公开(公告)号：EP0847394A1

公开(公告)日：1998-06-17

申请号：EP96930128.0

申请日：1996-08-29

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： OTTEN, Martina ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  HILL, Regina, Luise ,  KARDORFF, Uwe ,  VOSSEN, Marcus ,  PLATH, Peter ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf

IPC: C07D333 ,  A01N43 ,  C07D275 ,  C07D279 ,  C07D327 ,  C07D335 ,  C07D409 ,  C07D495

CPC classification number: C07D335/06 ,  A01N43/12 ,  A01N43/18 ,  C07D333/64 ,  C07D333/66 ,  C07D495/10

Abstract: Benzoyl derivatives according to formula (I), where substituents L, M, X, Y and n have the meaning given in claim 1 and Q stands for a 2-position cross-linked cyclohexane-1,3-dione ring according to formula (II), where R?15, R16, R18, and R20¿ indicate hydrogen or C¿1?-C4-alkyl, R?19¿ indicates hydrogen, C¿1?-C4-alkyl or a -COOR?14¿ group, R17 indicates hydrogen, C¿1?-C4-alkyl or C3-C4-cycloalkyl where these groups may carry one to three of the following substituents: halogen, C1-C4-alkylthio or C1-C4 alkoxy, or R?17¿ indicates tetrahydropyranyl-3, tetrahydropyranyl-4 or tetrahydrothiopyranyl-3, or R?17 and R20¿ together form a bond or a three to six member carbocyclic ring, where in the case that Y = C=O, X is not equal to NR23, and agriculturally usable salts, a process for the production thereof and their use as herbicides.

公开(公告)号：EP0846113A1

公开(公告)日：1998-06-10

申请号：EP96927702.0

申请日：1996-08-07

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  ZAGAR, Cyrill ,  SCHIFFER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf ,  WALTER, Helmut

IPC: A01N43 ,  C07D401 ,  C07D521

CPC classification number: C07D231/12 ,  A01N43/56 ,  C07D233/56 ,  C07D249/08 ,  C07D401/04

Abstract: The invention concerns substituted 1-(pyridyl)-pyrazols of general formula (I) in which the substituents have the following meanings: R1: hydrogen, C¿1?-C3 alkyl, halogen, C1-C3 alkyl halide; R?2: C¿1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkinyl, C1-C4 alkoxy, C3-C4 alkenyloxy, C3-C4 alkinyloxy, which can be substituted by 1 to 6 halogen atoms, NO2, cyano, halogen, rhodano, amino, furthermore a C(=O)R7, S(O)¿nR?8 or NH-C(=O)R9 group; R3: amino, halogen, rhodano, cyano, nitro, hydroxy, C¿1?-C3 alkyl, C1-C3 alkyl halide, furthermore an S(O)nR?8, N(R10)R11, OR12, SR13, N=C(R14)-N(R15)R16¿ group or, if R1 = hydrogen, additionally N=C(R?17)R18; R4¿: halogen, an XR19 group or, if R3 = N=C(R?14)-N(R15)R16¿ and N(R?10)R11 when R10¿ = hydrogen or C(=O)R?7 and R11 = C¿3-C4 alkenyl or C3-C4 alkinyl or, if R6 = fluorine or trifluoromethyl, additionally hydrogen; and R5, R6: independently of each other, halogen or C¿1?-C3 alkyl halide. The invention further concerns the N-oxides and salts of compounds (I) which can be used for agricultural purposes, processes for their preparation and their use as herbicides.

公开(公告)号：EP0836594A1

公开(公告)日：1998-04-22

申请号：EP96922038.0

申请日：1996-06-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  SCHÄFER, Peter ,  ZAGAR, Cyrill ,  WESTPHALEN, Karl-Otto ,  WALTER, Helmut ,  MISSLITZ, Ulf ,  MENKE, Olaf ,  MENGES, Markus

IPC: A01N43 ,  A01N47 ,  A01N53 ,  C07C239 ,  C07C265 ,  C07C271 ,  C07C275 ,  C07D239 ,  C07D405

CPC classification number: C07D239/54 ,  A01N43/54 ,  A01N47/12 ,  A01N47/24 ,  A01N47/30 ,  A01N53/00 ,  C07C239/08 ,  C07C239/10 ,  C07C265/12 ,  C07C271/22 ,  C07C271/28 ,  C07C271/54 ,  C07C271/58 ,  C07C275/40

Abstract: The invention pertains to benzylhydroxylamines of formula (I), wherein X is -N(R7)-O-; Y is O, S; R1 is halogen, CN, NO¿2?, CF3; R?2¿ is H, halogen; R3 is H, NH¿2?, CH3; R?4¿ is H, halogen, C¿1?-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkyl thio, C1-C6 alkyl sulfinyl or C1-C6 alkyl sulfonyl; R?5¿ is H, halogen, C¿1?-C6 alkyl; R?6¿ is H, C¿1?-C6 alkyl, C1-C6 alkyl halide, C3-C6 cycloalkyl, C2-C6 alkenyl; R?8¿ is H, C¿1?-C6 alkyl, C3-C8 cycloalkyl, C1-C6 alkyl halide, C3-C6 alkenyl or C3-C6 alkinyl, where each of the last five radicals indicated can carry 1-3 substituents. The invention also pertains to the salts of (I), with R?3, R7¿ and/or R8 being hydrogen. These compounds are useful as herbicides and for desiccation/defoliation of plants.

公开(公告)号：EP0811007A1

公开(公告)日：1997-12-10

申请号：EP96902274.0

申请日：1996-02-14

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： VON DEYN, Wolfgang ,  HILL, Regina, Luise ,  KARDORFF, Uwe ,  ENGEL, Stefan ,  OTTEN, Martina ,  VOSSEN, Marcus ,  PLATH, Peter ,  RANG, Harald ,  HARREUS, Albrecht ,  KÖNIG, Hartmann ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  MISSLITZ, Ulf

IPC: C07D231 ,  A01N43 ,  C07D277 ,  C07D401 ,  C07D403 ,  C07D405 ,  C07D409 ,  C07D411 ,  C07D413 ,  C07D417

CPC classification number: C07D401/10 ,  A01N43/56 ,  A01N43/74 ,  A01N43/80 ,  C07D231/24 ,  C07D403/10 ,  C07D405/10 ,  C07D409/10 ,  C07D411/10 ,  C07D413/10 ,  C07D417/10

Abstract: Pyrazol-4-yl-benzoyl derivatives have the formula (I), in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)¿n-CO-R?8; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is O, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR?9R10; R8 is C¿1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR?9R10; R9¿ is hydrogen or C¿1?-C4 alkyl; R?10 is C¿1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula (II) in which R1 is C1-C4 alkyl; R2 is hydrogen or C¿1?-C4 alkyl; and R?3¿ is hydrogen, C¿1?-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture.

公开(公告)号：EP0695302B1

公开(公告)日：1997-08-13

申请号：EP94913587.5

申请日：1994-04-13

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： BAUMANN, Ernst ,  HARREUS, Albrecht ,  BRATZ, Matthias ,  RHEINHEIMER, Joachim ,  VOGELBACHER, Uwe, Josef ,  THEOBALD, Hans ,  GERBER, Matthias ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto ,  RADEMACHER, Wilhelm

IPC: C07D409/12 ,  C07D405/12 ,  C07D401/12 ,  A01N43/54 ,  A01N43/66 ,  C07D333/24 ,  C07D213/55

CPC classification number: C07D239/34 ,  A01N43/54 ,  C07D401/12 ,  C07D403/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/10 ,  C07D417/12 ,  C07D491/04

Abstract: The invention concerns 3-halo-3-heteroaryl carboxylic acid derivatives of formula (I) in which R is a formyl group, a CO2H group or a group which can be hydrolysed to give a COOH group and the other substituents are as follows: R?2 and R3¿ are halogen, C¿1?-C4 alkyl, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy or C1-C4 alkylthio; X is nitrogen or CR?13, R13¿ being hydrogen or forming, together with R3, an alkylene or alkenylene chain in which each methylene group may be replaced by oxygen; R4 is an optionally substituted five-membered or six-membered heteroaromatic ring containing one to three nitrogen atoms and/or a sulphur or oxygen atom; R5 is hydrogen or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl or phenyl; Y is sulphur, oxygen or a single bond; Z is halogen.

公开(公告)号：EP0777658A1

公开(公告)日：1997-06-11

申请号：EP95923241.0

申请日：1995-06-07

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： HEISTRACHER, Elisabeth ,  VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  HAMPRECHT, Gerhard ,  KLINTZ, Ralf ,  SCHÄFER, Peter ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: A01N43 ,  C07D249

CPC classification number: A01N43/653 ,  C07D249/12

Abstract: Substituted triazolinones of formula (I) are disclosed, in which R1, R2 represent C¿1?-C6 alkyl or C1-C6 alkyl halide; R?3¿ represents H or a halogen; R4 represents CN, a halogen, C¿1?-C6 alkyl, C1-C6 alkyl halide, C1-C6 alkoxy or C1-C6 alkoxyl halide; R?5¿ represents NO¿2?, CN or hydrogen; R?6¿ represents -OR?7, -SR7, -N(R8)-R9¿ or -N(R?8)-OR10; R7¿ represents H, C¿1?-C6 alkyl, C3-C6 alkenyl, C3-C6 alkinyl, C3-C6 cycloalkyl, C1-C6 alkyl halide, cyano-C1-C6 alkyl, C1-C6 alkoxy-C1-C6-alkyl, C1-C6 alkylthio-C1-C6-alkyl, C1-C6 alkoxycarbonyl-C1-C6-alkyl, C1-C6-alkylaminocarbonyl-C1-C6-alkyl, Di-(C1-C6-alkyl)-aminocarbonyl-C1-C6 alkyl, C1-C6 alkyloxyamino-C1-C6 alkyl, Di-(C1-C6-alkoxy)-C2-C6-alkyl, Di-(C1-C6-alkylthio)-C2-C6 alkyl, C3-C6 alkenyl halide, (as required) substituted phenyl or benzyl; R?8, R9, R10¿ represent C¿1?-C6 alkylcarbonyl, C1-C6 alkylcarbonyl halide or one of the possible R?7¿ groups; R8 + R9 represent a halide 4 to 6-membered C chain in which one methylene unit can be replaced by oxygen or C¿1?-C4 alkylamino. Also disclosed are the salts of compounds of formula (I). Use as herbicides, for desiccation and defoliation of plants.

公开(公告)号：EP0775123A2

公开(公告)日：1997-05-28

申请号：EP95927733.0

申请日：1995-07-27

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： PLATH, Peter ,  KARDORFF, Uwe ,  VON DEYN, Wolfgang ,  ENGEL, Stefan ,  KAST, Jürgen ,  RANG, Harald ,  KÖNIG, Hartmann ,  GERBER, Matthias ,  WALTER, Helmut ,  WESTPHALEN, Karl-Otto

IPC: C07D275 ,  A01N43 ,  A01P13 ,  C07D417

CPC classification number: C07D275/06 ,  A01N43/80 ,  C07D417/10

Abstract: Saccharin derivatives of formula (I) are disclosed, wherein the substituents have the following meanings: L, M stand for hydrogen, alkyl, alkoxy, alkylthio, chlorine, cyano, methylsulphonyl, nitro or trifluoromethyl; Z stands for hydrogen, alkyl, cycloalkyl, alkenyl, alkinyl, acyl, benzyl (optionally substituted by halogen, alkyl), or phenyl; J stands for an optionally substituted cyclohexane-1,3-dione ring linked at position 2.

公开(公告)号：EP0770067A1

公开(公告)日：1997-05-02

申请号：EP95924968.0

申请日：1995-07-04

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  SCHÄFER, Peter ,  VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  MÜNSTER, Peter ,  KIRSTGEN, Reinhard ,  HARREUS, Albrecht ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: C07D239 ,  A01N37 ,  A01N43 ,  C07C251 ,  C07C259 ,  C07C265 ,  C07C271 ,  C07C331 ,  C07D209 ,  C07D413

CPC classification number: C07D209/48 ,  A01N37/32 ,  A01N37/50 ,  A01N43/54 ,  C07C251/40 ,  C07C259/06 ,  C07C265/14 ,  C07C271/28 ,  C07C271/58 ,  C07C331/28 ,  C07D239/54

Abstract: Substituted cinnamic oxime derivatives (I) and hydroxamide derivatives (II) (formulae I and II) where R1 = halogen, NO¿2?, CN, CF3; R?2¿ = H, halogen; R3 = H, halogen, C¿1?-C6 alkyl halide, C3-C6 alkenyl, C3-C6 alkinyl, hydroxy-C1-C4 alkyl; R?4¿ = H, halogen, -S-, -O-CO-, -O-SO¿2? or a chemical bond; Y' = -O- or -S-; R?5¿ = possibly substituted C¿1?-C6 alkyl or C1-C6 alkyl halide, C3-C6 alkenyl, C3-C6 alkinyl, possibly substituted phenyl or phenyl C1-C6 alkyl; or, if Y is -O-, -S- or a chemical bond, (C1-C6 alkyl) carbonyl or (C1-C6 alkoxy) carbonyl; or, if Y is a chemical bond, hydrogen or halogen; R?5' = R5¿, H or (C¿1?-C6 alkyl halide) carbonyl; R?6¿ = H, C¿1?-C6 alkyl, C1-C6 alkyl halide, C3-C6 cycloalkyl, C3-C6 alkenyl, C3-C6 alkinyl, hydroxy C1-C6 alkyl, C1-C6 alkoxy C1-C6 alkyl, C1-C6 alkylthio C1-C6 alkyl, cyano C1-C6 alkyl, (C1-C6 alkoxy) carbonyl C1-C6 alkyl, (C1-C6 alkyl) carbonyl C1-C6 alkyl, (C1-C6 alkyl) carbonyloxy C1-C6 alkyl or possibly substituted phenyl C1-C6 alkyl or, if Y is oxygen or sulphur, R?5 + R6¿ together = substituted C¿1?-C3 alkylene; Cyc = N-(3,4,5,6 tetrahydrophthalimido) or (a), X?1, X2¿ = oxygen or sulphur; R7 = H, C¿1?-C6 alkyl, C1-C6 alkyl halide, NH2; R?8, R9¿ = H, halogen, C¿1?-C6 alkyl, C1-C6 alkyl halide or possibly substituted phenyl; and salts of I and II. Use: herbicides; desiccation/defoliation of plants.

公开(公告)号：EP0763025A1

公开(公告)日：1997-03-19

申请号：EP95921788.0

申请日：1995-05-31

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  SCHÄFER, Peter ,  DITRICH, Klaus ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: C07D231 ,  A01N43 ,  A01N47 ,  C07D401 ,  C07D403 ,  C07D405 ,  C07D409

CPC classification number: C07D401/10 ,  A01N43/56 ,  C07D231/22 ,  C07D403/10 ,  C07D405/10

Abstract: Substituted 3-phenylpyrazoles (I) in which: R1 represents -C(R?8)=C(R7,R12¿), (a), -C(R?9,R10)-C(R8,R11,R12¿), (b), (c), -C(R9)=C(R8)-phenyl or -C(R?9,R10)-C(R8,R13¿)-phenyl; R2 represents CN, CF¿3?, halogen; R?3¿ represents H, C¿1?-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl; R?4¿ represents C¿1?-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkylsulfinyl, C1-C4-haloalkylsulfinyl, C1-C4-alkylsulfonyl, C1-C4-haloalkylsulfonyl; R?5¿ represents H, NO¿2?, halogen, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R?6¿ represents H, halogen; Y represents -O-, -S-, -CH¿2?-; Z represents 2- to 5-membered chain; R?7¿ represents CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted aminocarbonyl; R?8, R9, R10, R13¿ represent H, CN, halogen, C¿1?-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, carboxylic acid/ester radical, substituted or unsubstituted -N(H)-CO-R?25¿, amino or aminocarbonyl: R11 represents CN, halogen, carboxylic acid/ester radical, substituted or unsubstituted amino or aminocarbonyl, azido, OH, (halo)alkoxy, alkenyloxy, alkylcarbonyloxy; R12 represents isoxazolidinylcarbonyl, carboxylic acid/ester radical, acid amide group, -CO-O-N=C(R31)-(C1-C6-alkyl), -CO-O-N=C(R31)-CO-O-(C¿1?-C6-alkyl), -CO-O-N=C(R31)-(C1-C4-alkyl)-CO-O-(C1-C4-alkyl)-CO-O-CH2-R?14¿, -CO-O-C(R14)-(C1-C4-alkyl), substituted or unsubstituted aminocarbonyl or aminothiocarbonyl, -CO-NH-SO2-(C1-C4-alkyl), -CO-R36, -CO-O-(C¿1?-C4-alkyl)-C(R?14¿)=N-O-(C¿1?-C4-alkyl), substituted or unsubstituted -CO-NH-CH(R?30¿)-(COOH/ester) substituted or unsubstituted cyclopentyliminooxy- or cyclohexyliminooxycarbonyl; R14 represents H, C¿1?-C4-alkyl, phenyl, benzyl; R?25, R30¿ represents H, C¿1?-C6-alkyl, C1-C6-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, substituted or unsubstituted C3-C7-cycloalkyl, phenyl or phenyl-C1-C6-alkyl; R?31¿ represents C¿1?-C6-alkyl, C1-C4-haloalkyl, C1-C6-alkoxy-C1-C4-alkyl, C1-C6-alkoxycarbonyl-C1-C4-alkyl, di-[C1-C6-alkoxycarbonyl]-C1-C4-alkyl, C3-C6-cycloalkyl, C1-C6-alkoxy, C1-C6-alkoxycarbonyl, 2-furyl, substituted or unsubstituted phenyl; R?36¿ represents H, halogen, C¿1?-C4-alkyl, C2-C4-alkenyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, are used as herbicides.

公开(公告)号：EP0759907A1

公开(公告)日：1997-03-05

申请号：EP95920017.0

申请日：1995-05-10

Applicant: BASF AKTIENGESELLSCHAFT

Inventor： VON DEM BUSSCHE-HÜNNEFELD, Christoph-Sweder ,  KLINTZ, Ralf ,  HAMPRECHT, Gerhard ,  HEISTRACHER, Elisabeth ,  SCHÄFER, Peter ,  MÜNSTER, Peter ,  DITRICH, Klaus ,  KÖNIG, Hartmann ,  WESTPHALEN, Karl-Otto ,  GERBER, Matthias ,  WALTER, Helmut

IPC: A01N43 ,  A01N53 ,  C07D231 ,  C07D401 ,  C07D403 ,  C07D405 ,  C07D409 ,  C07D411 ,  C07D413 ,  C07F9

CPC classification number: A01N53/00 ,  A01N43/56 ,  C07D231/18 ,  C07D231/20 ,  C07F9/65033

Abstract: Substituted 3-phenylpyrazoles of formula (I), where R1 is H, or a substituent; R2 is CN, CF¿3?, halogen; R?3¿ is H, alkyl, halogenalkyl; R4 is C1-C4 alkyl, C1-C4 halogenalkyl; R5 is H, NO¿2?, halogen, -COOR, optionally substituted aminocarbonyl (where R is H, a substituent); and Z is -O-, -S-, -SO-, -SO2-; and agriculturally usable salts thereof, for use as herbicides.

Abstract translation: 式（I）的取代3-苯基吡唑，其中R1是H或取代基; R2是CN，CF 3，卤素; R 3是H，烷基，卤代烷基; R4是C1-C4烷基，C1-C4卤代烷基; R5是H，NO2，卤素，-COOR，任选取代的氨基羰基（其中R是H，取代基）; Z是-O - ， - S - ， - SO - ， - SO 2 - 和其农业上可用的盐，用作除草剂。