Molybdenum recovery from epoxidate
    385.
    发明公开
    Molybdenum recovery from epoxidate 失效
    MolybdäneWiedergebung aus Epoxidaten

    公开(公告)号:EP0742047A2

    公开(公告)日:1996-11-13

    申请号:EP96303414.5

    申请日:1996-05-13

    Inventor: Evans, Thomas I.

    Abstract: Epoxidate from the molybdenum catalyzed epoxidation of an olefin such as propylene with a hydroperoxide such as ethylbenzene hydroperoxide is treated with 2 to 15 times the stoichiometric equivalent of aqueous base such as sodium hydroxide to form the molybdate and the resulting mixture is phase separated to separate an organic phase reduced in molybdenum and a net aqueous stream containing removed molybdenum, the mass ratio of the organic phase to the net aqueous stream being 450-3,000/l.

    Abstract translation: 选择性地从环氧化物混合物中除去Mo值。 包括产物。 的烯烃与有机氢过氧化物的催化环氧化反应:(a)处理混合物。 用一个水 (等于形成钼酸盐的2-15倍); (b)sepg。 混合 成为一个水平 相位限制 大部分Mo和有机相; 和(c)sepg。 从aq。 流的相位contg 净Mo值除去有机相的重量比:流量 净Mo值= 450-3000:1。

    Process for the production of formates
    390.
    发明公开
    Process for the production of formates 失效
    一种用于甲酸酯的制备过程。

    公开(公告)号:EP0104875A1

    公开(公告)日:1984-04-04

    申请号:EP83305550.2

    申请日:1983-09-21

    Abstract: An alkyl ester of formic acid is prepared by reacting carbon monoxide with an alcohol in the presence, as catalyst, of (a) a guanidine or (b) an amidine and an epoxide.
    The amidine or guanidine structure can be cyclic. The process can be operated in the liquid phase at pressures from 20 to 120 bars and temperatures from 40 to 150°C with excess carbon monoxide over that required for conversion of the alcohol to the formate ester.

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