Abstract:
The present invention is directed to a method for making silica glass and silica glass preforms. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO2 is provided and introduced directly into the flame of a combustion burner, which converts the compound to silica, thereby forming finely divided amorphous soot. The soot is vaporized proximate the site where the liquid is converted into silica glass by atomizing the liquid, preferably with a stream of atomizing gas. A heater proximate the burner face and around the burner flame increases soot capture rate and allows for a reduction of the velocity of the atomizing gas. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass.
Abstract:
The present invention is directed to methods of producing soot used in the manufacture of optical waveguides. Both non-aqueous liquid reactants and aqueous solutions containing one or more salts are delivered through an atomizing burner assembly to form a homogenous soot stream containing the oxides of the selected elements contained within the non-aqueous liquid reactant and the aqueous solution. The resulting multi-component soot is collected by conventional methods to form preforms used in the manufacture of optical waveguide fibers. Alternatively, an aqueous solution may be atomized with a gas at a first burner assembly to form an aerosol and a reactant vaporized for delivery to a second burner assembly. Preforms produced by the methods are also disclosed. The aqueous solution is preferably one comprising a metal salt, e.g. acetate, nitrate, sulfate, carbonate, chloride, hydroxide. The metal of the metal salt is preferably an alkali metal, an alkaline earth metal, lead, lanthanum, cobalt, antimony, erbium, aluminum, neodymium, praeseodymium.
Abstract:
The present invention is directed to a method and apparatus for forming soot used in making glass, and in particular, optical waveguides. A liquid precursor (66) is first fed into orifice (52) of a liquid orifice insert (48 ) within an injector (44) positioned within an atomizing burner assembly, and is thereafter discharged from the injector into a pressurization chamber (56). An atomization gas (70) is also fed into the pressurization chamber (56) to mix with the liquid precursor liquid stream (68) which breaks into droplets (76) . The liquid precursor and atomization gas are forced under pressure out of an atomization orifice (32) on the face of the burner (30) assembly. Flame gas (74), reaction gas (84) and shield gas (82) are ejected from burner orifices (40, 38, 36 and 34) to produce the flame. The atomized liquid precursor thus discharged is fed into the flame (72) produced at the face of the burner assembly where the atomized liquid precursor reacts with the flame to form soot (78) on a rotating mandrel (80).
Abstract:
A dispersion compensating single mode optical waveguide fiber designed to change the wavelength window of operation of a link from 1301 nm to 1550 nm. The dispersion compensating waveguide fiber is characterized by a core glass region refractive index profile comprised of at least three segments (2, 4, 6, 8). The segment (2) on the waveguide center has a positive relative refractive index. At least one segment (4, 8), spaced apart from the waveguide centerline has a negative relative refractive index.
Abstract:
The present invention is directed to a method for making silica glass and silica glass preforms. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO2 is provided and introduced directly into the flame of a combustion burner, which converts the compound to silica, thereby forming finely divided amorphous soot. The soot is vaporized proximate the site where the liquid is converted into silica glass by atomizing the liquid, preferably with a stream of atomizing gas. A heater proximate the burner face and around the burner flame increases soot capture rate and allows for a reduction of the velocity of the atomizing gas. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass.
Abstract:
The present invention is directed to a method for making fused silica glass. A liquid, preferably halide-free, silicon-containing compound capable of being converted by thermal oxidative decomposition to SiO2 is provided and introduced directly into the flame of a combustion burner, thereby forming finely divided amorphous soot. The amorphous soot is deposited on a receptor surface where, either substantially simultaneously with or subsequently to its deposition, the soot is consolidated into a body of fused silica glass. The invention further relates to an apparatus for forming fused silica from liquid, preferably halide-free, silicon-containing reactants which includes: a combustion burner which, in operation, generates a flame; an injector for supplying a liquid silicon-containing compound to the flame to convert the compound by thermal oxidative decomposition to a finely divided amorphous soot; and a receptor surface on which the soot is deposited.
Abstract:
A high-silica glass sheet has an average thickness of less than 150 microns and an average surface roughness over one or both of its two major surfaces of less than 1 nm. The glass sheet is formed using a roll-to-roll glass soot deposition and sintering process. The glass sheet may comprise a plurality of substantially parallel surface protrusions, which are visible only when a major surface of the glass sheet is viewed at an angle sufficiently removed from normal incidence.
Abstract:
The invention is directed to glass articles having improved resistance to edge fracture resulting from armoring the edges using metallic material adhesively bonded to the edges of the glass article. In one embodiment the metallic edge material is machinable to enable final finish of the part to specification tolerances. One of a plurality of layers of the metallic material can be adhesively applied to edge. The glass articles have a selected length, selected width and selected thickness, and the metallic/adhesive edge protecting composite is applied to less than or equal to the thickness of the glass such that the protecting composite does not contact the surfaces of the glass.
Abstract:
An image mask assembly for photolithography. The image mask assembly includes an image mask, a synthetic fused silica pellicle for protecting the image mask, and a frame holding the image mask and pellicle. The image mask includes a synthetic fused silica sheet comprising at least one layer and having a pattern written on a surface of the fused silica sheet. Methods of making the image mask and synthetic fused silica pellicle are also provided.
Abstract:
A method and apparatus for forming a hermetic seal between two substrates (101, 201) includes providing an electromagnetic absorbent sealing material (102) perimetrically about a surface of one of the substrates. Furthermore, the illustrative method includes heating the sealing material. In addition, a package (200) having a hermtic seal and apparati for disposing a sealing material are described.