Method for producing porous structures from synthetic polymers
    32.
    发明授权
    Method for producing porous structures from synthetic polymers 有权
    从合成聚合物制备多孔结构的方法

    公开(公告)号:US08999211B2

    公开(公告)日:2015-04-07

    申请号:US12867040

    申请日:2009-02-11

    Abstract: A process for producing porous structures from polyamide by dissolving the polyamide in an ionic liquid and precipitating or coagulating the dissolved polyamide by contacting the solution with a liquid precipitant medium. Fibers are produced from the dissolved polyamide in a wet-spinning process by precipitation in protic solvents, in particular water, a C1-4-alkanol or mixtures thereof, and subsequent freeze-drying. Foils, films or coatings are produced by blade coating the dissolved polyamide onto a substrate surface, optionally spraying with protic solvent, in particular water, a C1-4-alcohol or mixtures thereof, dipping into a precipitation or coagulation bath, freeze-drying of the resulting foil, of the film or of the coated substrate. Molded parts are prepared by extracting the dissolved polyamide with protic solvents, preferably water, a C1-4-alcohol or mixtures thereof, wherein the dissolved polymer is transformed to a solid or wax-like state by cooling and extracted after subsequent molding.

    Abstract translation: 通过将聚酰胺溶解在离子液体中并通过使溶液与液体沉淀剂介质接触使溶解的聚酰胺沉淀或凝结来从聚酰胺制造多孔结构的方法。 通过在质子溶剂,特别是水,C 1-4链烷醇或其混合物中沉淀,然后冷冻干燥,在湿纺丝方法中,由溶解的聚酰胺生产纤维。 通过将溶解的聚酰胺刮涂到基材表面上,任选地喷涂质子溶剂,特别是水,C1-4醇或其混合物,将其浸入沉淀或凝固浴中,冷冻干燥 所得到的箔,膜或涂覆的基底。 通过用质子溶剂,优选水,C 1-4醇或其混合物萃取溶解的聚酰胺来制备模制部件,其中通过冷却将溶解的聚合物转化为固体或蜡状状态,并在随后的模塑之后提取。

    Porous cross-linked polyimide-urea networks
    33.
    发明授权
    Porous cross-linked polyimide-urea networks 有权
    多孔交联聚酰亚胺 - 尿素网络

    公开(公告)号:US08974903B2

    公开(公告)日:2015-03-10

    申请号:US13804546

    申请日:2013-03-14

    Abstract: Porous cross-linked polyimide-urea networks are provided. The networks comprise a subunit comprising two anhydride end-capped polyamic acid oligomers in direct connection via a urea linkage. The oligomers (a) each comprise a repeating unit of a dianhydride and a diamine and a terminal anhydride group and (b) are formulated with 2 to 15 of the repeating units. The subunit was formed by reaction of the diamine and a diisocyanate to form a diamine-urea linkage-diamine group, followed by reaction of the diamine-urea linkage-diamine group with the dianhydride and the diamine to form the subunit. The subunit has been cross-linked via a cross-linking agent, comprising three or more amine groups, at a balanced stoichiometry of the amine groups to the terminal anhydride groups. The subunit has been chemically imidized to yield the porous cross-linked polyimide-urea network. Also provided are wet gels, aerogels, and thin films comprising the networks, and methods of making the networks.

    Abstract translation: 提供多孔交联聚酰亚胺 - 尿素网络。 网络包括通过尿素键直接连接的两个酸酐封端的聚酰胺酸低聚物的亚基。 低聚物(a)各自包含二酐和二胺和末端酐基团的重复单元,和(b)与2至15个重复单元配制。 通过二胺与二异氰酸酯的反应形成亚单元,形成二胺 - 脲键二胺基,二胺 - 脲键 - 二胺基与二酐和二胺反应形成亚单位。 亚基已经通过交联剂交联,所述交联剂包含三个或更多个胺基团,所述交联剂以胺基团与末端酐基团的平衡化学计量比。 该亚基已被化学酰亚胺化以产生多孔交联的聚酰亚胺 - 尿素网络。 还提供了湿凝胶,气凝胶和包含网络的薄膜以及制造网络的方法。

    Micro-particles containing a 3-D polymeric structure
    34.
    发明授权
    Micro-particles containing a 3-D polymeric structure 有权
    含有3-D聚合物结构的微粒子

    公开(公告)号:US08821931B2

    公开(公告)日:2014-09-02

    申请号:US12270452

    申请日:2008-11-13

    Abstract: Micro-sized particles having a polymeric structure of cells are provided. Also provided is a method of producing micro-sized particles having a polymeric structure comprising: (1) forming a homogenous solution by heating a mixture of a high molecular weight polymer and a low molecular weight material, wherein said low molecular weight material makes up at least about 50% by weight of the homogenous solution, (2) forming a dispersed solution by dispersing the homogenous solution formed in step (1) into an inert material, (3) cooling the dispersed solution to cause the high molecular weight polymer to phase separate from the low molecular weight material, (4) forming solid particles comprised of said low molecular weight material trapped inside a structure of cells of said high molecular weight polymer, and (5) removing the solid particles from the dispersed solution.

    Abstract translation: 提供具有电池聚合结构的微尺寸颗粒。 还提供了一种生产具有聚合物结构的微尺寸颗粒的方法,包括:(1)通过加热高分子量聚合物和低分子量材料的混合物形成均匀溶液,其中所述低分子量材料组成 至少约50重量%的均匀溶液,(2)通过将步骤(1)中形成的均匀溶液分散在惰性物质中形成分散溶液,(3)冷却分散溶液使高分子量聚合物相 与低分子量材料分离,(4)形成由所述低分子量材料构成的固体颗粒,所述低分子量材料被捕获在所述高分子量聚合物的细胞结构内,和(5)从分散溶液中除去固体颗粒。

    MICRO-PARTICLES CONTAINING A 3-D POLYMERIC STRUCTURE
    36.
    发明申请
    MICRO-PARTICLES CONTAINING A 3-D POLYMERIC STRUCTURE 有权
    含有三维聚合物结构的微粒

    公开(公告)号:US20090285894A1

    公开(公告)日:2009-11-19

    申请号:US12270452

    申请日:2008-11-13

    Abstract: Micro-sized particles having a polymeric structure of cells are provided. Also provided is a method of producing micro-sized particles having a polymeric structure comprising: (1) forming a homogenous solution by heating a mixture of a high molecular weight polymer and a low molecular weight material, wherein said low molecular weight material makes up at least about 50% by weight of the homogenous solution, (2) forming a dispersed solution by dispersing the homogenous solution formed in step (1) into an inert material, (3) cooling the dispersed solution to cause the high molecular weight polymer to phase separate from the low molecular weight material, (4) forming solid particles comprised of said low molecular weight material trapped inside a structure of cells of said high molecular weight polymer, and (5) removing the solid particles from the dispersed solution.

    Abstract translation: 提供具有电池聚合结构的微尺寸颗粒。 还提供了一种生产具有聚合物结构的微尺寸颗粒的方法,包括:(1)通过加热高分子量聚合物和低分子量材料的混合物形成均匀溶液,其中所述低分子量材料组成 至少约50重量%的均匀溶液,(2)通过将步骤(1)中形成的均匀溶液分散在惰性物质中形成分散溶液,(3)冷却分散溶液使高分子量聚合物相 与低分子量材料分离,(4)形成由所述低分子量材料构成的固体颗粒,所述低分子量材料被捕获在所述高分子量聚合物的细胞结构内,和(5)从分散溶液中除去固体颗粒。

    Process for preparing porous bioresorbable material having interconnected pores
    37.
    发明申请
    Process for preparing porous bioresorbable material having interconnected pores 审中-公开
    制备具有互连孔的多孔生物可再吸收材料的方法

    公开(公告)号:US20030146532A1

    公开(公告)日:2003-08-07

    申请号:US10038419

    申请日:2002-01-02

    Abstract: The present invention provides a process for preparing a porous bioresorbable material having interconnected pores. A bioresorbable polymer and a low molecular weight oligomer are dissolved in an organic solvent to form a bioresorbable polymer solution. The bioresorbable polymer has a molecular weight greater than 20,000 and the oligomer has a molecular weight of 200 to 4000. The bioresorbable polymer solution is then contacted with a coagulant to form a porous bioresorbable material.

    Abstract translation: 本发明提供一种制备具有互连孔的多孔生物可再吸收材料的方法。 将生物可再吸收聚合物和低分子量低聚物溶解在有机溶剂中以形成生物可再吸收的聚合物溶液。 生物再吸收聚合物的分子量大于20,000,低聚物的分子量为200至4000.然后将生物可再吸收的聚合物溶液与凝结剂接触以形成多孔生物可再吸收材料。

    Fine polybenzimidazole-containing particles
    38.
    发明授权
    Fine polybenzimidazole-containing particles 失效
    含聚苯并咪唑的微粒

    公开(公告)号:US5223550A

    公开(公告)日:1993-06-29

    申请号:US888935

    申请日:1992-05-26

    Abstract: Fine, porous polybenzimidazole-containing particles prepared by spray-atomizing/quenching a polybenzimidazole-containing polymer solution into porous polybenzimidazole-containing particles, and fluidized bed, oppose jet milling the particles into fine, porous polybenzimidazole-containing particles. The milled particles exhibit a narrow particle size distribution centered at about a 5 .mu.m mean particle size, a surface area of about 35 m.sup.2 /g, and an open porosity of about 1.2 cm.sup.2 /gm which is at pore radius of less than about 100 nm.

    Abstract translation: 通过将含聚苯并咪唑的聚合物溶液喷雾雾化/猝灭制备成多孔聚苯并咪唑的颗粒和流化床制备的细微多孔的含聚苯并咪唑的颗粒相对于将颗粒喷射研磨成细微多孔的含聚苯并咪唑的颗粒。 研磨的颗粒表现出以约5μm平均颗粒大小为中心的窄粒度分布,约35m 2 / g的表面积和约1.2cm 2 / gm的孔隙度,其孔径小于约100 nm。

    Highly porous compressible polymeric powders
    39.
    发明授权
    Highly porous compressible polymeric powders 失效
    高度多孔的可压缩聚合物粉末

    公开(公告)号:US5169871A

    公开(公告)日:1992-12-08

    申请号:US852608

    申请日:1992-03-17

    Abstract: A process for forming polymer powders by dissolving one or more polymers in a suitable solvent, followed by atomizing the solution into a droplet atmosphere of a non-solvent to precipitate polymer particles. The particles are separated from the non-solvent, washed and dried to produce a powder with a rounded particle morphology, high internal porosity and surface area, and high apparent density.Polymer powders with these properties can be pressed to dense shaped articles suitable for sintering in automated presses because the powders have good low and compressibility characteristics. The process if particularly useful when applied to soluble polymers that are not readily shaped by melt processing means.

    Abstract translation: 通过将一种或多种聚合物溶解在合适的溶剂中形成聚合物粉末的方法,然后将溶液雾化成非溶剂的液滴气氛以沉淀聚合物颗粒。 将颗粒与非溶剂分离,洗涤并干燥以产生具有圆形颗粒形态,高内部孔隙率和表面积以及高表观密度的粉末。 具有这些性能的聚合物粉末可以压制成适合于自动压力机中烧结的致密成形制品,因为粉末具有良好的低和可压缩特性。 该方法在应用于不容易通过熔融加工方法成型的可溶性聚合物时特别有用。

Patent Agency Ranking