Abstract:
A composition of an oil-soluble ionic detergent that does not contribute metal ions to the composition, and which comprises a quaternary non-metallic pnictogen cation and an organic anion having at least one hydrocarbyl group of sufficient length to impart oil solubility to the detergent, the detergent having a total base number (TBN) to total acid number (TAN) ratio of at least 2:1 imparts ash-free basicity to a lubricant composition.
Abstract:
A composition of an oil-soluble ionic detergent that does not contribute metal ions to the composition, and which comprises a quaternary non-metallic pnictogen cation and an organic anion having at least one hydrocarbyl group of sufficient length to impart oil solubility to the detergent, the detergent having a total base number (TBN) to total acid number (TAN) ratio of at least 2:1 imparts ash-free basicity to a lubricant composition.
Abstract:
A perfluoropolyether, a composition comprising the perfluoropolyether, a process for producing the perfluoropolyether, and a process for improving the thermostability of grease or lubricant are provided. The perfluoropolyether comprises perfluoroalkyl radical end groups in which the radical has at least 3 carbon atoms per radical and is substantially free of perfluoromethyl and perfluoroethyl end groups. The process for producing the perfluoropolyether can comprise (1) contacting a perfluoro acid halide, a C2- to C4-substituted ethyl epoxide, or a C3+ fluoroketone with a metal halide to produce an alkoxide; (2) contacting the alkoxide with either hexafluoropropylene oxide or tetrafluorooxetane to produce a second acid halide; (3) esterifying the second acid halide to an ester; (4) reducing the ester to its corresponding alcohol; (5) converting the alcohol with a base to a salt form; (6) contacting the salt form with a C3 or higher olefin to produce a fluoropolyether; and (7) fluorinating the fluoropolyether. The process for improving the thermostability of a grease or lubricant comprises combining the grease or lubricant with the composition.
Abstract:
The present invention provides a grease composition which is excellent in peel resistance, not to mention lubricity, as compared with the prior art products. A novel grease composition for rolling bearing is provided, comprising a base oil, an extender, an inorganic compound-based filler having an average particle diameter of not more than 2 &mgr;m and zinc dithiocarbamate.
Abstract:
Waterborne lubricants comprising: (A) water-soluble inorganic salt; (B) homogeneously dispersed solid lubricant; (C) at least one homogeneously emulsified substance selected from mineral oils, animal and plant oils and fats, and synthetic oils; (D) surfactant; and (E) water, in which the weight ratio (B)/(A) is from 0.05:1 to 2:1 and the weight ratio {C/(A+B)} is from 0.05:1 to 1:1, provide a one-step, highly lubricating waterborne lubricant for use in the cold plastic working of metals. This waterborne lubricant can replace the conversion coating treatment (phosphate, oxalate, etc.)+reactive soap treatment combined lubrication system now in general use and is free of the environmental issues associated with the combined lubrication system, provides for facile coating removal, and is not subject to the decline in seizure resistance caused by nonuniform add-on when large numbers of workpieces are treated together by immersion.
Abstract:
A self-lubricating coating is provided which includes a mixture of a curable acrylate composition including a dipentaerythritol pentaacylate and a solid lubricant, such as polytetraflourethylenr. The curable acrylate composition may also include triethylene glycol dimethacrylate. An aramid pulp may also be added to the coating mixture. Also disclosed is a method of manufacturing the coating, and a self-lubricating bearing having the coating disposed on its surface.
Abstract:
Mucilages and mucilage extracts are disclosed that are effective as water-soluble, non-toxic, biodegradable, environmentally benign lubricants and/or coolants for a variety of industrial and machining purposes. One embodiment of the invention is a cooling and/or lubricating composition comprises a sufficient amount of the mucilage to cool and/or lubricate a machining surface. Other embodiments further comprise a sufficient amount of a preservative to substantially inhibit degradation of the composition. Also encompassed within the scope of this invention are methods for making mucilage-comprising cooling and/or lubricating compositions, as well as concentrating and drying such compositions. Other aspects of this invention are methods for machining a surface, comprising extracting a mucilage, adding a sufficient amount of a preservative to substantially inhibit degradation of the mucilage to form a mucilage mixture, applying the mucilage mixture to a surface to be machined, and thereafter machining the surface. In another aspect, the invention provides methods for lubricating and/or cooling a machining surface comprising extracting a mucilage, adding a sufficient amount of a preservative to substantially inhibit degradation of the mucilage to form a mucilage mixture, and applying the mucilage mixture to the machining surface to act as a lubricant and/or coolant. A farther aspect of this invention is the use of plant mucilages to coat the outer hull of watercraft, thereby reducing friction and drag, and increasing the speed of the craft. Optionally, such a composition may further comprise a cream wax.
Abstract:
The present invention relates to a method for mechanical working of metal and other solid materials with a cooling and lubricating composition containing a major portion of carbon dioxide and a minor portion of a polar lubricant containing at least one polar organic compound with at least one oxygen atom. The polar groups may be selected from the group consisting of the ether, hydroxyl, carboxyl, ester and amido group or mixtures thereof.
Abstract:
Low bleed silicone grease compositions are prepared by blending high viscosity silicone oils with filler materials and/or silicone elastomers. Greases comprise three main types: I) grease comprising high viscosity silicone oil and filler material, II) grease comprising high viscosity silicone oil and silicone elastomer, and III) grease comprising high molecular weight silicone oil and filler material and silicone elastomer.
Abstract:
In accordance with the method according to the invention, for the production of the plastics overlay, first of all a paste is made of a plastics dispersion and fillers. This paste is free of organic solvents and is applied to a sintered porous metal layer. The multilayer material thus produced is then sintered. Since the use of organic solvents is dispensed with, health risks and the risk of fire are reduced. Moreover, the composite materials produced according to the invention exhibit excellent cavitation resistance. In addition to conventional lubricant-free applications, such as bearings, these composite materials may consequently be used in particular in gear pumps and shock absorbers.