公开(公告)号：WO2009080660A1

公开(公告)日：2009-07-02

申请号：PCT/EP2008/067772

申请日：2008-12-17

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MAZZUCCO, Antonio ,  RINALDI, Riccardo ,  SOFFRITTI, Silvia ,  BALESTRA, Enrico ,  PENZO, Giuseppe ,  MEI, Gabriele

Inventor： MAZZUCCO, Antonio ,  RINALDI, Riccardo ,  SOFFRITTI, Silvia ,  BALESTRA, Enrico ,  PENZO, Giuseppe ,  MEI, Gabriele

IPC: B01J19/24 ,  C08F10/00

CPC classification number: B01J19/2435 ,  B01J2219/00164 ,  B01J2219/00166 ,  B01J2219/00173 ,  C08F10/00 ,  C08F110/06 ,  C08F210/06 ,  C08F2/34 ,  C08F2/001 ,  C08F2500/05 ,  C08F210/16

Abstract: A process for the gas-phase polymerization of α-olefms carried out in two interconnected polymerization zones, wherein the growing polymer particles flow through the first of said polymerization zones (riser) under fast fluidization conditions, leave said riser and enter the second of said polymerization zones (downcomer) through which they flow downward in a densified form, the process being characterized in that: (a) the gas mixture present in the riser is totally or partially prevented from entering the downcomer by introducing into the upper part of said downcomer a liquid stream LB having a composition different from the gaseous mixture present in the riser; (b) the ratio R between the flow rate F p of polymer circulated between said downcomer and said riser and the flow rate LB of said liquid being adjusted in a range from 10 to 50.

Abstract translation: 一种用于在两个相互连接的聚合区中进行的α-烯烃的气相聚合的方法，其中生长的聚合物颗粒在快速流化条件下流过第一个所述聚合区（提升管），离开所述提升管并进入所述 聚合区（降液管），通过它们以致密化形式向下流动，该方法的特征在于：（a）通过引入所述降液管的上部，存在于提升管中的气体混合物被全部或部分地防止进入降液管 具有与提升管中存在的气体混合物不同的组成的液体流LB; （b）在所述降液管和所述提升管之间循环的聚合物的流量Fp与所述液体的流量LB之间的比R调节在10至50的范围内。

公开(公告)号：WO2009077293A1

公开(公告)日：2009-06-25

申请号：PCT/EP2008/066103

申请日：2008-11-25

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAVALIERI, Claudio ,  GALVAN, Monica

Inventor： CAVALIERI, Claudio ,  GALVAN, Monica

IPC: C08L23/10

CPC classification number: C08L23/10 ,  C08K5/005 ,  C08K5/0083 ,  C08K5/14 ,  C08L23/20 ,  C08L23/22 ,  Y10T428/1352 ,  C08L2666/06 ,  C08L2666/08

Abstract: A polyolefin composition having good transparency and mechanical properties comprising, all percent amounts being by weight: A) from 70 to 98% of a propylene homopolymer or copolymer having haze of 25% or less and melting temperature of 130°C or higher; and B) from 2 to 30% of a butene-1 copolymer containing from 0.5 to 30% of one or more comonomer(s).

Abstract translation: 具有良好的透明性和机械性能的聚烯烃组合物，其全部百分数为重量百分比：A）70-98％的雾度为25％或更低，熔点为130℃或更高的丙烯均聚物或共聚物; 和B）2至30％的含有0.5至30％的一种或多种共聚单体的丁烯-1共聚物。

公开(公告)号：WO2009056461A1

公开(公告)日：2009-05-07

申请号：PCT/EP2008/064087

申请日：2008-10-20

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  ARICH DE FINETTI, Nicolo'

Inventor： ARICH DE FINETTI, Nicolo'

IPC: C08F10/00 ,  C08F2/06

CPC classification number: C08F10/00 ,  C08F10/06 ,  C08F210/06 ,  C08F2400/02 ,  C08F2/06 ,  C08F2/00 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/17

Abstract: A method for controlling a solution process for the polymerisation of olefins is disclosed. The method is based on an algorithm that calculates predicted operating parameters of the process, including calculation of the extent of reaction (ξ), as a function of the solution density (ρ), and then calculation of the whole composition of the solution. The algorithm resolves a system of equations comprising the equation of state in the PC-SAFT form, the Lewis-Mayo equation for monomer incorporation into a copolymer, and the stoichiometry equation. Predicted parameters are compared to target parameters to detect possible deviations and implement corresponding compensation in the feed.

Abstract translation: 公开了一种用于控制烯烃聚合的溶液方法的方法。 该方法基于计算过程的预测操作参数的算法，包括作为溶液密度（λ）的函数的反应程度（？）的计算，然后计算溶液的整体组成。 该算法解决了包含PC-SAFT形式的状态方程，单体掺入共聚物的Lewis-Mayo方程式和化学计量方程式的方程组。 将预测参数与目标参数进行比较，以检测可能的偏差并在进料中实现相应的补偿。

公开(公告)号：WO2009053222A1

公开(公告)日：2009-04-30

申请号：PCT/EP2008/063029

申请日：2008-09-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MOSCARDI, Gilberto ,  COSTANTINI, Enrico

Inventor： MOSCARDI, Gilberto ,  COSTANTINI, Enrico

IPC: C08L23/08 ,  C08L23/10 ,  C08L51/00

CPC classification number: C08L23/10 ,  C08L23/0815 ,  C08L23/16 ,  C08L51/00 ,  C08L2666/06 ,  C08L2666/24

Abstract: Thermoset polyolefin elastomer obtained by static curing with water a silane-grafted thermoplastic heterophasic polyolefin composition (I) having a flexural modulus equal to or lower than 150 MPa, and comprising: (a) a crystalline propylene homopolymer or copolymer of propylene with up to 15% by weight of ethylene or other alpha-olefin comonomer(s), or their combinations, and (b) a copolymer or a composition of copolymers of ethylene with other alpha-olefins containing from 15% by weight to less then 40% by weight of ethylene; said thermoset polyolefin elastomer having a compression set value of from 30 to 65%, a ratio of elongation at break to compression set values of above 8, and hardness shore A values below 90.

Abstract translation: 通过用水静态固化获得的热固性聚烯烃弹性体，其具有等于或低于150MPa的挠曲模量的硅烷接枝的热塑性多相聚烯烃组合物（I），并且包含：（a）结晶丙烯均聚物或丙烯与多达15个共聚物 乙烯或其它α-烯烃共聚单体或其组合的重量％，和（b）乙烯与其它含有15重量％至小于40重量％的α-烯烃的共聚物或共聚物的共聚物或组合物 的乙烯; 所述热固性聚烯烃弹性体具有压缩永久变形值为30至65％，断裂伸长率与压缩永久变形值之比8以及硬度Shore A值低于90。

公开(公告)号：WO2009050025A1

公开(公告)日：2009-04-23

申请号：PCT/EP2008/062998

申请日：2008-09-29

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  SUNALLOMER LTD ,  PELLEGATTI, Giampaolo ,  GOBERTI, Paolo ,  BARALDI, Letizia ,  MINOWA, Kazuhiko ,  HISANAGA, Yukihiro

Inventor： PELLEGATTI, Giampaolo ,  GOBERTI, Paolo ,  BARALDI, Letizia ,  MINOWA, Kazuhiko ,  HISANAGA, Yukihiro

IPC: C08L23/08

CPC classification number: C08L23/0815 ,  C08L23/10 ,  C08L2205/02 ,  C08L2666/06

Abstract: Polyolefin composition comprising, in percent by weight: A) 50-75% of a blend of polymers (PP) and (EC I ), wherein (PP) is selected from the group consisting of: (i) propylene homopolymers; (ii) copolymers of propylene; (iii) combinations of said homopolymers (i) and copolymers (ii); (EC 1 ) is a copolymer of ethylene and propylene or CH 2 =CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical, or a copolymer of ethylene, propylene and the said CH 2 =CHR alpha-olefin(s), containing from 20 to 35%, of ethylene; and B) 25-50% of a copolymer (EC II ) of ethylene and propylene or CH 2 =CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical,or a copolymer of ethylene, propylene and the said CH 2 =CHR alpha-olefin(s), containing from 40 to 60% of ethylene; in which composition the copolymer component (EC I ) is present in amounts from 23 to 45% with respect to the total weight of (A),and the intrinsic viscosity [η tot ] of the fraction XS soluble in xylene at room temperature, referred to the total weight of (A) + (B), is of 3.5 dl/g or more.

Abstract translation: 聚烯烃组合物，其以重量百分比计包含：A）50-75％的聚合物（PP）和（ECI）共混物，其中（PP）选自：（i）丙烯均聚物; （ii）丙烯的共聚物; （iii）所述均聚物（i）和共聚物（ii）的组合; （EC1）是乙烯和丙烯或CH 2 =CHRα-烯烃的共聚物，其中R是2-8个碳的烷基，或乙烯，丙烯和所述的CH 2 = CHR的α-烯烃的共聚物 ），含有20至35％的乙烯; 和B）乙烯和丙烯或CH 2 =CHRα-烯烃的共聚物（ECII）的25-50％，其中R是2-8个碳的烷基，或乙烯，丙烯和所述的CH2的共聚物 = CHRα-烯烃，含有40至60％的乙烯; 在该组合物中，相对于（A）的总重量，共聚物组分（ECI）的存在量为23-45％，室温下可溶于二甲苯的级分XS的特性粘度[ηtot] （A）+（B）的总重量为3.5dl / g以上。

公开(公告)号：WO2009010413A1

公开(公告)日：2009-01-22

申请号：PCT/EP2008/058751

申请日：2008-07-07

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： GOVONI, Gabriele ,  PATRONCINI, Giovanni

IPC: C08F2/12 ,  C08F10/00

CPC classification number: C08F10/06 ,  C08F210/06 ,  C08F2/001 ,  C08F4/6492 ,  C08F2/005 ,  C08F4/651 ,  C08F210/16

Abstract: A process for the polymerization of olefins comprising: a) polymerizing at least a liquid olefin monomer in a polymerization reactor to form a polymerization slurry comprising a polyolefin and said liquid monomer; b) continuously transferring the polymerization slurry from the polymerization reactor to a flash chamber by means of a transfer line comprising a pipe where a turbulent flow of a tri-phase stream comprising polymer, liquid monomers, and gaseous monomers is established; c) separating the evaporated monomer from the polymer in said flash chamber; the process being characterized in that an anti-fouling agent in a liquid form is continuously introduced upstream the inlet of said pipe of step (b).

Abstract translation: 一种用于烯烃聚合的方法，包括：a）在聚合反应器中聚合至少一种液态烯烃单体以形成包含聚烯烃和所述液体单体的聚合浆料; b）通过包括管的输送管线将聚合淤浆从聚合反应器连续转移到闪蒸室，其中建立了包含聚合物，液体单体和气态单体的三相流的湍流; c）在所述闪蒸室中分离蒸发的单体与聚合物; 该方法的特征在于，在步骤（b）的所述管的入口的上游连续引入液体形式的防污剂。

公开(公告)号：WO2008142019A1

公开(公告)日：2008-11-27

申请号：PCT/EP2008/056042

申请日：2008-05-16

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  CAGNANI, Camillo ,  BECCARINI, Enrico ,  CAVALIERI, Claudio

Inventor： CAGNANI, Camillo ,  BECCARINI, Enrico ,  CAVALIERI, Claudio

IPC: C08F210/06

CPC classification number: C08F210/06 ,  C08F210/16 ,  C08F2500/11 ,  C08F2500/20

Abstract: A propylene polymer composition having a Flexural modulus lower than 500MPa, a total ethylene content from 9 to 30% by weight, a xylene soluble fraction at room temperature higher than 25% by weight, a melting temperature measured by DSC (Tm°C) from 130 to 150°C and a ratio between the weight of xylene soluble fraction at 25°C and the hexane soluble fraction determined on plaque (100μm) of higher than 4.

Abstract translation: 弯曲模量低于500MPa，总乙烯含量为9〜30重量％，室温下二甲苯可溶成分高于25重量％的丙烯聚合物组合物，DSC测定的熔融温度（Tm℃） 130℃〜150℃，二甲苯可溶成分在25℃下的重量与在斑块（100μm）上测定的己烷可溶成分之比高于4。

公开(公告)号：WO2008074712A1

公开(公告)日：2008-06-26

申请号：PCT/EP2007/063820

申请日：2007-12-12

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  MASARATI, Enrico ,  COSTANTINI, Enrico

Inventor： MASARATI, Enrico ,  COSTANTINI, Enrico

IPC: C08L23/10 ,  C08K3/00

CPC classification number: C08L53/005 ,  C08F110/06 ,  C08L23/10 ,  C08L51/06 ,  C08L2666/24 ,  C08L2666/06 ,  C08L2666/04 ,  C08L2666/02 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/24 ,  C08F2500/03 ,  C08F2500/04

Abstract: Polypropylene compositions having a MFR value (2.16 kg, 230 °C) from 15 to 200 g/10 min., comprising: A) a propylene polymer or polymer composition selected from propylene homopolymers or copolymers of propylene containing up to 5% by moles of comonomer(s), said homopolymers and copolymers having values of MFR, obtained without degradation treatments, from 500 to 2500 g/10 min., or combinations of the said homopolymers or copolymers; B) a filler or pigment, or their combinations; and optionally C) from 0.5 to 5% by weight, with respect to the total weight of A), B) and C), of a compatibilizer.

Abstract translation: 具有15-200g / 10min的MFR值（2.16kg，230℃）的聚丙烯组合物包括：A）丙烯聚合物或聚合物组合物，其选自丙烯均聚物或含有至多5摩尔％ 共聚单体，所述均聚物和共聚物具有不降解处理获得的MFR值，500至2500g / 10min，或所述均聚物或共聚物的组合; B）填料或颜料，或其组合; 和任选的C）相对于相容剂的A），B）和C）的总重量的0.5至5重量％。

公开(公告)号：WO2008064958A1

公开(公告)日：2008-06-05

申请号：PCT/EP2007/061145

申请日：2007-10-18

Applicant: BASELL POLIOLEFINE ITALIA S.R.L. ,  PRADELLA, Fiorella

Inventor： PRADELLA, Fiorella

IPC: C08K5/00 ,  C08K5/56 ,  C08L23/00 ,  C08L23/18

CPC classification number: C08K5/0091 ,  C08L23/18

Abstract: A process for producing a polybutene-1 composition having increased crystallization temperature T c A , comprising the step of blending the following components: A) a butene-1 polymer or polymer composition having crystallization temperature T c A equal to or higher than 50 °C; B) 50 to 3000 ppm by weight, with respect to the total weight of A) and B), of one or more metal complexes of polyhydric alcohols; said butene-1 polymer or polymer composition A) being brought to the molten state or maintained in the molten state during the blending step.

Abstract translation: 一种制备结晶温度升高的聚丁烯-1组合物的方法，包括混合以下组分的步骤：A） 具有等于​​或高于50℃的结晶温度T℃≤A的丁烯-1聚合物或聚合物组合物; B）相对于A）和B）的总重量为50-3000重量ppm的一种或多种多元醇的金属络合物; 所述丁烯-1聚合物或聚合物组合物A）在混合步骤期间变为熔融状态或维持熔融状态。

公开(公告)号：WO2008058839A2

公开(公告)日：2008-05-22

申请号：PCT/EP2007/061432

申请日：2007-10-24

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： PENZO, Giuseppe ,  RINALDI, Roberto

IPC: C08F10/00 ,  C08F297/08 ,  C08L23/00

CPC classification number: B01J8/1809 ,  B01J8/26 ,  B01J2208/00539 ,  B01J2208/0061 ,  B01J2219/00006 ,  B01J2219/0004 ,  C08F10/06 ,  C08F110/06 ,  C08F210/06 ,  C08L23/10 ,  C08L23/16 ,  C08L2308/00 ,  C08F2/34 ,  C08F2/001 ,  C08L2666/06 ,  C08F2500/12 ,  C08F210/16

Abstract: A process for the multistage polymerization of olefins comprising a gas-phase polymerization carried out in at least two serially connected gas-phase reactors, the continuous discharge of polymer and gas reaction mixture from an upstream reactor into a transfer device and the continuous feeding of polymer from said transfer device to a downstream reactor, said transfer device comprising: a) a separation chamber in which said gas reaction mixture is removed from the polymer; b) at least a couple of lock hoppers working intermittently in parallel, where one of said lock hoppers is continuously filled with the polymer coming from step a), while simultaneously the other one is continuously pressurized by means of a gas comprising the reaction mixture coming from said downstream reactor.

Abstract translation: 一种用于烯烃多段聚合的方法，包括在至少两个串联连接的气相反应器中进行的气相聚合，将聚合物和气体反应混合物从上游反应器连续排放到转移装置中以及连续进料聚合物 从所述转移装置到下游反应器，所述转移装置包括：a）分离室，其中所述气体反应混合物从聚合物中除去; b）至少两个平行间歇地工作的锁定料斗，其中一个所述锁定料斗连续填充来自步骤a）的聚合物，同时另一个通过包含反应混合物的气体连续加压 从所述下游反应器。