Abstract:
Adhesive (co)polymers of this disclosure comprise: a) an isobutylene copolymer having pendent succinate groups and optionally a tackifier. The pendent succinic acid groups ionically crosslinks the isobutylene copolymer by hydrogen boding with adjacent pendent succinic acid groups.
Abstract:
A polymerizable composition comprising a (meth)acrylate copolymer having pendent photoinitiator groups and a high Tg monomer or macromer is described. The resulting copolymer is physically crosslinking and is of the formula I: (I).
Abstract:
The present disclosure provides an ionically crosslinkable composition comprising a (meth)acrylate copolymer component having pendant acid functional groups and pendant photobase functional groups. On exposure to light, the pendant photobase group photolyzes to provide a pendant amine group, that ionically crosslinks the copolymer.
Abstract:
Conformable coating composition are described comprising a (meth)acrylate copolymer comprising interpolymerized monomer units of fluorinated monomer and a volatile solvent having a solubility parameter from 4.9-12.5 (cal/cm3)1/2. In some embodiments, the fluorinated monomer has a Tg
Abstract translation:描述的可贴合涂料组合物包含含有氟化单体的共聚单体单元和溶度参数为4.9-12.5(cal / cm 3)1/2的挥发性溶剂的(甲基)丙烯酸酯共聚物。 在一些实施例中,氟化单体具有<30℃的Tg。 在一些实施方案中,干燥的涂层在100%的伸长率下不显示粘连和不大于75%的失效。 还描述了一种可贴合膜,其包含本文所述涂料组合物的干燥涂料组合物,包含在基材上的可贴合膜层的制品和包含氟化单体,硅烷单体的共聚单元的共聚物; 和一种或多种Tg≥50℃的单体。
Abstract:
Adhesive compositions comprising a copolymer of isobutylene repeat units and alkene repeat units are described. At least a portion of the alkene repeat units are bonded to a pendent nitrogen atom of a quaternary ammonium salt comprising a free-radically polymerizable substituent. The adhesive optionally comprises other components such as tackifier, unfunctionalized polyisobutylene polymer, plasticizer, and combinations thereof.
Abstract:
An adhesive (co)polymers comprising: a) an isobutylene copolymer having pendent anhydride groups, b) a polyamine photobase generator and c) optionally a tackifier is described.
Abstract:
Presently described are methods of preparing a pressure sensitive adhesive composition comprising providing a non-aqueous pressure sensitive adhesive comprising a (meth)acrylic copolymer comprising epoxy-functional groups; adding a chlorinated triazine crosslinker to the pressure sensitive adhesive; and coating the pressure sensitive adhesive onto a substrate. In some embodiments, the method may further comprise contacting the pressure sensitive adhesive to a second substrate. The method further comprises exposing the pressure sensitive adhesive to actinic radiation to crosslink the epoxy-functional groups by means of the triazine crosslinker. The step of exposing can occur at the time of manufacture (e.g. of a pressure sensitive adhesive coated articles such as a tape) or at the time of use. Also described are non-aqueous pressure sensitive adhesive compositions and adhesive-coated articles.
Abstract:
Adhesive compositions comprising a copolymer of isobutylene repeat units and alkene repeat units are described. At least a portion of the alkene repeat units are bonded to a pendent nitrogen atom of a quaternary ammonium salt comprising a free-radically polymerizable substituent. The adhesive optionally comprises other components such as tackifier, unfunctionalized polyisobutylene polymer, plasticizer, and combinations thereof.