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公开(公告)号:AU2021238642A1
公开(公告)日:2022-10-06
申请号:AU2021238642
申请日:2021-03-17
Applicant: BASF SE , TRINAMIX GMBH
Inventor: BINDER KAI UWE , SIEDER GEORG , FERSTL WOLFGANG , KATZ TORSTEN , MODES GERD , HERMES WILFRIED , SCHMIDT FELIX , KETTNER MICHEL VALENTIN , BRILL JOCHEN , LUNGENSCHMIED CHRISTOPH
IPC: G05B19/418 , G01J3/02 , G01J3/28 , G01N21/27 , G01N21/31 , G01N21/35 , G01N21/359
Abstract: The present invention relates to a communication system (140), to a monitoring system (110) for in-situ monitoring of at least one substance (112) used in a gas scrubbing process, wherein the monitoring system (110) comprises the communication system (140), as well as to related methods (310, 312). The monitoring system (110) can, via the communication system (140), be used for monitoring the at least one substance (112) and to provide treatment data for treating the at least one substance (112). Herein, the communication system (140) comprises a cloud server (144), a first server (146), at least one second server (148, 148'), and at least one third server (150, 150'); wherein the first server (146) further has a first communication interface (156) configured to provide reference spectral information referring to at least one reference sample and reference analytical data to the cloud server (144); wherein each second server (148, 148') has a second communication interface (158, 158') configured to provide spectral information related to at least one substance (112) to the cloud server (144); wherein the cloud server (144) is configured to - generate a calibration model by using the reference spectral information referring to the at least one reference sample and the reference analytical data provided by the first server (146), wherein the calibration model comprises at least one parameter; - apply the calibration model to the spectral information related to the at least one substance (112) provided by the second server (148, 148'), whereby at least one value for the at least one parameter is extracted; - provide the at least one value for the at least one parameter to the first server (146) via the first communication interface (156); wherein the first server (146) is further configured to determine treatment data by using the at least one value for the at least one parameter provided by the cloud server (144), wherein the treatment data comprise at least one piece of data which is related to a proposed treatment of the at least one substance (112); wherein the first server (146) further has at least one third communication interface (160, 160'), wherein each third communication interface (160, 160') is configured to provide the treatment data to the at least one third server (150, 150').
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32.
公开(公告)号:EA032382B1
公开(公告)日:2019-05-31
申请号:EA201790452
申请日:2015-08-20
Applicant: BASF SE
Inventor: VORBERG GERALD , NOTZ RALF , INGRAM THOMAS , SIEDER GEORG , KATZ TORSTEN
Abstract: Изобретениеотноситсяк абсорбентудляселективногоудалениясероводородаизпотокатекучейгазовойсреды, содержащеговодныйраствор a) третичногоалканоламина; b) стерическизатрудненноговторичногоаминаобщейформулы (I), где Rи Rнезависимодруготдругавыбраныиз C-C-алкилаи C-C-гидроксиалкила; R, R, Rи Rсоответственнонезависимодруготдругавыбраныизводорода, C-C-алкилаи C-C-гидроксиалкилаприусловии, чтопоменьшеймереодиностаток Rи/или Rнаатомеуглерода, которыйнепосредственносоединенс атомомазота, означает C-C-алкилили C-C-гидроксиалкил, если Rозначаетводород; хи уозначаютцелыечисла 2-4 и z означаетцелоечисло 1-4; причеммолярноесоотношение b) к a) составляет 0,3-0,7; и c) кислотыв количестве, рассчитанномкакэквивалентнейтрализацииотносительнопротонируемыхатомовазотав (a) и (b), вдиапазоне 1,0-9,0%, причемкислота c) выбранаизнеорганическихкислот, выбранныхизфосфорнойкислотыи сернойкислоты, иорганическихкислот, выбранныхизфосфоновыхкислот, сульфокислот, карбоновыхкислот, третичныхаминокарбоновыхкислот, N-втор-алкиламинокарбоновыхкислоти N-трет-алкиламинокарбоновыхкислот. Предпочтительнымаминомформулы (I) является 2-(2-трет-бутиламиноэтокси)этанол. Абсорбентпозволяетустановлениеопределенной HS-селективностипридавлении, котороеобычноприсутствуетприочисткеприродногогаза. Крометого, изобретениеотноситсяк способуудалениясероводородаизпотокагазовойтекучейсреды, имеющегопарциальноедавление HS поменьшеймере 0,1 бари/илипарциальноедавление COпоменьшеймере 0,2 бар, посредствомуказанногоабсорбента.
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33.
公开(公告)号:ES2705764T3
公开(公告)日:2019-03-26
申请号:ES15753038
申请日:2015-08-20
Applicant: BASF SE
Inventor: VORBERG GERALD , NOTZ RALF , INGRAM THOMAS , SIEDER GEORG , KATZ TORSTEN
Abstract: Procedimiento para eliminar gases ácidos de una corriente de fluido seleccionada entre gases, la cual presenta una presión total de al menos 3,0 bares, en el cual la corriente de fluido se pone en contacto con un absorbente, el cual comprende una solución acuosa que comprende: a) una amina terciaria; b) una amina secundaria estéricamente impedidos la de la fórmula general (I)**Fórmula** en la cual R1 y R2 se seleccionan respectivamente, de modo independiente entre sí, entre alquilo de C1-4 e hidroxialquilo de C1-4; R3, R4, R5 y R6 se seleccionan respectivamente de manera independiente entre sí entre hidrógeno, alquilo de C1-4 e hidroxialquilo de C1-4, con la condición de que al menos un residuo R4 y/o R5 en el átomo de carbono que está unido directamente al átomo de nitrógeno represente alquilo de C1-4 o hidroxialquilo de C1-4, si R3 es hidrógeno; x e y son números enteros de 2 a 4 y z es un número entero de 1 a 4; donde la proporción molar entre b) y a) se encuentra en el intervalo de 0,3 a 0,7 y c) un ácido en una cantidad calculada como equivalente de neutralización con respecto a los átomos de nitrógeno protonables en a) y b), de 1,0 a 9,0%; en cuyo caso, en la corriente de fluido se presenta una presión parcial de sulfuro de hidrógeno de al menos 0,1 bar y una presión parcial de dióxido de carbono de al menos 0,2 bar.
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公开(公告)号:AU2017217911A1
公开(公告)日:2018-08-02
申请号:AU2017217911
申请日:2017-02-02
Applicant: BASF SE
Inventor: KATZ TORSTEN , NOTZ RALF , KERN ANDREAS
IPC: B01D53/14
Abstract: The invention relates to a method for separating C
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公开(公告)号:AU2016330797A1
公开(公告)日:2018-03-29
申请号:AU2016330797
申请日:2016-09-28
Applicant: BASF SE
Inventor: VORBERG GERALD , NOTZ RALF , INGRAM THOMAS , SIEDER GEORG , KATZ TORSTEN , GRUENANGER CHRISTIAN , DEGLMANN PETER
IPC: B01D53/14
Abstract: The invention relates to an absorbent for the selective removal of hydrogen sulfide from a fluid stream, containing an aqueous solution, comprising a) a tertiary amine; b) an amine pH promoter, selected from the compounds mentioned in the description; wherein the molar ratio between b) and a) is in the range of 0.05 to 1.0; and c) an acid having a pK
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公开(公告)号:CA2750458C
公开(公告)日:2017-10-24
申请号:CA2750458
申请日:2010-01-27
Applicant: BASF SE
Inventor: VORBERG GERALD , KATZ TORSTEN , SIEDER GEORG , RIEMANN CHRISTIAN , WAGNER RUPERT , LICHTFERS UTE , DENGLER ERIKA
Abstract: An absorbent for removing acidic gases from a fluid stream, comprising an aqueous solution a) of at least one metal salt of an amino carboxylic acid and b) of at least one acidic promoter, where the molar ratio of b) to a) is in the range from 0.0005 to 1Ø The acidic promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorbent exhibits, compared to absorbents based on amino acid salts, a reduced requirement for regeneration energy, without significantly reducing the absorption capacity of the solution for acidic gases. In a process for removing acidic gases from a fluid stream, the fluid stream is contacted with the absorbent.
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公开(公告)号:CA3013526A1
公开(公告)日:2017-08-17
申请号:CA3013526
申请日:2017-02-02
Applicant: BASF SE
Inventor: KATZ TORSTEN , NOTZ RALF , KERN ANDREAS
IPC: B01D53/14
Abstract: The invention relates to a method for separating C5-C8 hydrocarbons and acid gases from a fluid stream. According to said method: a) the fluid stream is brought into contact with an absorbent containing at least one amine, in an absorption zone, producing a de-acified fluid stream and an absorbent charged with acid gases; b) the charged absorbent is heated in a first heat exchanger and is expanded in a de-compression zone to a pressure of between 5 and 10 bar, producing a gas phase containing C5-C8 hydrocarbons and a charged absorbent stripped of hydrocarbons; c) the charged absorbent stripped of hydrocarbons is heated in an optional second heat exchanger and is fed into a stripper, in which the acid gases are at least partially released at a pressure of between 1 and 2.5 bar by supplying heat, producing a re-generated absorbent and a stream containing acid gas; and d) the re-generated absorbent is fed back into the absorption zone. The re-generated absorbent is used as the heating medium in the second heat exchanger and is used as the heating medium in the first heat exchanger after passing through the second heat exchanger. The relative quantities of heat transferred in the first heat exchanger and in the second heat exchanger are weighted such that the gas phase containing C5-C8 hydrocarbons contains between 50 and 97 vol.-% acid gases.
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公开(公告)号:CA2760732C
公开(公告)日:2017-05-09
申请号:CA2760732
申请日:2010-05-12
Applicant: BASF SE
Inventor: VORBERG GERALD , KATZ TORSTEN , SIEDER GEORG , RIEMANN CHRISTIAN , DENGLER ERIKA
IPC: B01D53/14
Abstract: An absorbent for removing acid gases from a fluid flow comprises an aqueous solution of a) at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) ranges between 0.0005 and 1Ø For example, the phosphonic acid is 1-hydroxyethane-1, 1-diphosphonic acid. Compared to absorbents based on amines or amine/promoter combinations, the absorbent requires less regeneration energy without substantially reducing the solution's capacity to absorb acid gases.
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公开(公告)号:CA3000274A1
公开(公告)日:2017-04-06
申请号:CA3000274
申请日:2016-09-07
Applicant: BASF SE
Inventor: INGRAM THOMAS , SIEDER GEORG , KATZ TORSTEN , VORBERG GERALD , NOTZ RALF
Abstract: The invention relates to the use of an amine of formula (I) where the groups R1 to R5 are defined as they are in the description, as well as to an absorption agent and a method for removing acid gases from a fluid flow, particularly for selectively removing hydrogen sulphide over carbon dioxide. The invention also relates to certain amines suitable for selectively removing hydrogen sulphide. Absorption agents based on the amines of formula (I) have a high degree of selectivity, high loading capacity and good regeneration capacity.
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40.
公开(公告)号:PE20150449A1
公开(公告)日:2015-04-08
申请号:PE2015000301
申请日:2013-08-19
Applicant: BASF SE
Inventor: KATZ TORSTEN , BARTLING KARSTEN
IPC: B01D53/14
Abstract: En el que a) la corriente de fluido que comprende agua se pone en contacto en una zona de absorcion con un absorbente que comprende al menos una amina, en donde se obtiene una corriente de fluido desacidificada y un absorbente cargado con gas acido, b) la corriente de fluido desacidificada se pone en contacto en una zona de lavado con un liquido de lavado acuoso, a fin de transferir amina arrastrada al menos en parte al liquido de lavado, en donde se obtienen una corriente de fluido desacidificada, desaminada y un liquido de lavado cargado de amina, c) la corriente de fluido desacidificada, desaminada se enfria corriente debajo de la zona de lavado, en donde un condensado superior absorbente se condensa de la corriente de fluido desaminada, desacidificada, d) el absorbente cargado se pasa a una zona de desorcion en donde los gases acidos se liberan al menos en parte, en donde se obtienen un absorbente regenerado y gases acidos desorbidos, e) el absorbente regenerado regresa a la zona de absorcion a fin de formar un circuito absorbente, f) el liquido de lavado cargado con amina y el condensado superior absorbente se introducen en el circuito absorbente y g) los gases acidos desorbidos se conducen a traves de una zona de enriquecimiento y los gases acidos que salen en la parte superior de la zona de enriquecimiento se enfrian, a fin de condensar de los gases acidos un condensado superior desorbente que en parte regresa a la zona de enriquecimiento y en parte sale del proceso
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