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    OPTICAL GLASS FIBER COATING COMPOSITION
    31.
    发明申请
    OPTICAL GLASS FIBER COATING COMPOSITION 审中-公开
    光学玻璃纤维涂料组合物

    公开(公告)号：WO1996011965A1

    公开(公告)日：1996-04-25

    申请号：PCT/NL1995000351

    申请日：1995-10-13

    Applicant: DSM N.V. ,  TAKASE, Hideaki ,  SUWA, Mitsuhito ,  KOMIYA, Zen ,  UKACHI, Takachi

    Inventor： DSM N.V.

    IPC: C08G18/67

    CPC classification number: C09D175/16 ,  C03C25/106 ,  C08F290/067 ,  C08G18/10 ,  C08G18/672 ,  C08G18/289 ,  C08G18/48

    Abstract: Provided is an optical glass fiber coating composition which when coated on an optical glass fiber and suitably cured provides a coating having the combination of properties (i) through (iv): (i) a stable tensile modulus that is low at room temperature and over a broad range of temperatures below room temperature, (ii) an adhesion to the optical glass fiber sufficient to prevent structural defects and microbending in the optical glass fiber, (iii) the capability of being removed by stripping from the optical glass fiber substantially no residue left on the optical glass fiber, and (iv) which satisfies each of the following inequalities (I) and (II), X (I), X/Y >/= 1/10 (II), wherein X is the tensile modulus (kg/mm ) measured at 23 DEG C and Y is the tensile modulus (kg/mm ) measured at -40 DEG C. This coating composition comprises: (A) a urethane (meth)acrylate formed from, (a) a diol compound containing at least one structure represented by one of the formulae (1): -CH2-CH20- and (2), (b) a compound containing two isocyanate groups, and (c) a compound containing a (meth)acrylate group and a hydroxy group; (B) a second (meth)acrylate-containing compound of which the homopolymer has a glass transition temperature of at most about 0 DEG C; and (C) a polymerization initiator.

    Abstract translation: 提供了一种光学玻璃纤维涂料组合物，其在光学玻璃纤维上涂覆并适当固化时提供了具有性能（i）至（iv）的组合的涂层：（i）在室温和过高时稳定的拉伸模量 宽范围的温度低于室温，（ii）对光学玻璃纤维的粘附足以防止光学玻璃纤维中的结构缺陷和微弯曲，（iii）通过从光学玻璃纤维剥离而被除去的能力基本上不含残留物 留在光学玻璃纤维上，和（iv）满足以下不等式（I）和（II）中的每一个，X <= 0.2kg / mm 2（I），X / Y> / = 1/10 （II），其中X是在23℃下测量的拉伸模量（kg / mm 2），Y是在-40℃下测得的拉伸模量（kg / mm 2）。该涂料组合物包含： A）由（a）含有至少一种由式（1）之一表示的结构的二醇化合物形成的氨基甲酸酯（甲基）丙烯酸酯， ：-CH 2 -CH 2 O-和（2），（b）含有两个异氰酸酯基的化合物，和（c）含有（甲基）丙烯酸酯基和羟基的化合物; （B）第二（甲基）丙烯酸酯化合物，其均聚物的玻璃化转变温度为至多约0℃; 和（C）聚合引发剂。

    PROCESS FOR THE MANUFACTURE OF BENZALDEHYDE
    32.
    发明申请
    PROCESS FOR THE MANUFACTURE OF BENZALDEHYDE 审中-公开
    苯甲醛制造工艺

    公开(公告)号：WO1995020560A1

    公开(公告)日：1995-08-03

    申请号：PCT/NL1994000020

    申请日：1994-01-27

    Applicant: DSM N.V. ,  ROZIE, Hendricus, Johannes ,  DSINTER, Maria, Louisa, Christina ,  DAKKA, Jihad, Baka ,  ZORAN, Amikam ,  SASSON, Yoel

    Inventor： DSM N.V.

    IPC: C07C45/36

    CPC classification number: C07C45/36 ,  C07C47/54

    Abstract: The invention relates to a process for the oxidation of toluene in a liquid phase using an oxygen containing gas at a temperature between 120-200 DEG C and a pressure between 2-50 atm in the presence of a catalyst comprising cobalt or manganese as a metal ion further comprising bromide, wherein the amount of metal ion is between 0.2 and 5 wt % with respect to the reaction mixture; the molar ratio of bromide: metal ion is between 0.05 and 4; and whereby the reaction mixture further comprises an organic onium compound in a molar ratio with respect to the metal ion of 0.1 to 4, which compound is able to solubilize the metal ion-bromide complex, whereby the oxidation is carried out in such a way that at least 15 wt % of the converted toluene is benzaldehyde by limitation of the conversion of toluene, whereafter the reaction mixture is subjected to a separation step to separate toluene and benzaldehyde, the toluene being recycled to the reaction mixture.

    Abstract translation: 本发明涉及一种在包含钴或锰作为金属的催化剂存在下，使用含氧气体在120-200℃和2-50atm之间的温度下在液相中氧化甲苯的方法 离子还包含溴化物，其中相对于反应混合物，金属离子的量为0.2至5重量％; 溴化物：金属离子的摩尔比为0.05〜4; 并且其中所述反应混合物还包含相对于所述金属离子的摩尔比为0.1至4的有机鎓化合物，所述化合物能够溶解所述金属离子 - 溴化物络合物，由此所述氧化以如下方式进行： 通过限制甲苯的转化，至少15wt％的转化甲苯是苯甲醛，然后将反应混合物进行分离步骤以分离甲苯和苯甲醛，将甲苯再循环到反应混合物中。

    PROCESS FOR THE PREPARATION OF AN ALDEHYDE
    33.
    发明申请
    PROCESS FOR THE PREPARATION OF AN ALDEHYDE 审中-公开
    制备ALDEHYDE的方法

    公开(公告)号：WO1995019331A2

    公开(公告)日：1995-07-20

    申请号：PCT/NL1995000008

    申请日：1995-01-05

    Applicant: DSM N.V. ,  GELLING, Onko, Jan ,  TOTH, Imre

    Inventor： DSM N.V.

    IPC: C07C00/00

    CPC classification number: C07C255/17 ,  C07C51/373 ,  C07C67/347 ,  C07C59/147 ,  C07C69/716

    Abstract: The invention relates to a process for preparing an aldehyde starting from an unsaturated compound by means of hydroformylation in the presence of hydrogen, carbon monoxide, platinum and a bidentate ligand, the hydroformylation being effected in an aqueous medium and the bidentate ligand being a water-soluble compound. The invention also relates to a process for preparing an aldehyde, in which the following steps are carried out: a) preparation of the aldehyde in a reaction zone using a process as described above, b) isolation of the aldehyde from the aqueous mixture leaving the reaction zone by extraction, c) recycle of the aqueous mixture of step b) to the reaction zone.

    Abstract translation: 本发明涉及一种通过在氢气，一氧化碳，铂和二齿配位体的存在下通过加氢甲酰化从不饱和化合物制备醛的方法，加氢甲酰化在水性介质中进行，二齿配位体是水 - 可溶性化合物。 本发明还涉及一种制备醛的方法，其中进行以下步骤：a）使用上述方法在反应区中制备醛，b）从含水混合物中分离出醛， 反应区域，c）将步骤b）的水性混合物再循环到反应区域。

    PHENYLSERINE AMIDES AND THE PREPARATION OF PHENYLSERINES/PHENYLSERINE AMIDES
    34.
    发明申请
    PHENYLSERINE AMIDES AND THE PREPARATION OF PHENYLSERINES/PHENYLSERINE AMIDES 审中-公开
    苯丙氨酸和苯丙氨酸/苯乙烯胺的制备

    公开(公告)号：WO1995016786A1

    公开(公告)日：1995-06-22

    申请号：PCT/NL1994000320

    申请日：1994-12-16

    Applicant: DSM N.V. ,  KAPTEIN, Bernardus

    Inventor： DSM N.V.

    IPC: C12P41/00

    CPC classification number: C12P41/006 ,  C07C315/04 ,  C07C317/48 ,  C07C319/20 ,  C07C323/41 ,  C07C323/63 ,  C12P13/04

    Abstract: Process for the preparation of a threo-phenylserine amide of general formula (2) in which glycine amide is contacted with the corresponding substituted benzaldehyde of formula (3) in an excess relative to the amount of glycine amide, this taking place at a pH between 9 and 14 in the presence of a suitable solvent. The resulting phenylserine amide can subsequently be hydrolyzed to a phenylserine amide of general formula (1), which is subsequently hydrolyzed to a phenylserine amide of general formula (1), which is subsequently subjected to a stereoselective enzymatic hydrolysis yielding a (2S,3R)-phenylserine. The non-hydrolyzed (2R,3S)-phenylserine amide can be isolated as a Schiff base and be recirculated and simply racemized. The (2S,3R)-phenylserine obtained can be used in the preparation of thiamphenicol or phlorophenicol. The threo-phenylserine amides of general formula (1) or (2) are new intermediates in this commercially attractive process for the preparation of thiamphenicol and phlorophenicol.

    Abstract translation: 制备通式（2）的苏氨基苯基丝氨酰胺的方法，其中甘氨酰胺与相应的式（3）取代的苯甲醛相对于甘氨酸酰胺的量以过量的速率接触，这发生在 9和14在合适的溶剂存在下进行。 随后将所得苯基丝氨酰胺水解成通式（1）的苯基丝氨酰胺，随后将其水解成通式（1）的苯基丝氨酰胺，随后将其进行立体选择性酶水解，得到（2S，3R） -phenylserine。 非水解的（2R，3S） - 苯基丝氨酰胺可以作为希夫碱分离并进行再循环并简单地外消旋化。 获得的（2S，3R） - 苯基丝氨酸可用于制备甲砜霉素或间苯二酚。 通式（1）或（2）的苏氨基苯基丝氨酸酰胺是制备甲砜霉素和间苯二酚的商业上有吸引力的方法的新中间体。

    PROCESS FOR THE ENZYMATIC PREPARATION OF OPTICALLY ACTIVE N-SUBSTITUTED-3-PYRROLIDINOL
    35.
    发明申请
    PROCESS FOR THE ENZYMATIC PREPARATION OF OPTICALLY ACTIVE N-SUBSTITUTED-3-PYRROLIDINOL 审中-公开
    光学活性N-取代-3-吡咯烷醇的制备方法

    公开(公告)号：WO1995003421A1

    公开(公告)日：1995-02-02

    申请号：PCT/NL1994000162

    申请日：1994-07-13

    Applicant: DSM N.V. ,  VAN TILBURG, Adrianus, Franciscus, Peter ,  VAN DOOREN, Theodorus, Johannes, Godfried, Maria ,  SCHEPERS, Catharina, Hubertina, Maria ,  DASSEN, Bernardus, Hendrik, Nicolaas ,  BROXTERMAN, Quirinus, Bernardus

    Inventor： DSM N.V.

    IPC: C12P41/00

    CPC classification number: C12P41/004 ,  C07D207/12 ,  C12P17/10

    Abstract: The invention relates to a process for the preparation of optically active N-substituted-3-pyrrolidinol of general formula (1), wherein R represents a linear, cyclic or branched alkyl, alkenyl, aryl, alkaryl or aralkyl group, optionally substituted with one or more halogen atoms, or wherein R = OR , wherein R may have the same meaning as stated above for R, via enantioselective enzymatic hydrolysis of a corresponding N-substituted-3-acyloxypyrrolidine of general formula (2), wherein R represents an acid residue, for instance a linear, cyclic or branched alkyl, alkenyl, aryl-aralkyl or aralkyl group, optionally substituted with one or more halogen atoms and for the preparation of an optically active N-substituted-3-acyloxypyrrolidine compound, wherein a mixture of the corresponding N-substituted-3-pyrrolidinol is subjected to an enzymatic enantioselective esterification by means of an enzyme with ester hydrolase activity.

    Abstract translation: 本发明涉及制备通式（1）的光学活性N-取代-3-吡咯烷醇的方法，其中R代表直链，环状或支链烷基，烯基，芳基，烷芳基或芳烷基，任选被一个 或更多的卤素原子，或其中R = OR 2，其中R 2可以具有与上述R相同的含义，通过相应的通式（2）的N-取代-3-酰氧基吡咯烷的对映选择性酶水解， 其中R 1表示酸残基，例如任选被一个或多个卤素原子取代的直链，环状或支链烷基，链烯基，芳基 - 芳烷基或芳烷基，并用于制备光学活性N-取代 - 3-酰氧基吡咯烷化合物，其中相应的N-取代-3-吡咯烷醇的混合物通过具有酯水解酶活性的酶进行酶学对映选择性酯化。

    PROCESS FOR THE ENZYMATIC PREPARATION OF A BETA-LACTAM DERIVATIVE
    36.
    发明申请
    PROCESS FOR THE ENZYMATIC PREPARATION OF A BETA-LACTAM DERIVATIVE 审中-公开
    用于制备BETA-LACTAM衍生物的方法

    公开(公告)号：WO1995003420A1

    公开(公告)日：1995-02-02

    申请号：PCT/NL1994000161

    申请日：1994-07-13

    Applicant: DSM N.V. ,  BOESTEN, Wilhelmus, Hubertus, Joseph ,  MOODY, Harold, Monro

    Inventor： DSM N.V.

    IPC: C12P35/04

    CPC classification number: C07C231/20 ,  C12P17/10 ,  C12P35/04 ,  C12P37/04

    Abstract: Process for the preparation of a beta -lactam derivative, wherein in an enzymatic reaction a beta -lactam nucleus is coupled to D-phenylglycine amide, and the enzyme, the solid phenylglycine and the beta -lactam derivative are separated out, wherein the mixture obtained after the enzymatic reaction, from which mixture at least the enzyme and the solid D-phenylglycine have been removed, is treated with a suitable aldehyde at a pH between 7.5 and 8.5, whereby the Schiff base of D-phenylglycine amide is formed, and the Schiff base of D-phenylglycine amide is separated out. The treatment with a suitable aldehyde preferably takes place before the beta -lactam derivative is separated out.

    Abstract translation: 制备β-内酰胺衍生物的方法，其中在酶促反应中将β-内酰胺核偶联至D-苯基甘氨酸酰胺，并分离出酶，固体苯基甘氨酸和β-内酰胺衍生物，其中获得的混合物 在酶反应之后，至少将酶和固体D-苯基甘氨酸从其中除去的混合物用合适的醛在7.5至8.5之间的pH下处理，由此形成D-苯基甘氨酸酰胺的席夫碱， 分离出D-苯基甘氨酸酰胺的席夫碱。 优选在分离β-内酰胺衍生物之前进行用合适的醛的处理。

    PROCESS FOR THE PREPARATION OF LOW MOLECULAR WEIGHT COPOLYMERS OF ETHYLENE WITH AT LEAST ONE OTHER 1-ALKENE
    37.
    发明申请
    PROCESS FOR THE PREPARATION OF LOW MOLECULAR WEIGHT COPOLYMERS OF ETHYLENE WITH AT LEAST ONE OTHER 1-ALKENE 审中-公开
    用于制备乙烯的低分子量重量共聚物与至少一种其他1-碱的方法

    公开(公告)号：WO1995000564A1

    公开(公告)日：1995-01-05

    申请号：PCT/NL1994000122

    申请日：1994-05-30

    Applicant: DSM N.V.

    Inventor： DSM N.V. ,  HALL, James, R.

    IPC: C08F210/16

    CPC classification number: C08F10/00 ,  C08F210/16 ,  C08F210/18 ,  C08F4/68 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/03 ,  C08F236/20

    Abstract: A copolymer having an RSV less than 0.6 and a process for its preparation in which ethylene, at least one other 1-alkene and, optionally, an aliphatic or alicyclic polyunsaturated monomer are polymerized in the presence of a catalyst system containing (1) a compound of vanadium, (2) at least one organometal compound, (3) an alpha -halo, ketoaromatic promoter and (4) a chain transfer agent in which the molar ratio of alkyl groups of the alkyl aluminum halide to halogen atoms is at least 1.5.

    Abstract translation: 具有RSV小于0.6的共聚物及其制备方法，其中乙烯，至少一种其它1-烯烃和任选的脂族或脂环族多不饱和单体在催化剂体系存在下聚合，所述催化剂体系含有（1）化合物 的钒，（2）至少一种有机金属化合物，（3）α-卤代酮类促进剂和（4）烷基铝卤化物与卤素原子的烷基摩尔比至少为1.5的链转移剂 。

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