公开(公告)号：US08303873B2

公开(公告)日：2012-11-06

申请号：US11480459

申请日：2006-07-05

Applicant: Andreas Dowe ,  Rainer Göring ,  Michael Böer ,  Roland Wursche ,  Martin Himmelmann ,  Franz-Erich Baumann ,  Karl Kuhmann

Inventor： Andreas Dowe ,  Rainer Göring ,  Michael Böer ,  Roland Wursche ,  Martin Himmelmann ,  Franz-Erich Baumann ,  Karl Kuhmann

IPC: B32B27/34 ,  C08J3/00 ,  C08L69/00 ,  A61K6/00

CPC classification number: B29C47/0004 ,  B29C47/0019 ,  B29C47/0021 ,  B29C47/0023 ,  B29C47/0026 ,  B29C47/065 ,  B29C49/4242 ,  B29K2069/00 ,  B29K2077/00 ,  B29L2023/00 ,  B29L2023/004 ,  B29L2023/22 ,  B32B27/08 ,  B32B27/18 ,  B32B27/34 ,  B32B2250/24 ,  B32B2264/0278 ,  B32B2307/308 ,  B32B2307/7265 ,  C08K5/098 ,  Y10T428/1393 ,  Y10T428/31725

Abstract: Multilayer composites are obtained from a molding composition which contains the following components: a) 100 parts by weight of polyamide and b) from 0.005 to 10 parts by weight of a compound having at least two carbonate units by coextruding with a molding composition based on a high-melting-point polymer whose crystallite melting point Tm is at least 255° C. and/or whose glass transition temperature Tg is at least 180° C.

Abstract translation: 多层复合材料由含有以下组分的模塑组合物获得：a）100重量份的聚酰胺和b）0.005至10重量份的具有至少两个碳酸酯单元的化合物，其通过与模塑组合物共挤出，基于 微晶熔点Tm至少为255℃的高熔点聚合物和/或其玻璃化转变温度Tg至少为180℃。

公开(公告)号：US20110209768A1

公开(公告)日：2011-09-01

申请号：US13128297

申请日：2009-10-07

Applicant: Andreas Dowe ,  Reinhard Beuth ,  Franz-Erich Baumann

Inventor： Andreas Dowe ,  Reinhard Beuth ,  Franz-Erich Baumann

IPC: F15D1/00

CPC classification number: F16L11/083 ,  B29C47/0023 ,  C08L77/00 ,  C08L77/06 ,  C08L77/12 ,  C08L2205/02 ,  F16L9/147 ,  F16L11/06 ,  Y02P20/544 ,  Y10T137/0318 ,  C08L2666/20

Abstract: A moulding composition which comprises at least 50% by weight of the following constituents:a) from 0 to 99 parts by weight of polyamide, andb) from 1 to 100 parts by weight of polyamide elastomer, selected from the group of polyetheresteramide and polyetheramide,where the total of the parts by weight is 100 and where the moulding composition comprises from 0 to 9% by weight of plasticizer,is used for the production of a moulding for contact with a supercritical medium, and preferably for the production of an inner thermoplastics layer in a flexible pipe or rigid pipe, in which a supercritical medium is conveyed. Low or zero plasticizer content eliminates any significant occurrence of problems such as increased stiffness and longitudinal shrinkage.

Abstract translation: 一种模塑组合物，其包含至少50重量％的以下组分：a）0至99重量份的聚酰胺，和b）1至100重量份的选自聚醚酯酰胺和聚醚酰胺的聚酰胺弹性体 ，其中重量份的总量为100，并且其中模塑组合物包含0至9重量％的增塑剂，用于生产与超临界介质接触的模制品，并且优选用于生产内部 柔性管或刚性管中的热塑性塑料层，其中传送超临界介质。 低或零增塑剂含量消除了任何显着的问题，例如增加刚度和纵向收缩。

公开(公告)号：US07579058B2

公开(公告)日：2009-08-25

申请号：US11685283

申请日：2007-03-13

Applicant: Andreas Dowe ,  Michael Boeer ,  Karl Kuhmann ,  Guido-Jan Schmitz

Inventor： Andreas Dowe ,  Michael Boeer ,  Karl Kuhmann ,  Guido-Jan Schmitz

IPC: F16L11/04

CPC classification number: B32B1/08 ,  B32B27/08 ,  B32B27/18 ,  B32B27/308 ,  B32B27/32 ,  B32B27/34 ,  B32B2262/101 ,  B32B2307/21 ,  B32B2597/00 ,  B32B2605/00 ,  F16L9/121 ,  F16L11/04 ,  Y10T428/13 ,  Y10T428/1352 ,  Y10T428/1379 ,  Y10T428/1383 ,  Y10T428/139 ,  Y10T428/1393

Abstract: A pipe includes an outer layer composed of a molding composition which includes at least 40% by weight of a polyamide whose monomer units contain an average of at least 8 carbon atoms, and a layer composed of a polypropylene molding composition. An outer diameter of the pipe is in a range from 6 to 20 mm, a wall thickness of the pipe is in a range from 1.0 to 2.0 mm, and a thickness of the polypropylene layer is from 25 to 75% of the wall thickness. The pipe can be used as an air-brake line that can be produced at low cost, has high bursting strength, and has good low-temperature impact resistance.

Abstract translation: 管包括由模制组合物组成的外层，该组合物包含至少40重量％的单体单元含有至少8个碳原子的平均聚酰胺和由聚丙烯模塑组合物组成的层。 管的外径在6〜20mm的范围内，管的壁厚在1.0〜2.0mm的范围内，聚丙烯层的厚度为壁厚的25〜75％。 该管道可以用作可以低成本生产，具有高破裂强度并且具有良好的耐低温冲击性的空气制动管路。

公开(公告)号：US09919494B2

公开(公告)日：2018-03-20

申请号：US14835215

申请日：2015-08-25

Applicant: Juergen Franosch ,  Franz-Erich Baumann ,  Horst Beyer ,  Andreas Dowe ,  Andreas Pawlik

Inventor： Juergen Franosch ,  Franz-Erich Baumann ,  Horst Beyer ,  Andreas Dowe ,  Andreas Pawlik

IPC: B32B15/088 ,  C08L77/02 ,  C08J5/00 ,  C08G73/02 ,  C08L77/06 ,  B32B15/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/34 ,  B32B1/08 ,  F16L11/04 ,  F16L9/147 ,  F16L58/10

CPC classification number: B32B15/088 ,  B32B1/08 ,  B32B15/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/34 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/714 ,  B32B2597/00 ,  B32B2605/08 ,  C08G73/028 ,  C08J5/00 ,  C08J2377/02 ,  C08J2477/02 ,  C08L77/02 ,  C08L77/06 ,  F16L9/147 ,  F16L11/04 ,  F16L58/10 ,  C08L79/02

Abstract: A metallic pipe for contact with a hydrolyzing medium provides longer operating times and improved high temperature resistance. The pipe contains a layer of a polyamide moulding composition containing at least 50% by weight of polyamide content containing: I) 60 to 98 parts by weight of a polyamide which contains 10 to 70 meq/kg of a terminal carboxy group and has a relative solution viscosity ηrel of at least 1.90, and II) 2 to 40 parts by weight of a polyamine-polyamide graft copolymer produced from: a) 0.5 to 25% by weight, based on the entire monomer mixture, of a polyamine having at least 4 nitrogen atoms, and b) 75 to 99.5% by weight, based on the entire monomer mixture, of polyamide-forming monomers selected from lactams, ω-aminocarboxylic acids and/or equimolar combinations of diamine and dicarboxylic acid, with the proviso that the amino group concentration of the graft copolymer is in the range from 100 to 2500 meq/kg, wherein the sum of the parts by weight of I) and II) is 100.

公开(公告)号：US09574700B2

公开(公告)日：2017-02-21

申请号：US12675122

申请日：2008-08-27

Applicant: Andreas Dowe ,  Rainer Goering ,  Martin Risthaus ,  Klaus Gahlmann ,  Reinhard Buessing ,  Hans-Juergen Kocks ,  Joern Winkels

Inventor： Andreas Dowe ,  Rainer Goering ,  Martin Risthaus ,  Klaus Gahlmann ,  Reinhard Buessing ,  Hans-Juergen Kocks ,  Joern Winkels

IPC: F16L58/10 ,  F16L1/028

CPC classification number: F16L58/109 ,  F16L1/028

Abstract: A pipeline laid trenchlessly and/or without a sand bed is produced using a metallic conduit which is encased with an extruded layer of a polyamide molding material. In this way, the durability of the outer shell required for trenchless laying techniques without a sand bed is ensured.

Abstract translation: 使用装有聚酰胺成型材料的挤压层的金属管道制造无槽地和/或没有沙床的管道。 以这种方式，确保了没有砂床的无沟槽铺设技术所需的外壳的耐久性。

公开(公告)号：US20160060459A1

公开(公告)日：2016-03-03

申请号：US14835215

申请日：2015-08-25

Applicant: Juergen FRANOSCH ,  Franz-Erich BAUMANN ,  Horst BEYER ,  Andreas DOWE ,  Andreas PAWLIK

Inventor： Juergen FRANOSCH ,  Franz-Erich BAUMANN ,  Horst BEYER ,  Andreas DOWE ,  Andreas PAWLIK

IPC: C08L77/02 ,  F16L9/14 ,  F16L9/12 ,  C08J5/00 ,  F16L11/04

CPC classification number: B32B15/088 ,  B32B1/08 ,  B32B15/08 ,  B32B27/18 ,  B32B27/28 ,  B32B27/34 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/714 ,  B32B2597/00 ,  B32B2605/08 ,  C08G73/028 ,  C08J5/00 ,  C08J2377/02 ,  C08J2477/02 ,  C08L77/02 ,  C08L77/06 ,  F16L9/147 ,  F16L11/04 ,  F16L58/10 ,  C08L79/02

Abstract: A metallic pipe for contact with a hydrolyzing medium provides longer operating times and improved high temperature resistance. The pipe contains a layer of a polyamide moulding composition containing at least 50% by weight of polyamide content containing: I) 60 to 98 parts by weight of a polyamide which contains 10 to 70 meq/kg of a terminal carboxy group and has a relative solution viscosity ηrel of at least 1.90, and II) 2 to 40 parts by weight of a polyamine-polyamide graft copolymer produced from: a) 0.5 to 25% by weight, based on the entire monomer mixture, of a polyamine having at least 4 nitrogen atoms, and b) 75 to 99.5% by weight, based on the entire monomer mixture, of polyamide-forming monomers selected from lactams, ω-aminocarboxylic acids and/or equimolar combinations of diamine and dicarboxylic acid, with the proviso that the amino group concentration of the graft copolymer is in the range from 100 to 2500 meq/kg, wherein the sum of the parts by weight of I) and II) is 100.

Abstract translation: 与水解介质接触的金属管提供更长的操作时间和改善的耐高温性。 该管包含一层聚酰胺模塑组合物，其含有至少50重量％的聚酰胺含量：I）60至98重量份的含有10至70meq / kg末端羧基的聚酰胺，并具有相对 溶液粘度和相对值至少为1.90，和II）2-40重量份由以下制备的聚胺 - 聚酰胺接枝共聚物制备：a）基于整个单体混合物的0.5至25重量％的具有 至少4个氮原子，和b）基于整个单体混合物的75至99.5重量％的选自内酰胺，ω-氨基羧酸和/或二胺和二羧酸的等摩尔组合的聚酰胺形成单体，条件是 接枝共聚物的氨基浓度范围为100〜2500meq / kg，其中I）和II）的重量份之和为100。

公开(公告)号：US08697814B2

公开(公告)日：2014-04-15

申请号：US13063134

申请日：2009-11-17

Applicant: Andreas Dowe ,  Reinhard Beuth ,  Franz-Erich Baumann

Inventor： Andreas Dowe ,  Reinhard Beuth ,  Franz-Erich Baumann

IPC: C08L69/00 ,  C08J5/00 ,  B29C45/00

CPC classification number: F16L11/06 ,  B29C47/00 ,  B29C47/0016 ,  B29C47/0021 ,  B29C47/0026 ,  C08G69/40 ,  C08G69/46 ,  C08J3/226 ,  C08J2377/00 ,  C08J2477/00 ,  C08L77/00 ,  C08L77/06 ,  C08L2205/02 ,  F16L9/147 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L2666/20

Abstract: A polyamide molding composition is condensed up in the melt by means of a masterbatch containing a compound having at least two carbonate units and also a polyetheramide in which at least 50% of the end groups are present as amino end groups, whereupon the melt mixture is discharged and solidified to give a molding composition or a molding. The product obtained has an increased amino end group content and consequently an improved hydrolysis resistance.

Abstract translation: 聚酰胺模塑组合物通过含有至少两个碳酸酯单元的化合物的母料在熔体中缩合，并且其中至少有50％的端基作为氨基端基存在的聚醚酰胺，因此熔融混合物是 排出并固化，得到模塑组合物或模制品。 所得产物具有增加的氨基端基含量，因此具有改善的耐水解性。

公开(公告)号：US08647551B2

公开(公告)日：2014-02-11

申请号：US11354114

申请日：2006-02-15

Applicant: Andreas Dowe ,  Rainer Goering ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

Inventor： Andreas Dowe ,  Rainer Goering ,  Martin Himmelmann ,  Sonja Bollmann ,  Franz-Erich Baumann ,  Roland Wursche

IPC: C08F283/04 ,  C08L77/00 ,  B29C49/00

CPC classification number: C08K5/098 ,  C08L69/00 ,  C08L77/02 ,  Y10T428/1352 ,  Y10T428/139 ,  C08L77/00 ,  C08L2666/14

Abstract: A process for producing moldings with condensing-up of a polyamide molding composition whose polyamide component contains, as a result of the method of preparation, at least 5 ppm of phosphorus in the form of an acidic compound by means of a compound having at least two carbonate units, wherein a) from 0.001 to 10% by weight, based on the polyamide, of a salt of a weak acid is added to the polyamide molding composition prior to compounding or during compounding, b) a mixture of the finished composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, effects a significant increase in the melt stiffness combined with moderate processing pressures, which considerably simplifies, in particular, the production of hollow bodies and hollow profiles having large diameters.

Abstract translation: 一种聚酰胺成型组合物的制造用模制品的制造方法，其聚酰胺成分作为制备方法的结果，含有至少5ppm的酸性化合物形式的磷，该化合物具有至少两个 碳酸酯单元，其中a）基于聚酰胺的0.001至10重量％的弱酸盐在配混之前或在配混期间加入到聚酰胺模塑组合物中，b）成品组合物和 制备具有至少两个碳酸酯单元的化合物，c）如果合适的话，该混合物被储存和/或运输，以及d）随后将该混合物加工以产生模制物，其中仅在该步骤中发生冷凝， 结合中等加工压力的熔体刚度的显着增加，这特别地简化了具有大直径的中空体和中空型材的生产。

公开(公告)号：US08580899B2

公开(公告)日：2013-11-12

申请号：US11354100

申请日：2006-02-15

Applicant: Andreas Dowe ,  Rainer Goering ,  Sonja Bollmann ,  Franz-Erich Baumann

Inventor： Andreas Dowe ,  Rainer Goering ,  Sonja Bollmann ,  Franz-Erich Baumann

IPC: C08F283/04 ,  C08L77/00

CPC classification number: C08G69/48 ,  B29C47/0023 ,  B29C47/0054 ,  B29C47/043 ,  B29C47/065 ,  B29C49/04 ,  B29C2791/006 ,  B29K2023/06 ,  B29K2023/12 ,  B29K2055/02 ,  B29K2077/00 ,  B29K2105/0008 ,  B29K2105/0026 ,  B29K2105/0032 ,  B29K2105/0038 ,  B29K2105/0044 ,  B29K2105/16 ,  B29L2023/22 ,  B29L2031/7172 ,  C08K5/098 ,  F16L9/127 ,  Y10T428/139 ,  C08L77/00

Abstract: A process for producing moldings with condensing-up of a polyamide molding composition by means of a compound having at least two carbonate units, wherein a) a polyamide molding composition is made available, b) a mixture of the polyamide molding composition and the compound having at least two carbonate units is prepared, c) the mixture is, if appropriate, stored and/or transported and d) the mixture is subsequently processed to produce the molding, with the condensing-up occurring only in this step, and the molding is a hollow body or hollow profile having an external diameter of at least 30 mm and a wall thickness of at least 1 mm, effects a significant increase in the melt stiffness combined with moderate processing presssures, which considerably simplifies the production of these moldings.

Abstract translation: 一种通过具有至少两个碳酸酯单元的化合物聚酰胺模塑组合物生产模制品的方法，其中a）聚酰胺模塑组合物可获得，b）聚酰胺模塑组合物和具有 制备至少两个碳酸酯单元，c）如果适当，储存和/或运输混合物，以及d）随后将该混合物加工以产生模制品，其中仅在该步骤中发生冷凝，并且模塑是 具有至少30mm的外径和至少1mm的壁厚的中空本体或中空型材，与中等加工压力结合使熔体刚度显着提高，这大大简化了这些模制品的生产。

公开(公告)号：US20130032239A1

公开(公告)日：2013-02-07

申请号：US13640552

申请日：2011-03-18

Applicant: Karl Kuhmann ,  Andreas Dowe ,  Rainer Goering

Inventor： Karl Kuhmann ,  Andreas Dowe ,  Rainer Goering

IPC: F16L11/04

CPC classification number: B32B1/08 ,  B32B27/28 ,  B32B27/32 ,  B32B27/34 ,  B32B2307/546 ,  B32B2307/714 ,  F16L11/04

Abstract: The invention relates to a flexible pipe having a multi-layered structure comprising unbonded layers, comprising an inner lining having the following layer arrangement: a) an innermost layer made of a fluoropolymer molding compound, b) an intermediate layer made of a molding compound on the basis of an olefinic polymer, which is selected from the group consisting of polyethylene, isotactic polypropylene, syndiotactic polypropylene and syndiotactic polystyrene, c) an outer layer made of a polyamide molding compound, wherein the layer made of a polyamide molding compound is particularly efficiently protected against hydrolysis. The pipe is thus particularly suited for offshore applications in oil or gas production.

Abstract translation: 本发明涉及一种具有多层结构的柔性管，包括无粘结层，包括具有以下层布置的内衬：a）由氟聚合物模塑料制成的最内层，b）由模塑料制成的中间层 烯属聚合物的基础，其选自聚乙烯，全同立构聚丙烯，间同立构聚丙烯和间同立构聚苯乙烯，c）由聚酰胺模塑料制成的外层，其中由聚酰胺模塑料制成的层特别有效 防止水解。 因此，管道特别适用于油气生产中的海上应用。