CRYSTALLIZATION OF POLYPROPYLENE USING A SEMI-CRYSTALLINE, BRANCHED OR COUPLED NUCLEATING AGENT
    39.
    发明申请
    CRYSTALLIZATION OF POLYPROPYLENE USING A SEMI-CRYSTALLINE, BRANCHED OR COUPLED NUCLEATING AGENT 审中-公开
    使用半结晶,分支或偶联核化剂的聚丙烯的结晶

    公开(公告)号:WO03040095A3

    公开(公告)日:2003-09-12

    申请号:PCT/US0235715

    申请日:2002-11-05

    Abstract: A method of nucleating a propylene homo- or copolymer, the method comprising contacting the propylene polymer with a semi-crystalline branched or coupled polymeric nucleating agent under nucleation conditions. In one embodiment, the propylene homopolymer is characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. In another embodiment, the copolymer is characterized as comprising at least about 60 weight percent (wt%) of units derived from propylene, and as having at least one of the following properties: (i) 13 C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), of the copolymer is at least about 3 wt%, (iii) a skewness index, Six, greater than about -1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer, i.e., the units derived from ethylene and/or the unsaturated comonomer(s), in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.

    Abstract translation: 一种使丙烯均聚物或共聚物成核的方法,该方法包括在成核条件下将丙烯聚合物与半结晶支链或偶联的聚合物成核剂接触。 在一个实施方案中,丙烯均聚物的特征在于具有对应于约14.6和约15.7ppm的区域误差的13 C NMR峰,约等于强度的峰。 在另一个实施方案中,共聚物的特征在于包含至少约60重量%(wt%)衍生自丙烯的单元,并具有至少一个以下性质:(i)对应于区域误差的13 C NMR峰 约14.6和约15.7ppm,约等于强度的峰,(ii)当共聚单体含量(即衍生自乙烯和/或不饱和共聚单体的单元)的B值大于约1.4时,B值大于约1.4, 共聚物为至少约3重量%,(iii)偏度指数为6,大于约-1.20,(iv)具有保持基本相同的Tme的DSC曲线和随着共聚单体数量减少的Tmax,即 ,共聚物中衍生自乙烯和/或不饱和共聚单体的单元增加,和(v)比用齐格勒 - 纳塔(Ziegler-Natta)制备的可比共聚物报告更多的γ型晶体的X射线衍射图 ZN)催化剂。

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