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公开(公告)号:FI913389A0
公开(公告)日:1991-07-12
申请号:FI913389
申请日:1991-07-12
Applicant: HOECHST AG
Inventor: ERDELEN CHRISTIAN , RINGSDORF HELMUT , PRASS WERNER , SCHEUNEMANN UDE
IPC: G03F20060101 , G03F
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公开(公告)号:FI906007A
公开(公告)日:1991-06-10
申请号:FI906007
申请日:1990-12-05
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B32B9/00 , C07D213/30 , C07D213/38 , C07D213/77 , G02F1/361 , B32B
Abstract: A sandwich element useable for NLO purposes can be manufactured by the Langmuir-Blodgett technique. The sandwich element comprises a solid base supporting at least two thin films of regular structure which contain at least one amphiphilic compound of the general formula (I) where R is H(CH2)n , H(CH2)n or R and R are independently of one another H, H(CH2)p , H(CH2)p or X is a single bond, -CH=CH-, -N=N-, -CH=N-NH- or -CH=N, Y is a divalent radical O, NH or S, R is -H, -CO-(CH2)t , (CH2)t or YR is -COO , -CONH2, H, OH, SO2(CH2)u , -CO2(CH2)t or -CO2(CH2vOH), Z is at least partly a polyanion, l is 1-10, n is 10-25, m is 0-25, p is 10-25, q is 10-25, r is 0-25, t is 0-25, u is 1-20 and v is 2-10.
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公开(公告)号:FI906007A0
公开(公告)日:1990-12-05
申请号:FI906007
申请日:1990-12-05
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B32B9/00 , C07D213/30 , C07D213/38 , C07D213/77 , G02F1/361 , B32B
Abstract: A sandwich element useable for NLO purposes can be manufactured by the Langmuir-Blodgett technique. The sandwich element comprises a solid base supporting at least two thin films of regular structure which contain at least one amphiphilic compound of the general formula (I) where R is H(CH2)n , H(CH2)n or R and R are independently of one another H, H(CH2)p , H(CH2)p or X is a single bond, -CH=CH-, -N=N-, -CH=N-NH- or -CH=N, Y is a divalent radical O, NH or S, R is -H, -CO-(CH2)t , (CH2)t or YR is -COO , -CONH2, H, OH, SO2(CH2)u , -CO2(CH2)t or -CO2(CH2vOH), Z is at least partly a polyanion, l is 1-10, n is 10-25, m is 0-25, p is 10-25, q is 10-25, r is 0-25, t is 0-25, u is 1-20 and v is 2-10.
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34.
公开(公告)号:CA2014359A1
公开(公告)日:1990-10-12
申请号:CA2014359
申请日:1990-04-11
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: G02B1/04 , B05D1/20 , B32B27/30 , C07C67/08 , C07C69/54 , C07C69/708 , C07C231/02 , C07C233/05 , C07C233/18 , C07C233/20 , C07C235/06 , C08F20/26 , C08F20/28 , C08F20/54 , C08F120/28 , C08F120/68 , C08F120/70 , C08L33/04 , C08L33/24 , C09D133/04 , H01B3/18 , C07C255/27 , C07C235/74
Abstract: HOE 89/F 117 Amphiphilic monomers and polymers and film comprising at least one unimolecular layer thereof Amphiphilic monomers having mixed-chain structures of the general formulae (I) or (II) (I) (II) where Y is -O- or -NH-, X is a group of the formula -(CH2)n- or -(CH2-O-CH2)n-, l is an integer from 0 to 10, m is an integer from 10 to 26, n is an integer from 1 to 10, R1 is hydrogen, methyl, chlorine, cyano, fluorine or bromine, and R2 is O-alkyl or NH-alkyl, are polymerized alone or together with other comonomers. The polymers obtained are suitable for preparing ultrathin films on a suitable base material.
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公开(公告)号:DK655589A
公开(公告)日:1990-06-23
申请号:DK655589
申请日:1989-12-21
Applicant: HOECHST AG
Inventor: LUPO DONALD , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B32B27/30 , C07C233/05 , C07C233/80 , C08F20/34 , C08F20/36 , C08F20/52 , C08F20/60 , C08J5/18 , C07C235/74 , B32B27/06
Abstract: Amphiphilic monomers with mixed-chain structures of the formula in which Y denotes -O- or -NH- X denotes a group of the formula -(CH2)n- or -(CH2-O-CH2)n- l denotes an integer from 0 to 10, n denotes an integer from 1 to 10, R1 denotes hydrogen, methyl, chlorine, cyano, fluorine or bromine, R2 denotes C1-C24-alkyl or C1-C24-fluoroalkyl and R3 denotes C8-C24-alkyl or C8-C24-fluoralkyl, with the proviso that the groups R2 and R3 contain a different number of carbon atoms. The monomers are polymerized on their own or together with other comonomers. The polymers obtained are suitable for the preparation of ultra-thin layers on a suitable layer support.
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公开(公告)号:FI894182A
公开(公告)日:1990-03-08
申请号:FI894182
申请日:1989-09-05
Applicant: HOECHST AG
Inventor: CHERDRON HARALD , PRASS WERNER , SCHEUNEMANN UDE , LUPO DONALD
Abstract: Polyamides of the general formula [N(A)-X-N(B)-CO-Y-CO-]n are described, in which Y denotes a divalent group, X a divalent radical whose chain contains at least two carbon atoms, A and B independently of one another denote H or a C1 to C26 alkyl group and n denotes an integer greater than 4. The said polyamides contain at least one alkyl group of C6 to C26 per repeating unit. The groups X and/or Y contain at leat one CH2 group in the chain. The polyamides are prepared by reaction of a diamine of the formula NHA-X-NHB with an about equimolar amount of a reactive derivative of a dicarboxylic acid of the formula COOH-Y-COOH. The polyamides obtained can be used in order to prepare highly ordered monomolecular LB films on a support. For this purpose, the polyamide is dissolved in a volatile organic solvent which is immiscible with water and the solution is spread on the water/air interface. After evaporation of the solvent the layer is compressed and transferred to a solid support by the LB technique. The film is very stable and can be used to prepare optical waveguide systems, filters for optical purposes or protective layers.
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公开(公告)号:DE59502704D1
公开(公告)日:1998-08-06
申请号:DE59502704
申请日:1995-10-10
Applicant: HOECHST AG
Inventor: GEISS GERHARD , MUELLER HANS-KARL , PRASS WERNER , SCHEUNEMANN UDE , ZIMMERMANN ANDREAS
IPC: C08J3/12 , C01B33/14 , C01B33/145 , C01B33/16 , C04B14/06 , C04B20/00 , C04B30/02 , C04B38/08 , C08J3/20 , C08K3/36 , C08L101/00 , C09J1/00 , C09J11/04
Abstract: PCT No. PCT/EP95/03989 Sec. 371 Date Apr. 17, 1997 Sec. 102(e) Date Apr. 17, 1997 PCT Filed Oct. 10, 1995 PCT Pub. No. WO96/12683 PCT Pub. Date May 2, 1996The invention relates to a composition comprising between 30 and 95% by volume of aerogel particles and at least one aqueous binder, where the particle diameter of the aerogel particles is less than 0.5 mm and the aerogel particles preferably have hydrophobic surface groups, a process for the preparation thereof, and the use thereof.
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公开(公告)号:NO971792D0
公开(公告)日:1997-04-18
申请号:NO971792
申请日:1997-04-18
Applicant: HOECHST AG
Inventor: GEISS GERHARD , MUELLER HANS-KARL , PRASS WERNER , SCHEUNEMANN UDE , ZIMMERMANN ANDREAS
IPC: C01B33/14 , C01B33/145 , C01B33/16 , C04B14/06 , C08J3/12 , C04B20/00 , C04B30/02 , C04B38/08 , C08J3/20 , C08K3/36 , C08L101/00 , C09J1/00 , C09J11/04 , C04B14/04
Abstract: PCT No. PCT/EP95/03989 Sec. 371 Date Apr. 17, 1997 Sec. 102(e) Date Apr. 17, 1997 PCT Filed Oct. 10, 1995 PCT Pub. No. WO96/12683 PCT Pub. Date May 2, 1996The invention relates to a composition comprising between 30 and 95% by volume of aerogel particles and at least one aqueous binder, where the particle diameter of the aerogel particles is less than 0.5 mm and the aerogel particles preferably have hydrophobic surface groups, a process for the preparation thereof, and the use thereof.
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公开(公告)号:DE59008610D1
公开(公告)日:1995-04-06
申请号:DE59008610
申请日:1990-11-26
Applicant: HOECHST AG
Inventor: HAUBS MICHAEL , PRASS WERNER
Abstract: PCT No. PCT/EP90/02021 Sec. 371 Date Jul. 2, 1992 Sec. 102(e) Date Jul. 2, 1992 PCT Filed Nov. 26, 1990 PCT Pub. No. WO91/09669 PCT Pub. Date Jul. 11, 1991.Composite membrane, process for its production and its use A composite membrane for gas separation having a three-layer structure, constructed from A) a supporting membrane layer made of porous polymer, B) a nonporous, gas-permeable intermediate layer, C) a permselective layer of regularly arranged organic molecules having a layer thickness of 3 to 100 nm, the layers (A) and (C) enclosing the intermediate layer (B), wherein the permselective layer (C) is constructed from regularly arranged amphiphilic molecules which contain one or two alkyl chains each having 7 to 25 carbon atoms per polar hydrophilic group.
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40.
公开(公告)号:CA2045130A1
公开(公告)日:1990-07-15
申请号:CA2045130
申请日:1990-01-12
Applicant: HOECHST AG
Inventor: ERDELEN CHRISTIAN , RINGSDORF HELMUT , PRASS WERNER , SCHEUNEMANN UDE
IPC: B05D1/20 , B05D3/06 , C08F12/00 , C08F16/02 , C08F16/16 , C08F20/32 , C08F20/52 , C08F212/08 , C08F216/04 , C08F216/16 , C08F220/32 , C08F220/58 , C08J5/18 , C08J7/00 , C08L33/16 , G03F7/038 , G03F7/095
Abstract: - 18 - HOE 89/F 010 of the disclosure Radiation-sensitive film composed of at least one monomolecular layer of fluorine-containing amphiphiles If a vinyl monomer containing fluoroalkyl side groups is copolymerized with a vinyl monomer containing oxirane groups, an amphiphilic polymer is obtained. To prepare a sandwich, a polymer is dissolved in a volatile organic solvent which is immiscible with water, the solution is spread on the water/air boundary surface, the resultant layer is compressed after the solvent has evaporated and transferred to a solid layer support by the LangmuirBlodgett technique. The oxirane rings are cleaved and the film crosslinked by the action of high-energy radiation on the film.
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