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31.
公开(公告)号:GB869399A
公开(公告)日:1961-05-31
申请号:GB2392959
申请日:1959-07-13
Applicant: BASF AG
Inventor: POHLEMANN HEINZ , WINDERL SIEGFRIED , STUMMEYER HERBERT , ADOLPHI HEINRICH
Abstract: The invention comprises compounds of formula: where R1 and R2 are C1-4 alkyl, X is oxyge or sulphur, R3 is hydrogen, methyl or chlormethyl, n is 1 or 2, m is 3 to 7 and when n is 2, the R3 groups may be the same or different. They are prepared by reacting a compound: where Y is hydrogen, a metal or ammonium with a lactam or thiolactam of formula: where Z is hydroxyl or chlorine. A solvent may be used and temperatures of 15 to 100 DEG C. are mentioned, although lower temperatures may be used. The products have pesticidal properties (see Group VI).
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公开(公告)号:GB815965A
公开(公告)日:1959-07-01
申请号:GB3158
申请日:1958-01-01
Applicant: BASF AG
Inventor: POHLEMANN HEINZ , STUMMEYER HERBERT , ADOLPHI HEINRICH
Abstract: The invention comprises esters of formula where R and R1 are C1-4 alkyl groups, X is O or S, Hal is halogen, Z is H or a C1-4 saturated or unsaturated aliphatic hydrocarbon radical and Y is O or S or a sulphone, sulphoxy or -NH-group. They may be prepared by reacting an O,O-dialkyl phosphoric acid monohalide with a 3-halogen-butene-(3)-ol-(2) substituted in the 1-position of formula Specified butenols include various 1-alkoxy-, 1-alkenoxy-, 1-monoalkylamino-, 1-mono-alkenylamino-, 1 - alkylmercapto-, 1 - alkenylmercapto -, 1 - alkyl - or alkenyl - sulphoxy - or sulphonyl - 3 - chloro -, bromo - or iodo butene-(3)-ol-(2). Suitable phosphorus halides include the monochlorides, bromides and iodides of dialkylphosphoric and thionophosphoric acids. The reaction occurs in the cold but a temperature of 15-120 DEG C., preferably 40-50 DEG C., is preferred. An inert solvent may be used such as a hydrocarbon or chlorohydrocarbon. An acid-binding agent may also be used such as a tertiary amine or alkali carbonate or bicarbonate. Examples describe the preparation by reaction of the appropriate butenol and dialkyl phosphoric or thionophosphoric acid chloride or bromide of (1) diethyl 1-methoxy-3-chloro - butene - 3 - yl - 2 thionophosphate; (2) diethyl 1 - n - propylamino - 3 - chlorobutene - 3-yl-2 thionophosphate; (3) diethyl 1-ethylmercapto - 3 - chloro - butene - 3 - yl thionophosphate; (4) dimethyl 1-ethyl-mercapto-3-chloro - butene - 3 - yl - 2 thionophosphate; (5) dibutyl 1 - n - propylamino - 3 - chloro - butene - 3 - yl - 2 thionophosphate; (6) dipropyl 1 - ethylmercapto - 3 - chloro - butene - 3 - yl - 2 thionophosphate; (7) diethyl 1 - n - propylamino - 3 - chlorobutene - 3 - yl - 2 phosphate; (8) diethyl 1-amino-3-chloro-butene-3-yl-2 thionophosphate; and (9) diethyl 1-allylamino-3 -chlorobutene - 3 - yl - 2 thionophosphate; acid binding agents used are pyridine, and triethylamine which also act as solvents and sodium carbonate using methylene chloride as solvent.
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公开(公告)号:DE3767940D1
公开(公告)日:1991-03-14
申请号:DE3767940
申请日:1987-06-29
Applicant: BASF AG
Inventor: HIMMELE WALTER , THEOBALD HANS , GOETZ NORBERT , ZOMBIK WINFRIED , WILD JOCHEN , ADOLPHI HEINRICH , HOFMEISTER PETER , KUENAST CHRISTOPH
IPC: A01N43/16 , A01N43/28 , A01N43/30 , A01N43/32 , A01N43/80 , A01N47/12 , A01N47/20 , A01N47/32 , A01N49/00 , A01N53/00 , C07D309/10 , C07D309/12 , C07D309/14 , C07D309/30 , C07D311/02 , C07D311/94 , C07D407/12
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公开(公告)号:HU199852B
公开(公告)日:1990-03-28
申请号:HU447486
申请日:1986-10-24
Applicant: BASF AG
Inventor: BUERSTINGHAUS RAINER , KIEHS KARL , ADOLPHI HEINRICH , HARRIES VOLKER
Abstract: Bisthiolphosphates of the formula where R is alkyl, and pesticides containing these compounds.
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公开(公告)号:DK157679B
公开(公告)日:1990-02-05
申请号:DK49482
申请日:1982-02-05
Applicant: BASF AG
Inventor: LANGE ARNO , KIEHS KARL , ADOLPHI HEINRICH , BECKER RAINER
IPC: A01N47/34 , C07C275/54 , C07C275/46
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公开(公告)号:ZA8704878B
公开(公告)日:1989-03-29
申请号:ZA8704878
申请日:1987-07-06
Applicant: BASF AG
Inventor: HIMMELE WALTER , THEOBALD HANS , GOETZ NORBERT , ZOMBIK WINFRIED , WILD JOCHEN , ADOLPHI HEINRICH , HOFMEISTER PETER , KUENAST CHRISTOPH
IPC: A01N43/16 , A01N43/28 , A01N43/30 , A01N43/32 , A01N43/80 , A01N47/12 , A01N47/20 , A01N47/32 , A01N49/00 , A01N53/00 , C07D309/10 , C07D309/12 , C07D309/14 , C07D309/30 , C07D311/02 , C07D311/94 , C07D407/12 , C07D , A01N
CPC classification number: C07D407/12 , A01N43/16 , A01N43/28 , A01N43/30 , A01N43/32 , A01N43/80 , A01N47/12 , A01N47/20 , A01N47/32 , A01N49/00 , A01N53/00 , C07D309/10 , C07D309/30 , C07D311/02
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公开(公告)号:ZA852108B
公开(公告)日:1985-12-24
申请号:ZA852108
申请日:1985-03-21
Applicant: BASF AG
Inventor: HOFMEISTER PETER , BUERSTINGHAUS RAINER , ADOLPHI HEINRICH
IPC: C07D317/68 , A01N37/10 , A01N37/40 , A01N43/30 , A01N43/32 , A01N47/02 , C07C67/08 , C07C67/14 , C07C69/76 , C07C69/767 , C07C69/78 , C07C69/92 , C07D319/08 , C07D319/18 , C07C , C07D , A01N
Abstract: Propargyl esters of the formula I (I) where R1 is OCnH2n+1 (n=1 or 2), OCF3, OCF2CHF2 or F and R2 is H, or R1 and R2 together form -O(CH2)mO- (m=1 or 2), a process for their preparation, and their use for controlling pests.
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38.
公开(公告)号:CA1191150A
公开(公告)日:1985-07-30
申请号:CA409757
申请日:1982-08-19
Applicant: BASF AG
Inventor: BUERSTINGHAUS RAINER , KIEHS KARL , SEUFERT WALTER , ADOLPHI HEINRICH
IPC: A01N57/10 , A01N57/12 , A01N57/18 , A01N57/20 , A01N57/22 , A01N57/26 , A01N57/28 , A01N57/30 , C07F9/02 , C07F9/09 , C07F9/11 , C07F9/165 , C07F9/17 , C07F9/24 , C07F9/40 , C07F9/06 , A01N57/00
Abstract: Oximinophosphoric acid derivatives of the formula (I) where R1 is straight-chain or branched alkyl of not more than 4 carbon atoms, R2 is a straight-chain or branched alkoxy or alkylthio group of not more than 4 carbon atoms, straightchain or branched alkoxyalkylthio of not more than 6 carbon atoms, straight-chain or branched alkyl of not more than 3 carbon atoms, phenyl or a straight-chain or branched alkylamino or dialkylamino radical where each alkyl is of not more than 4 carbon atoms, R3 is straight-chain or branched alkoxy of not more than 4 carbon atoms or methoxymethyl, and X is oxygen or sulfur, processes for their preparation and their use for controlling pests.
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39.
公开(公告)号:HU179118B
公开(公告)日:1982-08-28
申请号:HUBA003847
申请日:1979-09-10
Applicant: BASF AG
Inventor: BAUMANN ANNEGRIT , KIEHS KARL , ADOLPHI HEINRICH , KOENIG KARL-HEINZ
IPC: A01N47/34 , C07C275/34 , C07C275/54 , C07D213/82 , C07D333/38 , C07C127/22 , A01N9/20
Abstract: Aroylureas of the formula where A denotes a phenyl, thienyl or pyridyl-3 radical which is mono- or polysubstituted by halogen, linear or branched alkyl of 1 to 4 carbon atoms, or linear or branched alkoxy of 1 to 4 carbon atoms, R denotes linear or branched alkyl of 1 to 4 carbon atoms or linear or branched alkoxy of 1 to 4 carbon atoms, and n denotes one of the integers 0,1 and 2, which have an insecticidal and acarididal action, and a process for combating insects and mites with these active ingredients.
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公开(公告)号:ZA8104638B
公开(公告)日:1982-08-25
申请号:ZA8104638
申请日:1981-07-09
Applicant: BASF AG
Inventor: BUERSTINGHAUS RAINER , KIEHS KARL , ADOLPHI HEINRICH , POMMER ERNST HEINRICH
IPC: A01N57/10 , A01N57/12 , A01N57/14 , A01N57/26 , A01N57/28 , C07F9/165 , C07F9/173 , C07F9/24 , C07F9/32 , C07F9/36 , A01N , C07F
CPC classification number: C07F9/1651 , A01N57/12 , A01N57/14 , A01N57/28 , C07F9/1653 , C07F9/173 , C07F9/2408
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