Process for producing copper nanoparticles
    382.
    发明授权
    Process for producing copper nanoparticles 有权
    生产铜纳米粒子的方法

    公开(公告)号:US07422620B2

    公开(公告)日:2008-09-09

    申请号:US10997220

    申请日:2004-11-23

    Abstract: The present invention provides a process for producing copper nanoparticles, comprising steps of: a) reacting an aqueous solution containing a reductant with an aqueous solution of a copper salt while stirring for 1-8 min, wherein the reductant being one or more selected from a group consisting of hydrazine hydrate, sodium borohydride and sodium hypophosphite; b) adding an apolar organic solution containing the extracting agent and continuing the stirring for 0.5-1.5 hrs, said extracting agent being one or more selected from the group consisting of alkyl dithiocarbonic acid and salts thereof, O,O′-dialkyl dithiophosphoric acid and salts thereof, and dialkylamino dithioformic acid and salts and said apolar organic solution being one selected from the group consisting of benzene, toluene and straight or branched alkanes having 6-12 carbon atoms, wherein the alkyl having 6-20 carbon atoms; and c) post-treating the reaction product to obtain copper nanoparticles.

    Abstract translation: 本发明提供一种生产铜纳米颗粒的方法,包括以下步骤:a)在搅拌1-8分钟的同时使含有还原剂的水溶液与铜盐水溶液反应,其中还原剂是选自以下的一种或多种: 由水合肼,硼氢化钠和次磷酸钠组成的组; b)加入含有提取剂的非极性有机溶液并继续搅拌0.5-1.5小时,所述提取剂是选自烷基二硫代碳酸及其盐,O,O-二烷基二硫代磷酸和 其盐和二烷基氨基二硫代甲酸及其盐,所述非极性有机溶液选自苯,甲苯和具有6-12个碳原子的直链或支链烷烃,其中具有6-20个碳原子的烷基; 和c)对反应产物进行后处理以获得铜纳米颗粒。

    Antioxidant compositions and industrial fluids containing same
    389.
    发明授权
    Antioxidant compositions and industrial fluids containing same 失效
    含有其的抗氧化剂组合物和工业流体

    公开(公告)号:US06764983B1

    公开(公告)日:2004-07-20

    申请号:US10187184

    申请日:2002-07-01

    Abstract: The present invention provides new compounds that can be used as antioxidants for either molecules that do not conation ester groups or esters of alcohols that contain two or more ester groups per molecule wherein at least two of the ester groups are on adjacent carbons in the alcohol moiety. Copper ions can enhance the antioxidization activity of the new compounds. Compositions containing one of the new compound and methods of using the new compounds are disclosed.

    Abstract translation: 本发明提供了新的化合物,其可以用作不分配酯基团的分子的抗氧化剂或每分子含有两个或更多个酯基团的醇酯,其中至少两个酯基在醇部分中的相邻碳上 。 铜离子可以增强新化合物的抗氧化活性。 公开了含有新化合物之一的组合物和使用新化合物的方法。

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