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    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS
    31.
    发明公开
    PROCESS FOR THE PREPARATION OF HIGH PURITY PROPYLENE POLYMERS 有权
    VERFAHRENFÜRDIE HERSTELLUNG VON HOCHREINEN PROPYLENPOLYMEREN

    公开(公告)号：EP2758440A1

    公开(公告)日：2014-07-30

    申请号：EP12759441.4

    申请日：2012-09-17

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GALVAN, Monica ,  PANTALEONI, Roberto ,  FUSCO, Ofelia ,  GADDI, Benedetta ,  NEUMANN, Andreas ,  MAZZUCCO, Antonio ,  COLLINA, Gianni ,  SARTORI, Gabriella

    IPC: C08F4/651 ,  C08F4/654 ,  C08F10/06 ,  C08J5/18 ,  C08F4/649

    CPC classification number: C08F10/06 ,  C08J5/18 ,  C08J2323/14 ,  C08F4/651 ,  C08F4/6543 ,  C08F110/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15

    Abstract: A process for the preparation of high purity propylene polymers carried out in the presence of a catalyst comprising the product obtained by contacting: (a) a solid catalyst component comprising Mg, Ti and at least a first internal electron donor compound (HD) selected among the succinates and a second internal electron donor compound (2ID) selected among the 1,3-diethers, wherein the molar ratio of first internal donor over second internal donor 1ID:2ID is comprised between 4:6 and 9:1, with (b) an organo-aluminium compound, and optionally with (c) an external electron donor compound, said process being carried out at a temperature equal or higher than 78° C. and by employing a molar ratio of organo-aluminum compound over solid catalyst component (b):(a) of lower than 5.

    Abstract translation: 一种制备高纯度丙烯聚合物的方法，所述丙烯聚合物在催化剂存在下进行，所述催化剂包括通过使（a）包含Mg，Ti和至少第一内部电子给体化合物（HD）的固体催化剂组分与 所述琥珀酸盐和选自所述1,3-二醚中的第二内给电子体化合物（2ID），其中所述第一内给体相对于所述第二内供体1ID：2ID的摩尔比为4：6至9：1，与（b ）有机铝化合物，并且任选地与（c）外电子给体化合物反应，所述方法在等于或高于78℃的温度下进行，并且通过使用有机铝化合物与固体催化剂组分的摩尔比 （b）:( a）低于5。

    PROPYLENE-BASED COPOLYMER COMPOSITION FOR PIPES
    33.
    发明公开
    PROPYLENE-BASED COPOLYMER COMPOSITION FOR PIPES 有权
    丙烯基共聚物-ZUSAMMENSETZUNGFÜRROHRE

    公开(公告)号：EP3149082A1

    公开(公告)日：2017-04-05

    申请号：EP15717935.9

    申请日：2015-04-28

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GALVAN, Monica ,  TISI, Francesca ,  PELLEGATTI, Giampaolo ,  BOLOGNESI, Sandro ,  NEUMANN, Andreas

    IPC: C08L23/12 ,  C08L23/14

    CPC classification number: C08L23/14 ,  C08L23/12 ,  C08L23/16 ,  C08L2203/18 ,  C08L2205/025 ,  C08L2207/02 ,  F16L9/12

    Abstract: A polyolefin composition made using a propylene/ethylene copolymer (90.0 wt % to 99.0 wt %) and a heterophasic (second) propylene/ethylene copolymer (1.0 wt % to 10.0 wt %). The composition is useful for the production of pressure pipes, e.g., for use at low temperature, and of pipes for use in heat radiating systems, among other applications. The propylene/ethylene copolymer has between 1.0 wt % and 8.0 wt % ethylene derived units. The second propylene/ethylene copolymer is made using (1) a propylene homopolymer or a propylene/ethylene copolymer (12 wt % to 52 wt %) and (2) a propylene ethylene copolymer (48 wt % to 88 wt %) that has a content of ethylene derived units ranging from 15.0 wt % to 42.0 wt %.

    Abstract translation: 一种聚烯烃组合物，其包含：A）90.0wt％至99.0wt％; 的丙烯与乙烯的共聚物，其中：i）乙烯衍生单元的含量为1.0重量％至8.0重量％; （ii）熔融温度范围为135℃至155℃; （iii）0.2g / 10min至3.5g / 10min范围内的熔体流动速率（230℃/ 5kg .. ISO 1133）; （iv）二甲苯可溶物在25℃的范围为20.0重量％至4.0重量％; （v）多分散性PI的范围为3.0至7.0; B）为1.0重量％〜10.0重量％ 的丙烯，乙烯共聚物组合物，其包含：b1）12重量％至52重量％; 的丙烯均聚物或丙烯/乙烯共聚物; b2）为48重量％至88重量％的丙烯乙烯共聚物，其乙烯衍生单元的含量为15.0重量％至42.0重量％。

    NUCLEATED PROPYLENE-BASED POLYOLEFIN COMPOSITIONS
    34.
    发明公开
    NUCLEATED PROPYLENE-BASED POLYOLEFIN COMPOSITIONS 有权
    NUKLEIERTE POLYOLEFINZUSAMMENSETZUNGEN AUF PROPLENBASIS

    公开(公告)号：EP2986652A1

    公开(公告)日：2016-02-24

    申请号：EP14709338.9

    申请日：2014-03-12

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： GALVAN, Monica ,  NEUMANN, Andreas ,  CAPUTO, Tiziana ,  MAZZUCCO, Antonio ,  PELLEGATTI, Giampaolo

    IPC: C08F210/06

    CPC classification number: C08K5/527 ,  C08F210/16 ,  C08K5/0083 ,  C08K5/098 ,  C08K5/1575 ,  C08F210/06 ,  C08F4/651 ,  C08L23/14

    Abstract: A polyolefin composition, particularly fit for the production of extrusion blow molded articles, comprising (a) a propylene-ethylene copolymer having a content of units deriving from ethylene of 4.0 % by weight or higher, and (b) a nucleating agent and having a crystallization temperature (Tc) higher than 117°C can be obtained by copolymerizing propylene and ethylene in the presence of a catalyst system obtained by contacting a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other selected from 1,3 diethers, an aluminum hydrocarbyl compound, and optionally an external electron donor compound.

    Abstract translation: 一种聚烯烃组合物，特别适用于生产挤出吹塑制品，其包含（a）乙烯衍生物的含量为4.0重量％以上的丙烯 - 乙烯共聚物，和（b）成核剂，并具有 在通过使包含卤化镁的固体催化剂组分，至少具有Ti-卤素键的钛化合物的固体催化剂组分和在至少含有Ti-卤素键的钛化合物的溶剂存在下，在丙烯与乙烯之间进行共聚，可以获得高于117℃的结晶温度（Tc） 至少两种电子给体化合物，其中一种以相对于供体总量为40至90摩尔％的量存在，选自琥珀酸盐，另一种选自1,3-二醚，铝烃基化合物和任选的 外电子给体化合物。

    ELASTOMERIC POLYOLEFIN COMPOSITIONS
    37.
    发明授权
    ELASTOMERIC POLYOLEFIN COMPOSITIONS 有权
    弹性体聚烯烃组合物

    公开(公告)号：EP1797138B1

    公开(公告)日：2010-04-28

    申请号：EP05787154.3

    申请日：2005-09-05

    Applicant: Basell Poliolefine Italia S.r.l.

    Inventor： MASSARI, Paola ,  NEUMANN, Andreas ,  COLLINA, Gianni ,  FUSCO, Ofelia

    IPC: C08L23/10 ,  C08F110/06 ,  C08F4/651

    CPC classification number: C08F210/06 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08F4/651 ,  C08F2/001 ,  C08L2666/06 ,  C08F2500/15 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/04 ,  C08F210/08 ,  C08F2500/21 ,  C08F210/14

    Abstract: An olefin polymer composition comprising (by weight, unless otherwise specified): A) 60-85% of a crystalline propylene homopolymer or a crystalline copolymer of propylene containing 3% or less of ethylene or C4-C10 α-olefin(s) or of combinations thereof, said homopolymer or copolymer having a Polydispersity Index (P.I.) value of from 4.5-6 and a content of isotactic pentads (mmmm), measured by 13C NMR on the fraction insoluble in xylene at 25 °C, higher than 96%; B) 15-40% of a partially amorphous copolymer of ethylene containing from 35% to 70% of propylene or C4-C10 α-olefin(s) or of combinations thereof, and optionally minor proportions of a diene. The said olefin polymer composition exhibits a value of elongation at break ranging from 150 to 600% according to ISO method 527.

    Abstract translation: 一种烯烃聚合物组合物，该组合物含有（除非另有说明，按重量计）：A）60-85％的结晶丙烯均聚物或含3％或更少的乙烯或C 4 -C 10α-烯烃的结晶共聚物或 所述均聚物或共聚物具有从4.5-6的多分散指数（PI）值和通过13C NMR测得的在25℃下不溶于二甲苯的部分的高于96％的等规五单元组含量（mmmm）; B）15-40％的含有35-70％丙烯或C4-C10α-烯烃或其组合的乙烯的部分无定形共聚物，以及任选小比例的二烯。 根据ISO方法527，所述烯烃聚合物组合物表现出150-600％的断裂伸长率值。

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