Mixtures with special softening agents suited as a solid electrolyte or separator for electrochemical cells

    公开(公告)号:AU9629298A

    公开(公告)日:1999-04-27

    申请号:AU9629298

    申请日:1998-10-01

    Applicant: BASF AG

    Abstract: A mixture Ia comprises a mix IIa composed ofa) from 1 to 95% by weight of a solid III, preferably a basic solid III, with a primary particle size of from 5 nm to 20 mum andb) from 5 to 99% by weight of a polymeric composition IV, obtainable by polymerizingb1) from 5 to 100% by weight, based on the composition IV, of a condensation product V ofalpha) at least one compound VI which is capable of reacting with a carboxylic acid or with a sulfonic acid or with a derivative or a iixture of two or more of these, andbeta) at least 1 mol per mole of the compound VI of a carboxylic acid or sulfonic acid VII which has at least one functional group capable of free-radical polymerization, or of a derivative thereof or of a mixture of two or more thereof andb2) from 0 to 95% by weight, based on the composition IV, of another compound VIII with an average molecular weight (number average) of at least 5000 having polyether segments in its main or side chain and at least one ester of the formula (E1) to (E5)where each of R , R , R and R is identical with or different from the others and, independently of the others, is linear or branched-chain C1-C4-alkyl (-CH2-CH2-O)n-CH3, where n is from 1 to 3, C3-C6-cycloalkyl or an aromatic hydrocarbon group which may in turn be substituted, with the proviso that at least one of the groups R , R , R or R is (-CH2-CH2-O)n-CH3, where n is from 1 to 3.

    COMPOSITE SUITABLE FOR USE IN ELECTROCHEMICAL CELLS

    公开(公告)号:CA2305218A1

    公开(公告)日:1999-04-22

    申请号:CA2305218

    申请日:1998-10-08

    Abstract: A composite comprises Aa) at least one first layer which comprises a mixture Ia, comprising a mix IIa consisting of a) from 1 to 95 % by weight of a solid III, preferably a basic solid III, having a primary particle size of from 5 nm to 20 .mu.m and b) from 5 to 99 % by weight of a polymeric composition IV obtainable by polymerization of b1) from 5 to 100 % by weight, based on the composition IV, of a condensation product V of .alpha.) at least one compound VI which is able to react with a carboxylic acid or a sulfonic acid or a derivative or a mixture of two or more thereof, and .beta.) at least 1 mol per mol of the compound VI of a carboxylic acid or sulfonic acid VII which contains at least one free-radically polymerizable functional group, or a derivative thereof or a mixture of two or more thereof, and b2) from 0 to 95 % by weight, based on the composition IV, of a further compound VIII having a mean molecular weight (number average) of at least 5000 and polyether segments in the main chain or a side chain, where the proportion by weight of the mix IIa in the mixture Ia is from 1 to 100 % by weight, and the layer is free of an electron-conducting, electrochemically active compound, and B) at least one second layer which comprises an electron-conducting, electrochemically active compound, wherein the first layer or layers and the second layer or layers are joined to one another by one of the two methods V1 or V2: V1) Lamination of the first layer or layers with the second layer or layers under the action of heat or pressure or under the action of heat and pressure, or V2 Corona treatment of the first layer or layers, the second layer or layers or the first layer or layers and the second layer or layers and subsequent bringing together of the corona-treated first layer or layers with the corona-treated or untreated second layer or layers.

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