公开(公告)号：EP0677080A1

公开(公告)日：1995-10-18

申请号：EP94903854.0

申请日：1993-12-21

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KRONER, Matthias ,  HARTMANN, Heinrich ,  SCHORNICK, Gunnar ,  BAUR, Richard ,  POTTHOFF-KARL, Birgit ,  SCHWENDEMANN, Volker ,  KUD, Alexander

IPC: B01F17 ,  C08G69 ,  C08G73 ,  C09B67 ,  C09D17 ,  C11D3

CPC classification number: C11D3/3719 ,  B01F17/005 ,  C08G69/10 ,  C08G73/0611 ,  C08G73/1092 ,  C09B67/0085 ,  C09D17/00

Abstract: Described is a method of producing polymers of aspartic acid by reacting (a) maleic acid anhydride and (b) ammonia and/or primary or secondary amines essentially in the molar ratio (a):(b) of 1:0.1 to 1:3 to give half-amides of maleic acid or fumaric acid, or their ammonium salts, at temperatures of up to 100 DEG C and subsequently condensing the reaction products with each other, optionally also with compounds capable of condensing with them, at temperatures above 100 DEG C and optionally hydrolysing the condensation products. Also described is the use of the polymers thus produced as scale inhibitors, pigment dispersants and additives to washing and cleaning agents.

公开(公告)号：EP0656914A1

公开(公告)日：1995-06-14

申请号：EP93917793.0

申请日：1993-08-16

Applicant: BASF Aktiengesellschaft

Inventor： FUNHOFF, Angelika ,  MC KEE, Graham, Edmund ,  HARTMANN, Heinrich ,  BAUR, Richard ,  KUD, Alexander ,  SCHWENDEMANN, Volker

IPC: B01F17 ,  C08G2 ,  C08G4 ,  C11D3

CPC classification number: C11D3/3711 ,  B01F17/0028 ,  C08G2/18 ,  C08G4/00

Abstract: A process for the production of polyacetals by the copolymerisation of glyoxylic acid esters with cyclic formals derived from dioles, homopolymers of formaldehyde, trioxepane or mixture of these compounds, in which up to 50 wt % of this group of monomers may be replaced by other conventional copolymerisable monomers like epoxides, aldehydes with at least 2 C atoms, tetrahydrofurane and/or C2 to C4 olefines, in the presence of anionic or cationic polymerisation initiators and possibly the hydrolysis of the glyoxyl acid esters polymerised into the copolymer, use of the polyacetal carboxylates thus obtainable as an additive in low-phosphate and phosphate-free washing and cleaning agents, as a water treatment agent and as a dispersant for finely divided substances, and polyacetals which are obtainable by the anionically or cationically initiated copolymerisation of glyoxyl acid esters with cyclic formals derived from diols and possibly the introduction of stable final groups and possibly hydrolysis of the ester groups of the glyoxyl acid esters polymerised into the copolymers.

公开(公告)号：EP0652936A1

公开(公告)日：1995-05-17

申请号：EP93915947.0

申请日：1993-07-17

Applicant: BASF Aktiengesellschaft

Inventor： KRONER, Matthias ,  HARTMANN, Heinrich ,  BOECKH, Dieter ,  BAUR, Richard ,  KUD, Alexander ,  SCHWENDEMANN, Volker

IPC: C08G69 ,  C08G73 ,  C11D3

CPC classification number: C11D3/2082 ,  C08G69/00 ,  C08G73/00 ,  C11D3/2086 ,  C11D3/37

Abstract: Reaction products from polybasic carboxylic acids- and amino groups-containing compounds are obtained by heating mixtures of (a) polybasic carboxylic acids from the group composed of citric acid, isocitric acid, aconitic acid, itaconic acid and/or tartaric acid and (b) amino group-containing compounds, at a molar ratio of (a):(b) from 1:0.1 to 1:10 at temperatures of at least 80 °C. Also disclosed is a process for preparing these polymer reaction products, as well as their use as additives for phosphate-poor and phosphate-free washing and cleaning agents.

公开(公告)号：EP0621908A1

公开(公告)日：1994-11-02

申请号：EP93902188.0

申请日：1993-01-14

Applicant: BASF Aktiengesellschaft

Inventor： SCHWENDEMANN, Volker ,  GLASER, Klaus ,  TSCHANG, Chung-Ji ,  BURKHART, Bernd ,  OFTRING, Alfred ,  DUNG, Bernhard

IPC: C25D3

CPC classification number: C25D3/14

Abstract: Des pièces moulées nickelées sont produites par dépôt électrolytique de nickel dans des bains acides aqueux qui contiennent comme constituants essentiels un ou plusieurs sels de nickel, un ou plusieurs acides inorganiques et au moins deux brillanteurs. On utilise comme brillanteurs un mélange de: (A) 2 à 98 % en poids d'un ou plusieurs composés cycliques de N-allyl- ou N-vinylammonium ayant la formule (I), dans laquelle l'atome N fait partie d'un système cyclique pyridinique, quinoléique ou isoquinoléique, qui peut en outre porter un ou deux substituants alkyle ayant un à quatre atomes de carbone; R1, R3 et R4 désignent hydrogène ou alkyle C1-C4; R2 désigne hydrogène ou méthyle; m représente un nombre entre 0 et 4; n représente un nombre entre 1 et 4; et X- désigne un anion organique ou inorganique à valence n qui favorise la solubilité dans l'eau; et de (B) 98 à 2 % en poids d'un ou plusieurs composés acétyléniquement insaturés ayant la formule (II): R4-C=C-R5, dans laquelle les résidus R4 et R5 sont identiques ou différents et désignent alkyle C1-C4 substitué par hydroxyle, sulfo, amino, alkylamino C1-C4 ou di(C1-C4-alkyl)amino. On peut faire réagir les groupes hydroxyles avec 1 à 10 moles d'un oxyde d'alcylène C2-C4 ou d'un mélange de ces oxydes d'alcylène et un des résidus R4 ou R5 peut également désigner de l'hydrogène ou C1-C4-alkyle.

Abstract translation: 镀镍模制品通过在含有作为基本组分的一种或多种镍盐，一种或多种无机酸和至少两种光亮剂作为基本组分的含水酸浴中通过电镀镍来生产。 （A）2至98重量％的一种或多种具有式（I）的N-烯丙基 - 或N-乙烯基铵环状化合物的混合物，其中N原子是 可另外带有一个或两个具有1至4个碳原子的烷基取代基的吡啶，喹啉或异喹啉环系统; R1，R3和R4代表氢或C1-C4烷基; R2是氢或甲基; m代表0和4之间的数字; n表示1和4之间的数字; X-表示促进在水中的溶解度的n价有机或无机阴离子; （B）98-2重量％的一种或多种具有式（II）的炔属不饱和化合物：R4-C = C-R5，其中残基R4和R5相同或不同并且表示C1-C4烷基; 被羟基，磺基，氨基，C 1 -C 4烷基氨基或二（C 1 -C 4烷基）氨基取代的C 4。 羟基可以与1至10摩尔的C 2 -C 4烯化氧或这些烯化氧的混合物反应，并且R 4或R 5残基之一还可以表示氢或C 1 -C 4烷基， C4烷基。

公开(公告)号：EP1819760A2

公开(公告)日：2007-08-22

申请号：EP05810889.5

申请日：2005-11-26

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KARL, Ulrich ,  FRENZEL, Stefan ,  SCHWENDEMANN, Volker ,  STEINBRENNER, Ulrich ,  LEININGER, Hartmut

IPC: C08J9/40

CPC classification number: C08J9/40 ,  C08J9/405 ,  C08J2205/05

Abstract: The invention relates to a method for producing modified open-cell foams consisting in bringing into contact (a) open-cell foams whose density ranges from 5 to 500 kg/m3 and average pore diameter ranges from 1νm to 1mm with (b) an aqueous formulation of at least one type of compound containing at least one half-aminal or aminal group per molecule or at least one type of polymer, in which at least one type of comonomer containing an OH or β-dicarbonyl or epoxy group is incorporated by polymerisation.

Abstract translation: 本发明涉及一种生产改性开孔泡沫塑料的方法，该方法包括使（a）密度范围为5-500kg / m 3，平均孔径范围为1μm-1mm的开孔泡沫与（b）含水 每个分子含至少一个半缩醛或缩醛基团的至少一种类型的化合物或至少一种类型的聚合物的制剂，其中至少一种含有OH或β-二羰基或环氧基团的共聚单体通过聚合引入 。

公开(公告)号：EP0777696B1

公开(公告)日：1998-02-25

申请号：EP95929870.4

申请日：1995-08-16

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KRONER, Matthias ,  SCHORNICK, Gunnar ,  STROTMANN, Uwe ,  SCHWENDEMANN, Volker ,  MEYER, Thomas ,  LUDWIG, Alfons

IPC: C08G73/06 ,  C08G69/10 ,  C08G73/10

CPC classification number: C02F5/12 ,  C08G73/1092 ,  C11D3/3719

Abstract: A process is disclosed for preparing polyaspartic acid salts by treating polycondensates in an aqueous medium with bases. At least 0.7 equivalents of an alkaline metal and/or alkaline earth metal base per mole of the aspartic acid, aspartic acid imide and/or amide units contained in the polycondensates are used. The bases are added during 30 minutes to 20 hours to an aqueous suspension of the polycondensates of aspartic acid heated up to 40 to 140 DEG C, and the reaction mixture is optionally allowed to continue to react. These alkaline metal and/or alkaline earth metal salts of polyaspartic acids obtained by treating aspartic acid polycondensates in an aqueous medium with more than 1 equivalent of an alkaline metal and/or alkaline earth metal base for reducing the molar mass of polycondensates are used as additives for washing and cleaning agents.

公开(公告)号：EP0648241B1

公开(公告)日：1997-08-27

申请号：EP93914689.0

申请日：1993-06-22

Applicant: BASF Aktiengesellschaft

Inventor： KRONER, Matthias ,  HARTMANN, Heinrich ,  BOECKH, Dieter ,  FUNHOFF, Angelika ,  BAUR, Richard ,  KUD, Alexander ,  SCHWENDEMANN, Volker ,  POTTHOFF-KARL, Birgit ,  BUECHNER, Karl-Heinz

IPC: C08G69/10 ,  C08F267/00 ,  C08F222/00 ,  C11D3/37 ,  C02F5/12 ,  C13F1/00

CPC classification number: C13B30/021 ,  C08F283/04 ,  C08G69/10 ,  C08G73/1092 ,  C11D3/3719 ,  C11D3/3788

Abstract: Modified polyaspartic acids are obtained by polycondensing (a) 1 to 99.9 mol % aspartic acid with (b) 99 to 0.1 mol % fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic polyhydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugar carboxylic acids and/or non-proteinogenic aminocarboxylic acids, or by polymerising monoethylenically unsaturated monomers in the presence of polyaspartic acids, in the manner of radically initiated graft copolymerisation. Also disclosed is a process for preparing these modified polyaspartic acids, as well as the use of these modified polyaspartic acids as additives to washing and cleaning agents, as water conditioning agents and as deposit inhibitors during the condensation of sugar juice.

公开(公告)号：EP0689555B1

公开(公告)日：1997-05-21

申请号：EP94909115.1

申请日：1994-03-05

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KRONER, Matthias ,  SCHORNICK, Gunnar ,  DENZINGER, Walter ,  BAUR, Richard ,  KUD, Alexander ,  POTTHOFF-KARL, Birgit ,  SCHWENDEMANN, Volker

IPC: C08F8/30 ,  C08F8/48

CPC classification number: C11D3/3719 ,  B01F17/005 ,  C08F8/44 ,  C08F2800/20 ,  C08G69/10 ,  C08G73/0611 ,  C08G73/1092 ,  C08F8/32 ,  C08F122/02 ,  C08F220/06 ,  C08F120/06 ,  C08F222/02

Abstract: The invention concerns polycocondensates of aspartic acid, obtained by condensing aspartic acid in the presence of carboxylic-group-containing polymers which include at least 10 mol % of a monoethylenically unsaturated carboxylic acid polymerized into the polymer and have a molecular weight of at least 300, in the ratio by weight of 1000:1 to 2:1. The invention also concerns methods of producing such polycocondensates and the use of the polycocondensates, in a form with free acid groups or in a form with the acid groups neutralized with ammonia, amines, alkali-metal bases or alkaline-earth bases, as an additive in washing and cleaning agents, as scale inhibitors or as dispersants for finely divided solids.

公开(公告)号：EP0573463B1

公开(公告)日：1997-05-14

申请号：EP92904766.0

申请日：1992-02-18

Applicant: BASF Aktiengesellschaft

Inventor： FUNHOFF, Angelika ,  SEELMANN-EGGEBERT, Hans-Peter ,  HARTMANN, Heinrich ,  BAUR, Richard ,  SCHWENDEMANN, Volker ,  KUD, Alexander ,  BERTLEFF, Werner

IPC: C08G2/14 ,  C08G2/18 ,  C11D3/37

CPC classification number: C11D3/3711 ,  C08G2/14 ,  C08G2/18

Abstract: Polyacetals containing units of formula (I), wherein R stands for H, C1-C4 alkyl or COOM, where M stands for a C1-C4 alkyl, alkali metal, ammonium and alkanolamine group, and m = 0 to 9, with K-values (determined by the H. Fikentscher method on the sodium salt in a 1 wt. % aqueous solution at 25 °C and pH 7) of at least 8.5. Method of preparing the polyacetals by polymerization of compounds of formula (II), wherein R stands for H, C1-C4 alkyl or COOM, where M stands for a C1-C4 alkyl, alkali metal, ammonium and alkanolamine group, R2 stands for C¿1?-C4 alkyl and m = 0 to 9, in the presence of initiators and possibly comonomers, and, possibly, hydrolysis of the ester groups of the polymers. Use of the polyacetals as additives in washing and cleaning agents.

公开(公告)号：EP0703972B1

公开(公告)日：1997-01-02

申请号：EP94918383.4

申请日：1994-06-03

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： DETERING, Jürgen ,  SCHADE, Christian ,  OPPENLAENDER, Knut ,  ZIRNSTEIN, Michael ,  SCHERR, Günter ,  TRIESELT, Wolfgang ,  SCHWENDEMANN, Volker

IPC: C11D3/37 ,  C08F283/04 ,  C08F283/00

CPC classification number: C11D3/3788 ,  C08F283/00 ,  C08G73/0206 ,  C08G73/0213 ,  C08G73/028 ,  C08F226/06

Abstract: Grafted polyamidoamines and polyethylene imines are produced by radically initiated polymerisation of (a) 1-vinylpyrrolidone, 1-vinyltriazol, 1-vinylimidazols, mixtures of said monomers or mixtures of at least one of said monomers with up to 20 % by weight other monoethylenically unsaturated monomers, in the presence of (b) water-soluble or water-dispersible polyamidoamines, polyethylene imines or their mixtures, the ratio by weight (a):(b) being comprises from 5:95 to 95:5. Also disclosed is a process for producing these grafted plymers, the use of the grafted polyamidoamines and polyethylene imines as additives in washing agents in order to inhibit colour transfer during the washing process and a washing agent based on surfactants which contains 0.05 to 10 % by weight of said grafted polymers.