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公开(公告)号：JPS6339955A
公开(公告)日：1988-02-20
申请号：JP18188286
申请日：1986-08-04
Applicant: TORAY INDUSTRIES
Inventor： KARASAWA HIROO , OKITA KIYOMI , YONETANI KIICHI
IPC: C08K3/18 , C08G59/00 , C08G59/18 , C08K3/22 , C08K5/15 , C08K5/1515 , C08K5/34 , C08K5/3492 , C08K5/59 , C08L63/00 , C08L67/00 , C08L67/02
Abstract: PURPOSE:To provide the title compsn. which has excellent flame retardance, mechanical properties, heat resistance and stability in residence during molding and hardly emits gas, by blending an arom. polyester with a specified compd. a low-molecular halogenated epoxy compd. and an antimony compd. CONSTITUTION:A cyanuric ester compd. (B) of a halogenated bisphenol of formula I [wherein Ar , Ar , Ar and Ar are each a [halogen- or (halogenated) lower alkyl-substd.] monomvalent arom. group; Ar is a [(halogenated) lower alkyl-substed.] halogen-substd. bivalent arom. group; and n is a degree of polmn.], obtd. by reacting a cyanuric halide with a halogenated bisphenol, is mixed with a halogenated epoxy compd. (B) of formula II or III [wherein X is halogen; Y is a member selected from the group consisting of a (halogenated) lower alkylene, -SO2, etc.; u and v are each 1-4; n' is 0-10; n'' is 1-10; and Ar is Ar ] in a weight ratio of 95-10/5-90 to obtain a mixture. 100 pts.wt. arom. polyester (A) is blended with 2-50 pts.wt. said mixture and 1-50 pts.wt. antimony compd. (D).
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公开(公告)号：JPS6315841A
公开(公告)日：1988-01-22
申请号：JP16018086
申请日：1986-07-08
Applicant: TORAY INDUSTRIES
Inventor： YONETANI KIICHI , KARASAWA HIROO , NAKAMURA SEIICHI
Abstract: PURPOSE:To obtain the title resin compsn. having excellent molding characteristic, etc., and providing moldings having excellent appearance, heat resistance and shock resistance, and being useful for an automobile outer ply material, comprising a specific polyphenylene ether and a copolyester prepd. by copolymerizing an arom. polyester with a vinyl polymer. CONSTITUTION:5-95wt% polyphenylene ether having a repeating unit represented by the formula (wherein R1-4 are H, halogen, (substd.) hydrocarbon group, CN, alkoxy, phenoxy, NO2) and whose intrinsic viscosity is 0.10-0.80dl/g (chloroform at 25 deg.C) is blended with 95-5wt% copolyester whose reduced viscosity is 0.8-2.5dl/g (o-chlorophenol, at 25 deg.C) prepd. by copolymerizing an arom. polyester with 3-60wt% vinyl polymer comprising one or more members selected from among an arom. vinyl monomer (e.g. (alpha-methyl)-styrene), a vinyl cyanide monomer (e.g. (meth)acrylonitrile) and alpha,beta-unsatd. acid ester monomer (e.g. methyl (meth)acrylate).
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公开(公告)号：JPS62127342A
公开(公告)日：1987-06-09
申请号：JP26537285
申请日：1985-11-26
Applicant: TORAY INDUSTRIES
Inventor： YONETANI KIICHI , KARASAWA HIROO , OKITA KIYOMI
Abstract: PURPOSE:To improve flame retardance and mechanical properties and to contemplate improvements in heat resistance and residence stability during molding, by blending an arom. polyester with a brominated polycarbonate oligomer whose terminal is blocked with a specified substituent and an antimony compd. CONSTITUTION:100pts.wt. arom. polyester is blended with 1-50pts.wt. brominated polycarbonate oligomer of formula I and 1-50pts.wt. antimony compd. In the formula I, X is a 1-10C hydrocarbon group, carbonyl, ether, -S- or -SO2-; l and m are each an integer of 1-4; n is an integer of 2-30; Ar and Ar' are each a substituent of formula II, III or IV; in the formulas II-IV, R1 and R2 are each a 1-6C alkyl, an alkoxy; R3-R5 are each H, a 1-6C alkyl, an alkoxy; Ar'' is a 6-10C aryl, an alkyl-substd. aryl.
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公开(公告)号：JP2002155196A
公开(公告)日：2002-05-28
申请号：JP2000356653
申请日：2000-11-22
Applicant: TORAY INDUSTRIES
Inventor： KOBAYASHI SADAYUKI , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition for over-sheet, excellent in surface appearance of a sheet during heat lamination, having high toughness so as not to crack during embossing, and used for multi-layered sheet which is used as a card for magnetic card, IC card, etc. SOLUTION: This thermoplastic resin composition is used as an over-sheet in a multilayered sheet formed by laminating sheets, and manufactured by adding at least an inorganic particle (A-3) selected from non-plate shaped inorganic particles to at least a thermoplastic resin selected from a noncrystalline polyester (A-1) and an aromatic polycarbonate (A-2).
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公开(公告)号：JP2002144500A
公开(公告)日：2002-05-21
申请号：JP2001249885
申请日：2001-08-21
Applicant: TORAY INDUSTRIES
Inventor： KOBAYASHI SADAYUKI , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a multilayer sheet having excellent embossing properties and high toughness, being excellent in thermal weldability on the occasion of heating lamination, showing little heat shrinkage and further being excellent also in the outward appearance of the surface, and a card such as a magnetic card or an IC card constituted of the sheet. SOLUTION: At least one layer of the multilayer sheet is a sheet A constituted of a vinyl-series (co) polymer and at least one of two surface layers is a sheet B constituted of one kind or more of thermoplastic resins selected out of an amorphous polyester and an aromatic polycarbonate. The card is constituted of the multilayer sheet.
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Patent Agency Ranking
公开(公告)号：JP2002096431A
公开(公告)日：2002-04-02
申请号：JP2001216510
申请日：2001-07-17
Applicant: TORAY INDUSTRIES
Inventor： KOBAYASHI SADAYUKI , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a multi-layer sheet having good emboss processing property, character marking and surface appearance and used for cards such as a magnetic card, and a card made of the same. SOLUTION: The multi-layer sheet comprises laminated three or more sheets including at least two or more sheets consisting of a thermoplastic resin and an inorganic plate-like filler, wherein its laminate form has a concentration distribution of the inorganic plate-like filler in a thickness direction of satisfying a specific relationship, and an average inorganic filler concentration in the multi-layer sheet in total of 3 wt.% or higher.
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公开(公告)号：JP2002001891A
公开(公告)日：2002-01-08
申请号：JP2001105612
申请日：2001-04-04
Applicant: TORAY INDUSTRIES
Inventor： KOBAYASHI SADAYUKI , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a multilayered polyester sheet used in a card such as a magnetic card or an IC card excellent not only in embossing processability but also in heat resistance and impact resistance, and the card comprising the same. SOLUTION: The multilayered polyester sheet is formed by laminating two or more sheets. At least one layer thereof is a sheet A comprising a thermoplastic resin composition prepared by compounding (a) amorphous polyester and (b) aromatic polycarbonate so that a weight ratio (a)/(b) becomes 10/90-80/20, and at least one layer thereof is a sheet B comprising a thermoplastic resin composition prepared by compounding 2-25 pts.wt. of (c) an inorganic lamellar filler with 100 pts.wt. of a thermoplastic resin component. A weight ratio (a)/(b) of (a) amorphous polyester and (b) aromatic polycarbonate is 85/15-100/0.
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公开(公告)号：JPH10130492A
公开(公告)日：1998-05-19
申请号：JP28772296
申请日：1996-10-30
Applicant: TORAY INDUSTRIES
Inventor： SUGIMURA MASAHIRO , TACHIBANA YASUHITO , KARASAWA HIROO
Abstract: PROBLEM TO BE SOLVED: To provide a polyamide resin compsn. excellent in tensile strength, low warp properties, surface appearance of a molding, and creep characteristics and a process for producing the same. SOLUTION: This compsn. is prepd. by polymerizing a polyamide-forming monomer contg. an inorg. solid which has been dispersed therein, is other than silicon oxide, and satisfies the condition (a) that the concn. of an acid point at which the Hammett's H0 parameter is in the range defined by the formula: +1.5>=H0 >-12 is in the range of 0.05-0.9 milliequivalent per g or the condition (b) that the concn. of a base point at which the Hammett's H- parameter is in the range defined by the formula: +33>=H- >=+9. 3 is in the range of 0.01-0.5 miliequivalent per g or by polymerizing a polyamide-forming monomer contg. silicone oxide which has been dispersed therein and satisfies the condition (c) that the concn. of an acid point at which the Hammett's H0 parameter is in the range defined by the formula: +4>=H0 >+2 is in the range of 0.05-0.2 miliequivalent per g.
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公开(公告)号：JPH0562902B2
公开(公告)日：1993-09-09
申请号：JP22836186
申请日：1986-09-29
Applicant: TORAY INDUSTRIES
Inventor： YONETANI KIICHI , KARASAWA HIROO , OKITA KYOMI
IPC: C08L67/02 , C08G59/00 , C08G59/48 , C08G63/183 , C08G63/82 , C08G63/85 , C08K5/15 , C08K5/1515 , C08L63/00 , C08L67/00
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公开(公告)号：JPH05163351A
公开(公告)日：1993-06-29
申请号：JP33038091
申请日：1991-12-13
Applicant: TORAY INDUSTRIES
Inventor： MATSUOKA HIDEO , KARASAWA HIROO , KOBAYASHI KAZUHIKO
Abstract: PURPOSE:To provide a new polyarylene sulfide sulfone polymer of excellent heat resistance. CONSTITUTION:A polyarylene sulfide sulfone of a melt viscosity of 6.20-6.60, obtained by reacting an aromatic dihalosulfone with phenolphthalein, an alkali metal salt and a source of sulfur. An aromatic dihalosulfone is reacted with phenolphthalein in a molar ratio of 99/1-60/40 in the presence of an alkali metal hydroixde or an alkyl metal salt in an organic amide solvent and/or an organic sulfone solvent to form an oligomer having halogen atoms at both ends. Next at least one source of sulfur selected from among an alkali metal sulfide, an alkali metal hydrosulfide and hydrogen sulfide is added to the reaction system and reacted with the oligomer at 175-235 deg.C for 1-20hr. Thus, a resin having a particularly high glass transition temperature and excellent thermal decomposition resistance can be obtained. This process is industrially advantageous in that a polymer having a high glass transition temperature which can be varied can be obtained.
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