公开(公告)号：US5338861A

公开(公告)日：1994-08-16

申请号：US919818

申请日：1992-07-24

Applicant: Artur Botta ,  Hans-Josef Buysch ,  Otto Immel ,  Lothar Puppe

Inventor： Artur Botta ,  Hans-Josef Buysch ,  Otto Immel ,  Lothar Puppe

IPC: B01J21/04 ,  B01J23/20 ,  C07B61/00 ,  C07D201/02 ,  C07D207/267 ,  C07D211/76 ,  C07D213/64 ,  C07D215/22 ,  C07D223/10 ,  C07D201/04

CPC classification number: C07D201/02 ,  Y02P20/52

Abstract: Substituted lactams of the formula ##STR1## can be prepared from lactam N-carboxylates or lactim O-carboxylates of the formulae ##STR2## by thermal or mixed thermal and catalysed CO.sub.2 elimination at 80.degree.-450.degree. C. Lactams substituted on the N atom by aliphatic groups such as those produced herein are useful as industrial aprotic solvents.

Abstract translation: 式（I）的取代的内酰胺可以通过热或混合的热和催化的二氧化碳消除从制备式“IMAGE”（II）或（IMAGE）（III）的内酰胺N-羧酸盐或内酰胺酸O-羧酸盐制备。 80°-450℃。通过脂族基团（例如本文制备的那些）在N原子上取代的内酰胺可用作工业非质子溶剂。

公开(公告)号：US4111952A

公开(公告)日：1978-09-05

申请号：US745018

申请日：1976-11-26

Applicant: John F. Knifton

Inventor： John F. Knifton

IPC: C07D201/02 ,  C07D207/26

CPC classification number: C07D201/02

Abstract: This invention concerns processes for preparing cyclic, 5-membered ring, lactams through the carbonylation of allylic substrates in the presence of rhodium catalysts.

Abstract translation: 本发明涉及在铑催化剂存在下通过烯丙基底物的羰基化制备环状5元环，内酰胺的方法。

公开(公告)号：US3947406A

公开(公告)日：1976-03-30

申请号：US667061

申请日：1967-09-12

Applicant: Edwin George Edward Hawkins

Inventor： Edwin George Edward Hawkins

IPC: C07D201/02 ,  C07D211/76 ,  C07D273/00 ,  C07D53/06

CPC classification number: C07D201/02 ,  C07C255/00

Abstract: Compounds of formula ##EQU1## where X,X' are divalent aliphatic radicals which may be the same or different are heated to decompose them to lactams.

Abstract translation: 其中X，X'是可以相同或不同的二价脂族基团的式NH XC ANGLE ANGLE CX'OO的化合物被加热以将其分解成内酰胺。

公开(公告)号：US3836525A

公开(公告)日：1974-09-17

申请号：US7255170

申请日：1970-09-15

Applicant: UBE INDUSTRIES

Inventor： MASAKI M ,  UCHIDA M ,  ODA T ,  YAMAMOTO K

IPC: C07B45/02 ,  C07C303/32 ,  C07D201/02 ,  C07D201/14 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07B45/02 ,  C07C303/32 ,  C07D201/14

Abstract: A PROCESS FOR THE PREPARATION OF LACTAMS AND SULFONIC ACID DERIVATIVES OF ACTIVE HYDROGEN-CONTAINING ORGANIC COMPOUNDS OF THE GROUP CONSISTING OF OXIMES, ALCOHOLS, PHENOLS, THIOLS, PRIMARY AMINES AND SECONDARY AMINES, WHICH COMPRISES REACTING A LACTAM-O-SULFONIC ACID WITH A COMPOUND SELECTED FROM THE SPECIFIED ORGANIC COMPOUNDS UNDER SUBSTANTIALLY ANHYDROUS CONDITIONS.

公开(公告)号：US3654268A

公开(公告)日：1972-04-04

申请号：US3654268D

申请日：1968-12-09

Applicant: BP CHEM INT LTD

Inventor： HAWKINS EDWIN GEORGE EDWARD

IPC: C07D201/02 ,  C07D273/00 ,  C07D41/06

CPC classification number: C07D201/02 ,  C07D273/00

Abstract: CYCLOHEXANONE IS CONVERTED TO 1,1''-PEROXYDICYCLOHEXYLAMINE WHICH IS THEN HEATED IN THE LIQUID PHASE TO PRODUCE CAPROLACTAM AND CYCLOHEXANONE, WHICH CYCLOHEXAMONE IS RECYCLED AS FEED TO THE PROCESS.

公开(公告)号：US3590032A

公开(公告)日：1971-06-29

申请号：US3590032D

申请日：1968-10-07

Applicant: BP CHEM INT LTD

Inventor： HARRIS BRIAN WALTON

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: CAPROLACTAM IS PRODUCED BY HEATING TOGETHER 1,1''-PEROXYDICYCLOHEXYLAMINE AND A LITHIUM HALIDE IN A MOLTEN CAPROLACTAM ENVIRONMENT.

公开(公告)号：US3560484A

公开(公告)日：1971-02-02

申请号：US83417369

申请日：1969-06-17

Applicant: TEIJIN LTD

Inventor： TANAKA IKUZO ,  UEHARA HIDEO ,  OSAKI HUKUE ,  YAMAGATA MASAYUKI

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

Abstract: CAPROLACTAM IS PREPARED IN A SINGLE STEP WITHOUT FORMATION OF BY-PRODUCT AMMONIUM SULFATE BY CONTACTING 2-NITROCYCLOHEXANONE AND/OR 2-NITROCYCLOHEXEN-1-O1 WITH HYDROGEN AT A TEMPERATURE RANGING FROM 150* TO 300* C. IN THE PRESENCE OF A LIQUID MEDIUM SUCH AS WATER, ALCOHOLS, ETHERS, BENZENE OR MIXTURES THEREOF AND OF AN ACTIVE HYDROGENATION CATALYST, PERFERABLY IN THE FURTHER PRESENCE OF A NITROGEN-CONTAINING BASIC SUBSTANCE SUCH AS AMMONIA. THIS INVENTION RELATS TO A NOVEL PROCESS FOR THE PREPARATION OF E-CAPROLACTAM.

公开(公告)号：US3535311A

公开(公告)日：1970-10-20

申请号：US3535311D

申请日：1967-04-21

Applicant: UGINE KUHLMANN

Inventor： BESSON PAUL ,  NALLET ALBERT

IPC: C07D201/02 ,  C07D41/06

CPC classification number: C07D201/02

公开(公告)号：WO2008103366A3

公开(公告)日：2008-12-24

申请号：PCT/US2008002202

申请日：2008-02-20

Applicant: UNIV MICHIGAN STATE ,  FROST JOHN W

Inventor： FROST JOHN W

IPC: C07D201/00 ,  C07D201/02 ,  C07D201/08

CPC classification number: C07D201/00 ,  C07D201/02 ,  C07D201/08 ,  Y02P20/52

Abstract: Catalytic processes for preparing caprolactam, pipecolinic acid, and their derivatives, from lysine or alpha-amino-epsilon-caprolactam starting materials, and products produced thereby. A process for preparing caprolactam or a derivative thereof, the process comprising contacting a reactant comprising lysine or alpha aminocaprolactam with a catalyst and a gas comprising hydrogen gas, in the presence of a solvent. The catalyst may be provided on a support material, such as a transition metal.

Abstract translation: 从赖氨酸或α-氨基-ε-己内酰胺起始原料制备己内酰胺，哌可啶酸及其衍生物的催化方法，以及由此产生的产物。 一种制备己内酰胺或其衍生物的方法，该方法包括在溶剂存在下使包含赖氨酸或α-氨基己内酰胺的反应物与催化剂和包含氢气的气体接触。 催化剂可以设置在载体材料如过渡金属上。

公开(公告)号：WO00017168A1

公开(公告)日：2000-03-30

申请号：PCT/EP1999/006690

申请日：1999-09-10

IPC: C07D223/04 ,  C07B61/00 ,  C07D201/02 ,  C07D223/10 ,  C07D295/023 ,  C07D295/02

CPC classification number: C07D201/02 ,  C07D295/023

Abstract: The invention relates to a method for the joint production of a cyclic lactam and a cyclic amine by reacting an aliphatic alpha, omega diamine in the gas phase with water and in the presence of a heterogeneous catalyst.

Abstract translation: 一种用于环状内酰胺的制备联合并且通过在非均相催化剂的存在下在气相中的脂族α，ω-二胺与水反应的环状胺的过程。