L2666/14 ,  C08L2666/04

Abstract: The present disclosure is directed generally to methods for making fiber reinforced polypropylene composite pellets using pre-cut fiber fed to a compounding extruder by improved fiber feeder systems. One form of the method includes feeding into a compounding extruder at least 25 wt % polypropylene based polymer, from 5 to 60 wt % pre-cut organic fiber, and from 0 to 60 wt % inorganic filler; and extruding, cooling and pelletizing the resultant mixture of components to form fiber reinforced polypropylene composite pellets; wherein the pre-cut organic fiber is fed from a feeder including a feeder hopper, one or more conditioning augers/agitators, one or more metering augers below the feeder hopper, and a means for controlling the speed of the conditioning augers/agitators and metering augers; and wherein an article molded from the pellets has a flexural modulus of at least 2.07 GPa and exhibits ductility during instrumented impact testing. In another form, the feeder includes a feeder hopper, two or more counter-rotating metering rollers, one or more separating rollers below the metering rollers, and a means for controlling the speed of the metering rollers and separating rollers. In yet another form, a circle feeder may be used to feed the pre-cut fiber.

Abstract translation: 本公开一般涉及使用通过改进的纤维馈送系统进料到配混挤出机的预切纤维来制备纤维增强聚丙烯复合颗粒的方法。 该方法的一种形式包括将至少25重量％的聚丙烯基聚合物，5至60重量％的预切割有机纤维和0至60重量％的无机填料进料到配混挤出机中; 挤出，冷却和造粒所得的组分混合物以形成纤维增强聚丙烯复合颗粒; 其中预切的有机纤维从包括进料器料斗，一个或多个调理螺旋推运器/搅拌器，在进料斗下方的一个或多个计量螺旋推运器的进料器进给，以及用于控制调节螺旋推料器/搅拌器和计量的速度的装置 螺旋钻 并且其中由颗粒模制的制品具有至少2.07GPa的弯曲模量并且在仪表式冲击试验期间具有延展性。 在另一种形式中，进料器包括进料斗，两个或多个反向旋转计量辊，计量辊下方的一个或多个分离辊，以及用于控制计量辊和分离辊的速度的装置。 在另一种形式中，可以使用圆形进给器来进给预切割的纤维。

公开(公告)号：US20080132635A1

公开(公告)日：2008-06-05

申请号：US11987253

申请日：2007-11-28

Applicant: Toru Noguchi ,  Akira Magario ,  Kazuyuki Yokoyama

Inventor： Toru Noguchi ,  Akira Magario ,  Kazuyuki Yokoyama

IPC: C08K7/02 ,  C08K3/04

CPC classification number: C08K5/14 ,  C08C19/08 ,  C08J3/201 ,  C08J5/042 ,  C08J2321/00 ,  C08K7/06 ,  C08L21/00

Abstract: A method of producing a carbon fiber composite material including: (a) masticating an elastomer to reduce the molecular weight of the elastomer to obtain a liquid elastomer; (b) mixing the elastomer obtained in the step (a) and carbon nanofibers having an average diameter of 0.5 to 500 nm to obtain a mixture; (c) increasing the molecular weight of the elastomer in the mixture obtained in the step (b) to obtain a rubbery elastic mixture; and (d) mixing the rubbery elastic mixture obtained in the step (c) to disperse the carbon nanofibers in the elastomer by a shear force to obtain a carbon fiber composite material.

Abstract translation: 一种碳纤维复合材料的制造方法，其特征在于，包括：（a）捏合弹性体以降低弹性体的分子量，得到液体弹性体; （b）将步骤（a）得到的弹性体与平均直径为0.5〜500nm的碳纳米纤维混合，得到混合物; （c）增加步骤（b）中获得的混合物中弹性体的分子量，得到橡胶弹性混合物; 和（d）将由步骤（c）得到的橡胶状弹性混合物混合，通过剪切力将碳纳米纤维分散在弹性体中，得到碳纤维复合材料。

公开(公告)号：US07300512B2

公开(公告)日：2007-11-27

申请号：US10495258

申请日：2002-02-22

Applicant: Darren Mark Ortalano ,  Jeffrey S. Carpenter ,  David Dick ,  Lisa Soni Adams

Inventor： Darren Mark Ortalano ,  Jeffrey S. Carpenter ,  David Dick ,  Lisa Soni Adams

IPC: C09C3/08 ,  C09C1/24 ,  C09B67/10 ,  C09B67/20

CPC classification number: C08J3/201 ,  C01P2004/51 ,  C01P2006/22 ,  C01P2006/60 ,  C01P2006/80 ,  C08J3/203 ,  C08J2391/00 ,  C08L91/00 ,  C08L91/06 ,  C09B67/0091 ,  C09C1/24 ,  C09C3/08 ,  C09C3/10

Abstract: A process of dispersing at least one pigment into a carrier such as castor oil or a vegetable wax such as palm oil glyceride wax. The resulting dispersion exhibits excellent color development and is fluid at room temperature. Suitable pigments include FD&C, D&C and inorganic pigments.

Abstract translation: 将至少一种颜料分散在载体如蓖麻油或植物蜡如棕榈油甘油酯蜡中的方法。 所得分散体显示出优异的显色性，并且在室温下是流体。 合适的颜料包括FD＆C，D＆C和无机颜料。

公开(公告)号：US20070268734A1

公开(公告)日：2007-11-22

申请号：US11596060

申请日：2005-05-10

Applicant: Shinya Fukui

Inventor： Shinya Fukui

IPC: C08J3/20

CPC classification number: G01N33/442 ,  B29C37/00 ,  B29C45/0013 ,  B29C2037/80 ,  B29C2037/90 ,  B29K2105/0052 ,  B29K2105/16 ,  B29K2995/0018 ,  C08J3/201

Abstract: A method for producing thermoplastic plastic capable of grasping information concerning the production process even after distribution. In a plurality of production processes including fusion of thermoplastic plastic 90, an information presenting substance 91 is added to the thermoplastic plastic sequentially and dispersed therein in each of the production process, wherein the information presenting substance is associated with information concerning each of the production process and radiates fluorescence upon an irradiation of an electromagnetic wave in a specified wavelength region.

Abstract translation: 即使在分配后也能够掌握有关生产工艺的信息的热塑性塑料的制造方法。 在包括热塑性塑料90的融合在内的多个制造方法中，将信息呈现物质91依次添加到热塑性塑料中并分散在其中，其中所述信息呈现物质与关于每个生产过程的信息相关联 并且在特定波长区域中的电磁波的照射下照射荧光。

公开(公告)号：US20070259993A1

公开(公告)日：2007-11-08

申请号：US11470831

申请日：2006-09-07

Applicant: Toru YAMAGUCHI

Inventor： Toru YAMAGUCHI

IPC: C08G59/42

CPC classification number: C08J3/201 ,  C08J2371/12 ,  C08K3/013 ,  C08L71/12 ,  C08L25/00

Abstract: Mass productivity and production stability of a polyphenylene ether composition are improved without deteriorating physical properties by means of a production process of polyphenylene ether composition comprising pre-melt compounding 20 to 98.5% by mass of a polyphenylene ether powder (I), 1 to 60% by mass of an inorganic filler powder (II) and 0.5 to 20% by mass of a thermoplastic elastomer having functional group (III), followed by melt compounding; wherein melt compounding is conducted using a twin-screw extruder having a total length of barrels of 800 mm or more, and a pre-melt compounding zone occupies 45 to 80 % of upstream of the twin-screw extruder based on the total length 100% of the twin-screw extruder when a drive side and a molten compound discharging side of the twin-screw extruder are regarded as upstream and downstream, respectively.

Abstract translation: 通过聚苯醚组合物的制造方法，聚醚醚类组合物的质量生产率和生产稳定性得到改善，不会使物理性能下降，其中包括预熔混合20〜98.5质量％的聚苯醚粉末（I），1〜60％ 的无机填料粉末（II）和0.5〜20质量％的具有官能团（III）的热塑性弹性体，然后熔融配混; 其中使用总长度为800mm以上的双螺杆挤出机进行熔融配混，并且预熔化合物区占双螺杆挤出机的总长度的100％的上游的45〜80％ 的双轴挤出机的驱动侧和熔融化合物排出侧分别被认为是上游和下游。

公开(公告)号：US20070225409A1

公开(公告)日：2007-09-27

申请号：US10591075

申请日：2005-02-23

Applicant: Kazuaki Matsumoto

Inventor： Kazuaki Matsumoto

IPC: C08L101/00

CPC classification number: C08K5/098 ,  B22F1/0018 ,  B22F1/0059 ,  B22F2999/00 ,  B82Y30/00 ,  C08J3/201 ,  C08K5/057 ,  H05K1/095 ,  B22F9/30

Abstract: A method for producing a thermoplastic resin composition containing ultrafine particles on an industrial scale is provided. The method for producing the thermoplastic resin composition containing ultrafine particles includes mixing a metal-containing organic compound with a thermoplastic resin; and then heating the resulting mixture at a temperature of not lower than the decomposition starting temperature and lower than the complete decomposition temperature of the metal-containing organic compound to produce a composition containing ultrafine metal particles and/or ultrafine metal oxide particles having a number-average particle size of 0.1 to 80 nm dispersed in the thermoplastic resin.

Abstract translation: 提供了一种以工业规模生产含有超细颗粒的热塑性树脂组合物的方法。 含有超微粒子的热塑性树脂组合物的制造方法包括将含金属的有机化合物与热塑性树脂混合; 然后在不低于分解开始温度并且低于含金属有机化合物的完全分解温度的温度下加热所得混合物，以制备含有数均分子量的超细金属颗粒和/或超细金属氧化物颗粒的组合物， 分散在热塑性树脂中的平均粒度为0.1〜80nm。