公开(公告)号：KR100511756B1

公开(公告)日：2005-08-31

申请号：KR1020030083004

申请日：2003-11-21

Applicant: 제일모직주식회사

Inventor： 강태곤 ,  임종철 ,  서경훈

IPC: C08L69/00

Abstract: 본 발명의 난연성 열가소성 수지조성물은 (A) 폴리카보네이트 수지 100 중량부; (B) 술폰산 금속염 0.01 내지 10 중량부; (C) 이산화티탄 100중량부에 대해서 알루미나(Al
2 O
3 )가 1% 이하로 표면개질된 특정 이산화티탄 2∼20 중량부; 및 (D) 평균 입자 크기가 0.05∼1000㎛이고, 밀도가 1.2∼2.3 g/㎤인 불소화 폴리올레핀계 수지 0.05∼5 중량부로 이루어지는 것을 특징으로 한다.

公开(公告)号：KR1020050053155A

公开(公告)日：2005-06-08

申请号：KR1020030086773

申请日：2003-12-02

Applicant: 제일모직주식회사

Inventor： 소명섭 ,  임종철 ,  서경훈

IPC: C08L69/00

Abstract: 본 발명에 따른 난연성 폴리카보네이트계 수지 조성물은 (A) 폴리카보네이트계 수지 45∼95 중량부, (B) 산으로 응집시킨 후, 에틸알콜 및 탈이온수로 세척하고 건조하여 얻은 고무변성 스티렌계 그라프트 공중합체 1∼50 중량부, (C) 스티렌계 공중합체 0∼50 중량부, (D) 인산 에스테르계 화합물 1∼30 중량부, 상기 (A)+(B)+(C)+(D) 100 중량부에 대하여, (E) 불소화 폴리올레핀계 수지 0.05∼5 중량부로 이루어지는 것을 특징으로 한다. 본 발명에 따른 난연성 폴리카보네이트계 수지 조성물은 성형되어 전기제품, 사무기기 등의 성형품에 이용될 수 있다.

公开(公告)号：KR100463960B1

公开(公告)日：2004-12-30

申请号：KR1020020040373

申请日：2002-07-11

Applicant: 제일모직주식회사

Inventor： 임종철 ,  양삼주

IPC: C08L69/00

CPC classification number: C08K5/5399 ,  C08K5/523 ,  C08L25/02 ,  C08L27/12 ,  C08L33/06 ,  C08L51/04 ,  C08L69/00 ,  C08L2666/02

Abstract: The flame retardant thermoplastic resin composition of the present invention comprises (A) 45~95 parts by weight of a polycarbonate resin; (B) 1~50 parts by weight of a rubber modified vinyl graft copolymer; (C) 0~50 parts by weight of a vinyl copolymer; (D) 1~30 parts by weight of a mixture of organic phosphorous compounds consisting of (d1) 1~50% by weight of a oligomeric compound of cyclic phosphazene and (d2) 99~50% by weight of an oligomeric phosphoric acid ester compound, per 100 parts by weight of the sum of (A), (B) and (C); and (E) 0.05~5 parts by weight of a fluorinated polyolefin resin per 100 parts by weight of the sum of (A), (B) and (C).

Abstract translation: 本发明的阻燃热塑性树脂组合物包含（A）45〜95重量份的聚碳酸酯树脂; （B）1〜50重量份的橡胶改性乙烯基接枝共聚物; （C）0〜50重量份的乙烯基共聚物; （D）1-30重量份由（d1）1-50重量％环状磷腈低聚化合物和（d2）99-50重量％低聚磷酸酯组成的有机磷化合物混合物 （A），（B）和（C）的总和为100重量份; 和（E）每100重量份的（A），（B）和（C）的总和为0.05〜5重量份的氟化聚烯烃树脂。

公开(公告)号：KR100462531B1

公开(公告)日：2004-12-17

申请号：KR1020020039204

申请日：2002-07-08

Applicant: 제일모직주식회사

Inventor： 임종철 ,  양삼주

IPC: C08L69/00

CPC classification number: C08K5/523 ,  C08L27/12 ,  C08L51/04 ,  C08L69/00 ,  C08L2666/02

Abstract: The flame retardant thermoplastic resin composition of the present invention comprises (A) 45-95 parts by weight of a thermoplastic polycarbonate resin; (B) 1-50 parts by weight of a vinyl graft copolymer; (C) 0-50 parts by weight of a vinyl copolymer or a mixture of vinyl copolymers; (D) 1-30 parts by weight of a mixture of organic phosphorous compounds (D-1) 5-95 parts by weight of a monomeric phosphoric acid ester compound or a mixture of monomeric phosphoric acid ester compounds and (D-2) 95-5 parts by weight of an oligomeric phosphoric acid ester compound or a mixture of oligomeric phosphoric acid ester compounds, per 100 parts by weight of the sum of (A), (B) and (C); and (E) 0.05-5 parts by weight of a fluorinated polyolefin resin per 100 parts by weight of the sum of (A), (B) and (C).

Abstract translation: 本发明的阻燃热塑性树脂组合物包含（A）45-95重量份的热塑性聚碳酸酯树脂; （B）1-50重量份的乙烯基接枝共聚物; （C）0-50重量份的乙烯基共聚物或乙烯基共聚物的混合物; （D）1-30重量份有机磷化合物（D-1）的混合物5-95重量份单体磷酸酯化合物或单体磷酸酯化合物与（D-2）95 -5重量份的低聚磷酸酯化合物或低聚磷酸酯化合物的混合物，每100重量份的（A），（B）和（C）的总和; 和（E）每100重量份的（A），（B）和（C）的总和为0.05-5重量份的氟化聚烯烃树脂。

公开(公告)号：KR100462530B1

公开(公告)日：2004-12-17

申请号：KR1020020032784

申请日：2002-06-12

Applicant: 제일모직주식회사

Inventor： 서경훈 ,  임종철 ,  양삼주

IPC: C08L69/00

Abstract: PURPOSE: Provided is a thermoplastic resin composition, which has a remarkably improved resistance against the chemicals used in coating and plating and has excellent flame resistance even at a thin thickness of about 1.2 mm. CONSTITUTION: The flame retardant thermoplastic resin composition comprises: (A) 45-95 parts by weight of a polycarbonate resin; (B) 1-50 parts by weight of an acrylic rubber-modified graft copolymer; (C) 1-50 parts by weight of a vinyl-based copolymer or a mixture of vinyl-based copolymers; (D) 1-30 parts by weight of a mixture of organic phosphorous compounds, based on 100 parts by weight of the total amount of base resins (A)+(B)+(C), in which the mixture contains (d1) 1-50 wt% of a cyclic phosphazene oligomer compound and (d2) 99-50 wt% of a phosphate ester compound; and (E) 0.05-5 parts by weight of a fluorinated polyolefin resin having an average particle diameter of 0.05-1000 micrometers and a density of 1.2-2.3 g/cm¬3, based on 100 parts by weight of the total amount of base resins (A)+(B)+(C).

Abstract translation: 目的：提供一种热塑性树脂组合物，其具有显着改进的耐涂覆和镀覆用化学品的耐受性，并且即使在约1.2mm的薄的厚度下也具有优异的阻燃性。 构成：阻燃热塑性树脂组合物包含：（A）45-95重量份的聚碳酸酯树脂; （B）1-50重量份的丙烯酸橡胶改性的接枝共聚物; （C）1-50重量份的乙烯基类共聚物或乙烯基类共聚物的混合物; （D）基于100重量份的基础树脂（A）+（B）+（C）的总量，1-30重量份的有机磷化合物的混合物，其中混合物含有（d1） 1-50重量％环状磷腈低聚物化合物和（d2）99-50重量％磷酸酯化合物; 和（E）0.05-5重量份的平均粒径为0.05-1000微米，密度为1.2-2.3克/立方厘米的氟化聚烯烃树脂，基于100重量份的碱总量 树脂（A）+（B）+（C）。

公开(公告)号：KR100442937B1

公开(公告)日：2004-08-04

申请号：KR1020010078058

申请日：2001-12-11

Applicant: 제일모직주식회사

Inventor： 임종철 ,  홍상현 ,  양삼주

IPC: C08L69/00

Abstract: PURPOSE: A flame retardant thermoplastic resin composition and a molded product prepared by using the composition are provided, to improve the flame retardancy, the heat resistance, the hot water resistance, the impact resistance, the stress cracking resistance, the heat stability and the workability. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a resin component; 1-30 parts by weight of a mixture of organic phosphorus-based compounds comprising 5-95 parts by weight of the phosphoric acid ester morpholide compound monomer of the formula I and 5-95 parts by weight of the phosphoric acid ester-based oligomer of the formula II; and 0.05-5 parts by weight of a fluorinated polyolefin-based resin having an average particle size of 0.05-1,000 micrometers and a density of 1.2-2.3 g/cm3, wherein R1, R2, R3, R5 and R6 are independently an unsubstituted or alkyl-substituted aryl group of C6-C20; x is 1 or 2; and R4 is an unsubstituted or alkyl-substituted arylene group of C6-C30; and n has an average of 0.3-5. The resin component comprises 45-95 parts by weight of a thermoplastic polycarbonate resin; 1-50 parts by weight of the vinyl-based graft copolymer obtained by graft polymerizing 5-95 parts by weight of a monomer mixture comprising 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures, onto 5-95 parts by weight of at least one polymer selected from the group consisting of butadiene rubber, acryl rubber, ethylene-propylene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber, isoprene rubber, ethylene-propylene-diene terpolymer and polyorganosiloxane-polyalkyl(meth)acrylate rubber composite; and 0-50 parts by weight of vinyl-based copolymers or their mixture obtained by copolymerizing 50-95 parts by weight of styrene, α-methylstyrene, halogen or alkyl-substituted styrene, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester or their mixtures and 5-50 parts by weight of acrylonitrile, methacrylonitrile, C1-C8 methacrylic acid alkyl ester, C1-C8 acrylic acid alkyl ester, maleic anhydride, C1-C4 alkyl or phenyl N-substituted maleimide or their mixtures.

Abstract translation: 目的：提供阻燃热塑性树脂组合物和使用该组合物制备的模塑制品，以改善阻燃性，耐热性，耐热水性，耐冲击性，耐应力开裂性，热稳定性和可加工性 。 构成：热塑性树脂组合物包含100重量份的树脂组分; 1-30重量份的有机磷基化合物混合物，其包含5-95重量份的式I的磷酸酯吗啉化合物单体和5-95重量份的磷酸酯类低聚物 公式二; 和0.05-5重量份的平均粒径为0.05-1,000微米且密度为1.2-2.3g / cm 3的氟化聚烯烃基树脂，其中R 1，R 2，R 3，R 5和R 6独立地为未取代的或 C6-C20的烷基取代的芳基; x是1或2; 并且R4是C6-C30的未取代的或烷基取代的亚芳基; n的平均值为0.3-5。 该树脂组分包含45-95重量份的热塑性聚碳酸酯树脂; 1-50重量份通过接枝聚合5-95重量份包含50-95重量份苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯的单体混合物获得的乙烯基类接枝共聚物 ，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯或它们的混合物和5-50重量份丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸酐， C1-C4烷基或苯基N-取代的马来酰亚胺或它们的混合物加入5-95重量份的至少一种选自丁二烯橡胶，丙烯酸橡胶，乙烯 - 丙烯橡胶，苯乙烯 - 丁二烯橡胶，丙烯腈 - 丁二烯橡胶， 丁二烯橡胶，异戊二烯橡胶，乙烯 - 丙烯 - 二烯三元共聚物和聚有机硅氧烷 - 聚（甲基）丙烯酸烷基酯橡胶复合物; 和0-50重量份的乙烯基共聚物或它们的混合物，它们是通过将50-95重量份的苯乙烯，α-甲基苯乙烯，卤素或烷基取代的苯乙烯，C1-C8甲基丙烯酸烷基酯，C1- -C8丙烯酸烷基酯或它们的混合物和5-50重量份的丙烯腈，甲基丙烯腈，C1-C8甲基丙烯酸烷基酯，C1-C8丙烯酸烷基酯，马来酸酐，C1-C4烷基或苯基N-取代的马来酰亚胺 或它们的混合物。

公开(公告)号：KR1020040007788A

公开(公告)日：2004-01-28

申请号：KR1020020040373

申请日：2002-07-11

Applicant: 제일모직주식회사

Inventor： 임종철 ,  양삼주

IPC: C08L69/00

CPC classification number: C08K5/5399 ,  C08K5/523 ,  C08L25/02 ,  C08L27/12 ,  C08L33/06 ,  C08L51/04 ,  C08L69/00 ,  C08L2666/02

Abstract: PURPOSE: A thermoplastic resin composition having excellent flame retardancy as well as excellent balance of properties such as mechanical strength, heat resistance, impact resistance, thermostability, workability, and appearance is provided by mixing a phosphazene compound having a specific structure and oligomeric phosphate ester compound in an appropriate ratio. CONSTITUTION: The flame retardant thermoplastic resin composition comprises (A) 45-95 pts.wt. of polycarbonate resin, (B) 1-50 pts.wt. of copolymer grafted with rubber-modified vinyl, (C) 0-50 pts.wt. of vinyl-based copolymer, (D) 1-30 pts.wt. of organophosphorus compound containing a mixture of 1-50 wt% of cyclic phosphazene oligomer compound(formula 2) and 99-50 wt% of oligomeric phosphate ester compound(formula 4), based on the total weight of the (A), (B) and (C) as 100 pts.wt, and (E) 0.05-5 pts.wt. of fluorinated polyolefin-based resin, based on the total weight of the (A), (B) and (C).

Abstract translation: 目的：通过混合具有特定结构的磷腈化合物和低聚磷酸酯化合物，提供具有优异的阻燃性以及良好的机械强度，耐热性，耐冲击性，耐热性，加工性和外观性能的平衡性的热塑性树脂组合物 以适当的比例。 构成：阻燃热塑性树脂组合物包含（A）45-95重量份 的聚碳酸酯树脂，（B）1-50重量份 的共聚物接枝橡胶改性乙烯基，（C）0-50重量份 的乙烯基类共聚物，（D）1-30重量份 的含有1-50重量％的环磷腈低聚物化合物（式2）和99-50重量％的低聚磷酸酯化合物（式4）的混合物的有机磷化合物，基于（A），（B ）和（C）为100重量份，（E）为0.05-5重量份 的（A），（B）和（C）的总重量的氟化聚烯烃类树脂。

公开(公告)号：KR1020030095537A

公开(公告)日：2003-12-24

申请号：KR1020020032784

申请日：2002-06-12

Applicant: 제일모직주식회사

Inventor： 서경훈 ,  임종철 ,  양삼주

IPC: C08L69/00

CPC classification number: C08L69/00 ,  C08J2300/22 ,  C08K5/523 ,  C08K5/5399 ,  C08L23/28 ,  C08L25/08 ,  C08L51/04 ,  C08L2201/02

Abstract: PURPOSE: Provided is a thermoplastic resin composition, which has a remarkably improved resistance against the chemicals used in coating and plating and has excellent flame resistance even at a thin thickness of about 1.2 mm. CONSTITUTION: The flame retardant thermoplastic resin composition comprises: (A) 45-95 parts by weight of a polycarbonate resin; (B) 1-50 parts by weight of an acrylic rubber-modified graft copolymer; (C) 1-50 parts by weight of a vinyl-based copolymer or a mixture of vinyl-based copolymers; (D) 1-30 parts by weight of a mixture of organic phosphorous compounds, based on 100 parts by weight of the total amount of base resins (A)+(B)+(C), in which the mixture contains (d1) 1-50 wt% of a cyclic phosphazene oligomer compound and (d2) 99-50 wt% of a phosphate ester compound; and (E) 0.05-5 parts by weight of a fluorinated polyolefin resin having an average particle diameter of 0.05-1000 micrometers and a density of 1.2-2.3 g/cm¬3, based on 100 parts by weight of the total amount of base resins (A)+(B)+(C).

Abstract translation: 目的：提供一种热塑性树脂组合物，其具有显着提高的对涂料和电镀中使用的化学品的抵抗性，并且即使在约1.2mm的薄厚度下也具有优异的阻燃性。 构成：阻燃热塑性树脂组合物包含：（A）45-95重量份的聚碳酸酯树脂; （B）1-50重量份的丙烯酸橡胶改性的接枝共聚物; （C）1-50重量份的乙烯基类共聚物或乙烯基类共聚物的混合物; （D）基于100重量份的基础树脂（A）+（B）+（C）的总量，含有（d1）的混合物的有机磷化合物的混合物为1-30重量份， 1-50重量％的环磷腈低聚物化合物和（d2）99-50重量％的磷酸酯化合物; 和（E）0.05-5重量份平均粒径为0.05-1000微米和密度为1.2-2.3克/厘米3的氟化聚烯烃树脂，基于100重量份的碱的总量 树脂（A）+（B）+（C）。

公开(公告)号：KR100367828B1

公开(公告)日：2003-11-17

申请号：KR1019970063466

申请日：1997-11-27

Applicant: 제일모직주식회사

Inventor： 임종철 ,  이제흔

IPC: C08J5/08

Abstract: PURPOSE: A styrene-based thermoplastic composite material is provided to improve the interfacial adhesion force, thereby improving the mechanical strength and impact strength. CONSTITUTION: The styrene-based thermoplastic composite material having improved impact strength comprises: (A) 50-95 parts by weight of a styrene-based thermoplastic resin; (B) 5-50 parts by weight of inorganic reinforcing materials; and (C) 1-50 parts by weight of a modified vinyl aromatic graft copolymer obtained by melting and kneading 100 parts by weight of a graft copolymer, 0.1-2 parts by weight of an organic peroxide, and 0.1-10 parts by weight of an epoxy group-containing reactive monomer to perform graft reaction, wherein the graft copolymer is prepared by the graft polymerization of 1-80 parts by weight of a rubbery polymer with 20-99 parts by weight of an aromatic vinyl monomer.

公开(公告)号：KR1020030065921A

公开(公告)日：2003-08-09

申请号：KR1020020006002

申请日：2002-02-02

Applicant: 제일모직주식회사

Inventor： 임종철 ,  홍상현 ,  양삼주

IPC: C08L69/00

CPC classification number: C08L69/00 ,  C08J5/00 ,  C08J2300/22 ,  C08K5/523 ,  C08L23/28 ,  C08L25/08 ,  C08L51/04 ,  C08L2201/02 ,  C08L2205/035

Abstract: PURPOSE: Provided is a fire retardant, thermoplastic resin composition which does not show a juicing phenomenon, and at the same time, has excellent balance of physical properties such as fire retardancy, mechanical strength, impact resistance, heat stability, workability, and appearance. CONSTITUTION: The composition comprises (A) 45-95 parts by weight of polycarbonate resin; (B) 1-50 parts by weight of rubber-modified vinyl graft copolymer; (C) 0-50 parts by weight of vinyl copolymer; (D) 1-30 parts by weight(based on the sum 100 parts by weight of the basic resin(A)+(B)+(C)) of mixture of organophosphorus compounds consisting of (D-1) 5-95 parts by weight of monomeric ester phosphate compound represented by formula I or mixture thereof and (D-2) 95-5 parts by weight of oligomeric ester phosphate compound represented by formula II or a mixture thereof(wherein each of R1 and R2 is independently hydrogen atom, or an alkyl group such as methyl, ethyl, propyl, isopropyl, butyl, sec-butyl, t-butyl, isobutyl, isoamyl, t-amyl, x is an integer of 1-3, each of R3, R4, R6 and R7 is independently C6-C20 aryl or alkyl-substituted C6-C20 aryl group, C5 is C6-C30 arylene or alkyl substituted C6-C30 arylene group, n is an integer representing a number of repeating unit, and an integer of 1-5, n has average value of 1-5 in mixture of the oligomeric ester phosphate compounds); (E) 0.05-5 parts by weight (based on the sum 100 parts by weight of the basic resin(A)+(B)+(C)) of fluorinated polyolefin resin having an average particle size of 0.05-1,000 micrometer and a density of 1.2-2.3 g/cm¬3.

Abstract translation: 目的：提供一种不显示榨汁现象的阻燃性热塑性树脂组合物，同时具有阻燃性，机械强度，耐冲击性，热稳定性，加工性和外观等物理性能的良好平衡。 构成：组合物包含（A）45-95重量份的聚碳酸酯树脂; （B）1-50重量份橡胶改性的乙烯基接枝共聚物; （C）0-50重量份的乙烯基共聚物; （D）1-30重量份（基于由（D-1）5-95重量份组成的有机磷化合物的混合物的100重量份的碱性树脂（A）+（B）+（C） 的由式I表示的单体酯磷酸酯化合物或其混合物和（D-2）95-5重量份由式II表示的低聚酯磷酸酯化合物或其混合物（其中R 1和R 2各自独立地为氢原子 ，或烷基如甲基，乙基，丙基，异丙基，丁基，仲丁基，叔丁基，异丁基，异戊基，叔戊基，x为1-3的整数，R3，R4，R6和 R7独立地是C6-C20芳基或烷基取代的C6-C20芳基，C5是C6-C30亚芳基或烷基取代的C6-C30亚芳基，n是表示重复单元数的整数，1-5的整数 ，低聚磷酸酯化合物的混合物的n平均值为1-5）; （E）平均粒径为0.05-1,000微米的氟化聚烯烃树脂的0.05-5重量份（基于100重量份的碱性树脂（A）+（B）+（C））和 密度为1.2-2.3g / cm 3。