公开(公告)号：EP2859026A1

公开(公告)日：2015-04-15

申请号：EP13725706.9

申请日：2013-05-30

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MIGNOGNA, Alessandro ,  ESPOSITO, Simona ,  GUIDOTTI, Simona ,  MORINI, Giampiero ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F110/08 ,  C08F4/651

CPC classification number: C08F4/52 ,  C08F4/10 ,  C08F4/16 ,  C08F110/08 ,  C08F4/651 ,  C08F2500/15 ,  C08F2500/17 ,  C08F110/06 ,  C08F2500/12

Abstract: Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C
1 -C
15 hydrocarbon groups, the R
1 -R
2 groups, equal to or different from each other, are hydrogen, halogen or C
1 -C
15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor

Abstract translation: 在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti的固体催化剂组分和下式（I）的电子给体化合物：其中R基团等于或不同于 彼此是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P ，S，N和Si，n和m是0至3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

公开(公告)号：EP2697271A1

公开(公告)日：2014-02-19

申请号：EP12711393.4

申请日：2012-03-29

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  MORINI, Giampiero ,  ESPOSITO, Simona ,  MIGNOGNA, Alessandro ,  PATER, Joachim T. M. ,  PIEMONTESI, Fabrizio ,  BRITA, Diego

IPC: C08F10/06 ,  C08F4/651

CPC classification number: C08F4/16 ,  C08F10/06 ,  C08F4/651 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/02 ,  C08F210/06 ,  C08F2/001

Abstract: A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.

Abstract translation: 一种多孔固体催化剂组分，其包含卤化镁，具有至少一个Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种电子给体化合物选自1,3-二醚，另一种选自琥珀酸酯，其特征在于， ID / Ti的摩尔比为0.30至0.90，其中ID是琥珀酸酯和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸供体的摩尔比高于或等于 ，0.60。

公开(公告)号：EP2542593A1

公开(公告)日：2013-01-09

申请号：EP11704782.9

申请日：2011-02-22

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  PIEMONTESI, Fabrizio ,  PATER, Jochem T. M. ,  MORINI, Giampiero

IPC: C08F4/651 ,  C08F110/06 ,  C08F4/654 ,  C08F4/646

CPC classification number: C08F110/06 ,  C08F4/6545 ,  C08F4/6465 ,  C08F4/651 ,  C08F2500/15

Abstract: Catalyst component for the polymerization of olefins CH
2 =CHR in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Mg, Ti, halogen and two electron donor compounds one of which selected from alkoxybenzenes and the other being selected from those of formula (II) where R
1 and R
II are the same or different and are hydrogen or linear or branched C
1 -C
18 hydrocarbon groups which can also form one or more cyclic structures; R
III groups, equal or different from each other, are hydrogen or C
1 -C
18 hydrocarbon groups; R
IV groups equal or different from each other, have the same meaning of R
III except that they cannot be hydrogen; each of R
I to R
IV groups can contain heteroatoms selected from halogens, N, O, S and Si.

Abstract translation: 用于烯烃CH 2 = CHR聚合的催化剂组分，其中R为氢或具有1-12个碳原子的烃基，其包含Mg，Ti，卤素和两种电子给体化合物，其中一种选自烷氧基苯，另一种选自 式（II）的那些：其中R 1和R 2相同或不同并且是氢或者也可以形成一个或多个环状结构的直链或支链C 1 -C 18烃基; R III基团彼此相同或不同，为氢或C 1 -C 18烃基; R IV基团彼此相同或不同，具有与R III相同的含义，除了它们不能是氢; R 1至R IV基团中的每一个可以含有选自卤素，N，O，S和Si的杂原子。

公开(公告)号：EP3140328B1

公开(公告)日：2020-11-18

申请号：EP15719487.9

申请日：2015-05-06

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： PIEMONTESI, Fabrizio ,  CATHELIN, Caroline ,  GUIDOTTI, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero ,  TARTARI, Davide ,  VITALE, Gianni

IPC: C08F110/06 ,  C08F210/06 ,  C08F4/657

公开(公告)号：EP3331927A1

公开(公告)日：2018-06-13

申请号：EP16750729.2

申请日：2016-08-03

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MORINI, Giampiero ,  COVEZZI, Massimo ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F2/34 ,  C08F110/06 ,  C08F4/651 ,  C08F4/649

CPC classification number: C08F110/06 ,  C08F2/34 ,  C08F4/6492 ,  C08F4/651 ,  C08F10/06 ,  C08F110/02 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/18 ,  C08F4/6543

Abstract: A gas-phase process for the homopolymerization or copolymerization of propylene with other olefins, including carrying out the polymerization in the presence of a catalyst system made from or containing: (a) a solid catalyst component made from or containing Mg, Ti, halogen, an electron donor selected from 1.3-diethers and an olefin polymer in a specific amount; (b) an aluminum alkyl compound and (c) an external electron donor (ED) compound, wherein components (b) and (c) being employed in amounts such that the Al/(ED) molar ratio ranges from about 2 to about 200.

公开(公告)号：EP3331702A1

公开(公告)日：2018-06-13

申请号：EP16763451.8

申请日：2016-07-19

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MASSARI, Paola ,  CATHELIN, Caroline ,  CAVALIERI,Claudio ,  CIARAFONI, Marco ,  FELISATI, Andrea ,  FERRARO, Angelo ,  MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: B32B27/32 ,  C08J5/18 ,  C08L23/14

CPC classification number: B32B27/32 ,  B32B7/04 ,  B32B27/08 ,  B32B27/18 ,  B32B2307/548 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/14 ,  C08J2423/14 ,  C08L23/14 ,  C08L23/142 ,  C08L2201/10 ,  C08L2203/162 ,  C08L2205/025 ,  C08L2308/00 ,  C08F210/08 ,  C08F2/001 ,  C08F4/6492

Abstract: A film made from or containing a polyolefin composition made from or containing: A) from about 19 wt % to about 50 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene copolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene copolymer; and B) from about 50 wt % to about 81 wt %, based upon the total weight of the polyolefin composition, of a propylene ethylene 1-butene terpolymer having an ethylene derived units content ranging from about 1.5 wt % to about 6.0 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer, and 1-butene derived units content of between about 4.8 wt % and about 12.4 wt %, based upon the total weight of the propylene ethylene 1-butene terpolymer; the sum of the amount of component A) and B) being 100.

公开(公告)号：EP3140329A1

公开(公告)日：2017-03-15

申请号：EP15719698.1

申请日：2015-04-28

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： MASSARI, Paola ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni ,  CATHELIN, Caroline ,  MORINI, Giampiero ,  CIARAFONI, Marco ,  CAVALIERI, Claudio ,  CAPUTO, Tiziana

IPC: C08F110/06 ,  C08F210/06 ,  C08F4/657

CPC classification number: C08F210/06 ,  C08F210/02 ,  C08F2800/20 ,  C08J5/18 ,  C08J2323/14 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/26 ,  C08F10/00 ,  C08F4/6492 ,  C08F4/6574

Abstract: A propylene ethylene copolymer characterized by the following features: ethylene content of between 1.8 and 10.0% by weight; molecular weight distribution (MWD), expressed in terms of Mw/Mn, greater than 4.0; the content of xylene soluble fraction (XS) and ethylene content (C2) fulfill the following relation: XS

Abstract translation: 一种丙烯乙烯共聚物，其特征在于以下特征：乙烯含量在1.8至10.0重量％之间; 分子量分布（MWD），以Mw / Mn表示，大于4.0; 二甲苯可溶成分（XS）和乙烯含量（C2）的含量满足下列关系：XS <（C2x2.1）-2.4其中：XS​​ =在25℃下可溶于二甲苯的馏分的重量％ C2 =通过NMR确定的共聚物中乙烯单元的重量％。

公开(公告)号：EP3116921A1

公开(公告)日：2017-01-18

申请号：EP15711084.2

申请日：2015-03-10

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  DALL'OCCO, Tiziano ,  LIGUORI, Dario ,  MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F110/02 ,  C08F110/06 ,  C08F210/06 ,  C08F4/657 ,  C08F4/02 ,  C08F4/651

CPC classification number: C08F4/64 ,  C08F4/12 ,  C08F10/02 ,  C08F10/06 ,  C08F4/6545 ,  C08F4/6465 ,  C08F4/6574 ,  C08F110/06 ,  C08F2500/04 ,  C08F210/06 ,  C08F210/16 ,  C08F2500/12 ,  C08F4/022 ,  C08F4/651 ,  C08F110/02

Abstract: The present disclosure relates to a solid catalyst component for the (co)polymerization of olefins CH2═CHR, in which R is hydrogen or a hydrocarbyl radical with 1-12 carbon atoms, comprising Ti, Mg, and Cl, and optionally an electron donor compound selected from the group consisting of ethers, amines, silanes, carbamates ketones, esters of aliphatic acids, alkyl and aryl esters of optionally substituted aromatic polycarboxylic acids, diol derivatives chosen among monoesters monocarbamates and monoesters monocarbonates or mixtures thereof, comprising from 0.1 to 50% wt of Bi with respect to the total weight of the solid catalyst component.

Abstract translation: 本公开涉及用于烯烃CH 2 = CHR（其中R是氢或具有1-12个碳原子的烃基）的（共）聚合的固体催化剂组分，其包含Ti，Mg和Cl，以及任选的电子给体 选自醚，胺，硅烷，氨基甲酸酯酮，脂肪酸的酯，任选取代的芳族多元羧酸的烷基和芳基酯，选自单酯单乳酸单酯和单酯单碳酸酯的二醇衍生物或其混合物，其包含0.1至50 Bi的％wt相对于固体催化剂组分的总重量。

公开(公告)号：EP2900707A1

公开(公告)日：2015-08-05

申请号：EP13774374.6

申请日：2013-09-25

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： GUIDOTTI, Simona ,  ESPOSITO, Simona ,  LIGUORI, Dario ,  MORINI, Giampiero ,  PIEMONTESI, Fabrizio ,  VITALE, Gianni

IPC: C08F10/06 ,  C08F4/657 ,  C08F4/651

CPC classification number: C08F10/06 ,  C08F4/6574 ,  C08F4/651 ,  C08F110/02 ,  C08F2500/18 ,  C08F2500/21 ,  C08F110/06 ,  C08F210/06 ,  C08F210/16

Abstract: Catalyst components component for the (co)polymerization of olefins CH
2 =CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Zn, CI, and an electron donor compound characterized by the fact that more than 50% of the titanium atoms are in the +4 valence state, and that the amount of Zn ranges from 0.1 to 4% by weight based on then total weight of said solid catalyst component.

公开(公告)号：EP2419461A1

公开(公告)日：2012-02-22

申请号：EP10711909.1

申请日：2010-03-31

Applicant: Basell Poliolefine Italia S.r.l.

Inventor： VITALE, Gianni ,  PIEMONTESI, Fabrizio ,  MINGOZZI, Ines ,  CAMURATI, Isabella, Maria, Vittoria ,  PELLEGATTI, Giampaolo

IPC: C08F10/08 ,  C08F4/649 ,  C08F4/654

CPC classification number: C08F10/08 ,  C08F110/08 ,  C08F210/08 ,  C08F4/6494 ,  C08F2500/03 ,  C08F2500/15 ,  C08F2500/17 ,  C08F210/06 ,  C08F210/16

Abstract: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH
2 =CHZ wherein Z is a C
3 -C
20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl
2 (b) an alkylaluminum co catalyst; and (c) a compound of formula (I) as external donor Wherein: R
1 , R
2 , R
3 and R
4 , equal to or different from each other, are hydrogen atoms or C
1 -C
20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R
1 , R
2 , R
3 and R
4 can be joined to form a C
5 -C
20 , saturated or unsaturated ring.