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公开(公告)号：WO2015031182A1
公开(公告)日：2015-03-05
申请号：PCT/US2014/052239
申请日：2014-08-22
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： SCHULTZ, Mitchell, Jo , BINDER, Thomas, P. , SUDHARSAN, Naveen , HILALY, Ahmad
CPC classification number: C07C51/47 , B01D15/1821 , B01D15/364 , C07B63/00 , C07C45/52 , C07C51/215 , C07C51/252 , C07C51/36 , C07C51/377 , C07C67/303 , C07C67/317 , C07C67/56 , C07C57/04 , C07C53/122 , C07C69/24 , C07C69/54
Abstract: Methods are provided for producing a reduced propionic acid content acrylic acid product having a propionic acid content comparable to acrylic acid products from the conventional two stage oxidation of propylene, but wherein the acrylic acid has been produced by oxidation of propane, by dehydration of glycerol to an acrolein intermediate and oxidation of the acrolein intermediate to acrylic acid, by dehydration of lactic acid or one or more lactate esters or by any combination of these source processes and otherwise is characterized by having excess propionic acid compared to a glacial acrylic acid conventionally prepared from propylene.
Abstract translation: 提供了用于制备丙烯酸含量降低的丙酸含量与丙烯酸的常规二阶段氧化相当的丙酸含量的丙烯酸还原反应的方法，但丙烯酸已经通过丙烷的脱水生成丙烯酸， 丙烯醛中间体和丙烯醛中间体氧化成丙烯酸，通过乳酸或一种或多种乳酸酯的脱水，或通过这些来源方法的任何组合，或其它方面的特征是具有过量的丙酸，与常规制备的冰丙烯酸相比， 丙烯。
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32.发明申请IMPROVED USE OF BYPRODUCT ACETIC ACID FROM OXIDATIVE METHODS OF MAKING ACRYLIC ACID AND/OR METHACRYLIC ACID 审中-公开从制备丙烯酸和/或甲基丙烯酸的氧化方法改进使用副产物的酸
公开(公告)号：WO2015012876A1
公开(公告)日：2015-01-29
申请号：PCT/US2013/067053
申请日：2013-10-28
Inventor： SUN, Junming , LIU, Changjun , WANG, Yong , SMITH, Colin , MARTIN, Kevin , VENKITASUBRAMANIAN, Padmesh
CPC classification number: C07C2/10 , C07C1/2078 , C07C51/252 , C07C2521/06 , C07C2523/06 , C07C11/09 , C07C11/18 , C07C9/21 , C07C57/04 , C07C53/08
Abstract: Processes are described for improved utilization of the byproduct acetic acid universally produced in various oxidative processes for making acrylic acid and methacrylic acid, wherein at least a portion of the byproduct acetic acid is converted to isobutene and optionally to one or more further value-added products which may be prepared from isobutene.
Abstract translation: 描述了用于改进在用于制备丙烯酸和甲基丙烯酸的各种氧化方法中普遍生产的副产物乙酸的方法，其中副产物乙酸的至少一部分转化为异丁烯并任选地转化成一种或多种其它增值产物 其可以由异丁烯制备。
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33.发明申请5-(HYDROXYMETHYL) FURAN-2-CARBALDEHYDE (HMF) SULFONATES AND PROCESS FOR SYNTHESIS THEREOF 审中-公开5-（羟甲基）呋喃二羧酸（HMF）磺酸盐及其合成方法
公开(公告)号：WO2014179156A1
公开(公告)日：2014-11-06
申请号：PCT/US2014/035395
申请日：2014-04-25
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： STENSRUD, Kenneth
IPC: C07D307/48
CPC classification number: C07D307/46 , C07C51/41 , C07D307/48 , C07D307/52 , C07D307/54
Abstract: 5-(hydroxymethyl) furan-2-carbaldehyde (HMF)-sulfonates and a method of preparing the same are described. The method involves reacting a mixture of 5-(hydroxymethyl)furfural (HMF), with at least one of a) a trifluoromethanesulfonate anhydride (triflate), b) a p -toluene-sulfonyl halide (tosylate), and c) methane-sulfonyl halide (mesylate), and a reagent of either 1) a nucleophilic base or 2) a combination of a non-nucleophilic base and a nucleophile. The HMF-sulfonates (e.g., triflate, tosylate, mesylate, etc. analogs of HMF) can serve as precursor materials from which various derivative compounds can be synthesized.
Abstract translation: 描述了5-（羟甲基）呋喃-2-甲醛（HMF） - 磺酸盐及其制备方法。 该方法包括使5-（羟甲基）糠醛（HMF）与a）三氟甲磺酸酐（三氟甲磺酸酯），b）对甲苯磺酰卤（甲苯磺酸酯）中的至少一种和c）甲磺酰基 卤化物（甲磺酸酯）和1）亲核碱的试剂或2）非亲核碱和亲核试剂的组合。 HMF-磺酸盐（例如，HMF的三氟甲磺酸酯，甲苯磺酸酯，甲磺酸酯等）类似物可以用作可以合成各种衍生化合物的前体材料。
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公开(公告)号：WO2014137619A1
公开(公告)日：2014-09-12
申请号：PCT/US2014/017563
申请日：2014-02-21
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： STENSRUD, Kenneth , HAGBERG, Erik , HOWARD, Stephen , ROCKAFELLOW, Erin M.
CPC classification number: C07D493/04
Abstract: A process is described for the acid-catalyzed dehydration of a sugar alcohol, wherein the catalyst comprises a water-tolerant Lewis acid. In particular embodiments, the catalyst comprises a homogeneous water-tolerant Lewis acid, especially a homogeneous Lewis acid selected from the group consisting of bismuth (III) triflate, gallium (III) triflate, scandium (III) triflate, aluminum triflate, tin (II) triflate and indium (III) triflate. Such catalysts are effective for dehydrating both of sorbitol and the 1,4-sorbitan dehydration precursor of isosorbide, and bismuth (III) triflate particularly is beneficial for dehydrating mannitol to isomannide.
Abstract translation: 描述了用于糖醇的酸催化脱水的方法，其中所述催化剂包含耐水路易斯酸。 在特定实施方案中，催化剂包含均相耐水路易斯酸，特别是选自三氟甲磺酸铋（III），三氟甲磺酸镓（III），三氟甲磺酸钪（III），三氟甲磺酸铝，二（二 ）三氟甲磺酸盐和铟（III）三氟甲磺酸盐。 这种催化剂对山梨糖醇和异山梨醇的1,4-脱水山梨糖醇脱水前体的脱水是有效的，并且三氟甲磺酸铋（III）特别有利于将甘露糖醇脱水成异麦芽糖苷。
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公开(公告)号：WO2014137576A1
公开(公告)日：2014-09-12
申请号：PCT/US2014/016758
申请日：2014-02-18
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： STENSRUD, Kenneth
IPC: C07D493/04 , A61K31/424
CPC classification number: C07D493/04 , C07D519/00
Abstract: Isohexide monotriflate compounds and a method of preparing the same are described. The method involves reacting a mixture of an isohexide, a trifluoromethanesulfonate anhydride, and either 1) a nucleophilic base or 2) a combination of a non-nucleophilic base and a nucleophile. The isohexide monotriflate compounds can serve as precursor materials from which various derivative compounds can be synthesized.
Abstract translation: 描述了异己烯单萜化合物及其制备方法。 该方法包括使异丙醚，三氟甲烷磺酸酐和1）亲核碱或2）非亲核碱和亲核试剂的组合的混合物反应。 异己烯单萜化合物可以作为可以合成各种衍生化合物的前体材料。
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Patent Agency Ranking36.发明申请
公开(公告)号：WO2014100526A1
公开(公告)日：2014-06-26
申请号：PCT/US2013/076773
申请日：2013-12-20
Applicant: ARCHER DANIELS MIDLAND COMPANY , INSTITUTE OF CELL BIOLOGY
Inventor： SEMKIV, Marta , DMYTRUK, Kostyantyn , SIBIRNY, Andriy, A. , ABBAS, Charles
CPC classification number: C12P7/06 , C12N9/16 , C12Y301/03001 , Y02E50/16 , Y02E50/17
Abstract: Described herein is a method to increase ethanol yield during alcoholic fermentation by expression a truncated versions of the Saccharomyces cerevisiae PHO8 gene coding for vacuolar or cytosolic form of alkaline phosphatase, which expression lowers biomass accumulation while diverting greater carbon to ethanol production. Also described are as nucleic acid sequences and vectors for expression of the PHO8 gene and strains carrying the same. Strains containing intact PHO8 gene encoding vacuolar form of alkaline phosphatase, had slightly lower intracellular ATP levels with insignificant changes in biomass accumulation and up to 13% increase in ethanol production.
Abstract translation: 本文描述了通过表达编码嗜碱性磷酸酶的液泡或胞质形式的酿酒酵母PHO8基因的截短形式来提高酒精发酵期间乙醇产量的方法，其表达降低了生物质积累，同时将更大的碳转移到乙醇生产中。 还描述了用于表达PHO8基因的核酸序列和载体以及携带相同载体的载体。 含有编码液泡形式碱性磷酸酶的完整PHO8基因的菌株细胞内ATP含量稍低，生物量积累变化不大，乙醇产量增加高达13％。
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公开(公告)号：WO2014093738A1
公开(公告)日：2014-06-19
申请号：PCT/US2013/074854
申请日：2013-12-13
Inventor： SUN, Junming , LIU, Changjun , WANG, Yong , SMITH, Colin , MARTIN, Kevin , VENKITASUBRAMANIAN, Padmesh , TERRIAN, Joshua
CPC classification number: C07C1/2078 , B01J21/066 , B01J23/06 , C07C1/207 , C07C1/2074 , C07C2/12 , C07C5/327 , C07C5/48 , C07C29/00 , C07C29/60 , C07C51/12 , C07C51/235 , C07C2521/06 , C07C2523/06 , C10G3/00 , C10G3/44 , C10G3/50 , C10G9/00 , C10G2400/20 , C10G2400/22 , C12P7/52 , C12P7/54 , Y02P20/52 , C07C11/10 , C07C11/09 , C07C11/18 , C07C31/202 , C07C31/205 , C07C53/08 , C07C53/122 , C07C11/167 , C07C11/06 , C07C11/08
Abstract: A process is described for making a product mixture including isobutene, propylene, 1-butene, 2-butene, 2-methyl-1-butene and 2-methyl-2-butene from a mixture of acetic acid and propionic acid through reaction in the presence of a source of hydrogen and of a mixed oxide catalyst, for example, a Zn x Zr y O z mixed oxide catalyst. A variety of commercially valuable products may be made in turn from the various C 3 , C 4 and C 5 constituents of the product mixture
Abstract translation: 描述了一种通过乙酸和丙酸的混合物制备包括异丁烯，丙烯，1-丁烯，2-丁烯，2-甲基-1-丁烯和2-甲基-2-丁烯的产物混合物的方法， 存在氢源和混合氧化物催化剂，例如Zn x ZrO 2混合氧化物催化剂。 可以从产品混合物的各种C3，C4和C5组分依次制备各种商业上有价值的产品
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38.发明申请STABLE MIXED OXIDE CATALYSTS FOR DIRECT CONVERSION OF ETHANOL TO ISOBUTENE AND PROCESS FOR MAKING 审中-公开用于乙醛直接转化为稳定的稳定的氧化物催化剂和制备方法
公开(公告)号：WO2014070354A1
公开(公告)日：2014-05-08
申请号：PCT/US2013/062784
申请日：2013-10-01
Inventor： JUNMING, Sun , CHANGJUN, Liu , YONG, Wang , SMITH, Colin , MARTIN, Kevin , VENKITASUBRAMANIAN, Padmesh
CPC classification number: H01L21/823842 , B01J21/06 , B01J23/06 , B01J27/02 , B01J37/08 , C07C1/20 , C07C2523/06 , H01L21/26513 , H01L21/823821 , H01L21/82385 , H01L27/0922 , H01L27/0924 , H01L29/66537 , H01L29/66545
Abstract: Zn x Zr y O z mixed oxide catalysts having improved stability for the conversion of ethanol to isobutene are described, together with methods for making such catalysts.
Abstract translation: 描述了具有改进的将乙醇转化为异丁烯的稳定性的Zn x Zn y O z混合氧化物催化剂，以及制备这种催化剂的方法。
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39.发明申请
公开(公告)号：WO2014005029A2
公开(公告)日：2014-01-03
申请号：PCT/US2013/048588
申请日：2013-06-28
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： BASEETH, Shireen , JADHAV, Swapnil
IPC: B29C67/00
CPC classification number: B01F17/0064 , A61K8/068 , A61K8/11 , A61K8/365 , A61K8/4993 , A61K8/553 , A61K9/1075 , A61K47/24 , A61K2800/10 , A61K2800/413 , A61Q19/00 , C09K8/035 , C09K2208/10
Abstract: Lecithin based microemulsions and their uses as nanoreactors and carrying materials are disclosed.
Abstract translation: 公开了基于卵磷脂的微乳液及其作为纳米反应器和携带材料的用途。
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公开(公告)号：WO2013188253A1
公开(公告)日：2013-12-19
申请号：PCT/US2013/044878
申请日：2013-06-10
Applicant: ARCHER DANIELS MIDLAND COMPANY
Inventor： STENSRUD, Kenneth
IPC: C07D493/04 , C07D407/14
CPC classification number: C07D493/04
Abstract: An improved, high yielding process is disclosed for making bisglycidyl ether derivatives of isosorbide, isomannide and/or isoidide, wherein up to quantitative yields overall are demonstrated. In another related aspect, a process is disclosed for making novel monoallyl, monoglycidyl ether derivatives or a combination of monoallyl, monoglycidyl ether derivatives and bisglycidyl ether derivatives via the same diallyl isohexide intermediate.
Abstract translation: 公开了一种改进的高产率方法，用于制备异山梨醇，异烟肼和/或异氰酸酯的双缩水甘油醚衍生物，其中总体上达到定量产率。 在另一相关方面，公开了通过相同的二烯丙基异己烯中间体制备新的单烯丙基，单缩水甘油醚衍生物或单烯丙基，单缩水甘油醚衍生物和双缩水甘油醚衍生物的组合的方法。
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