公开(公告)号：WO2012158870A1

公开(公告)日：2012-11-22

申请号：PCT/US2012/038264

申请日：2012-05-17

Applicant: ARKEMA INC. ,  KENNOY, Debra H. ,  VAN HORN, Brett L. ,  CHEN, Benjamin Bin ,  BONNET, Philippe

Inventor： KENNOY, Debra H. ,  VAN HORN, Brett L. ,  CHEN, Benjamin Bin ,  BONNET, Philippe

IPC: C07C21/18

CPC classification number: A62D1/0028 ,  C08J9/144 ,  C08J2203/162 ,  C08J2203/202 ,  C09K3/00 ,  C09K3/30 ,  C09K5/044 ,  C09K5/045 ,  C09K2205/122 ,  C09K2205/126 ,  C10M171/008 ,  C10N2220/30 ,  C10N2220/301 ,  C10N2230/00 ,  C11D7/30 ,  C11D7/5018 ,  C11D7/5054

Abstract: The present invention relates to non-flammable compositions comprising chlorotrifluoropropene with reduced risk of flammability which are useful as refrigerants, heat transfer fluids, solvents, cleaners, blowing agents, aerosols, extraction fluids, and the like.

Abstract translation: 本发明涉及包含氯三氟丙烯的不可燃组合物，其具有降低的可燃性的风险，其可用作制冷剂，传热流体，溶剂，清洁剂，发泡剂，气溶胶，萃取液等。

公开(公告)号：WO2011137033A1

公开(公告)日：2011-11-03

申请号：PCT/US2011/033513

申请日：2011-04-22

Applicant: ARKEMA INC. ,  CHEN, Benjamin B. ,  COSTA, Joseph S. ,  BONNET, Philippe

Inventor： CHEN, Benjamin B. ,  COSTA, Joseph S. ,  BONNET, Philippe

IPC: C08G18/00

CPC classification number: C08J9/08 ,  C08G18/4018 ,  C08G18/4027 ,  C08G18/544 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/005 ,  C08J9/0019 ,  C08J9/0023 ,  C08J9/0095 ,  C08J9/02 ,  C08J9/12 ,  C08J2203/02 ,  C08J2203/162 ,  C08J2203/184 ,  C08J2375/04

Abstract: The present invention is directed towards a method of stabilizing thermosetting foam blends such as polyurethane poly blends containing a blowing agent with negligible (low or zero) ozone-depletion and low GWP based upon unsaturated halogenated hydroolefins in which one or more ester is added to the thermosetting foam blends. The thermosetting foam blends typically in clued: polyol(s); surfactant(s); catalyst(s); flame retardent(s); organic acid inhibitor(s)/stabilizer(s); carbon dioxide generating agent(s). The addition of the one or more esters to the thermosetting foam blends was unexpectedly found to result in blends which were stable over time and the resulted foams have a uniform cell structure with little or no foam collapse.

Abstract translation: 本发明涉及一种稳定热固性泡沫共混物的方法，例如含有可忽略的（低或零）臭氧消耗和基于不饱和卤代烃的低GWP的发泡剂的聚氨酯聚合物混合物，其中将一种或多种酯加入到 热固性泡沫共混物。 热固性泡沫塑料通常在线索：多元醇; 表面活性剂（S）; 催化剂（S）; 阻燃剂; 有机酸抑制剂/稳定剂; 二氧化碳发生剂。 意外地发现将一种或多种酯加入到热固性泡沫共混物中导致随时间稳定的共混物，并且所得泡沫具有均匀的泡孔结构，几乎没有或没有泡沫破裂。

公开(公告)号：WO2011060211A1

公开(公告)日：2011-05-19

申请号：PCT/US2010/056440

申请日：2010-11-12

Applicant: ARKEMA INC. ,  ELSHEIKH, Maher Y. ,  BONNET, Philippe

Inventor： ELSHEIKH, Maher Y. ,  BONNET, Philippe

IPC: C07C21/04

CPC classification number: C07C17/389 ,  C07C17/42 ,  C07C21/04 ,  C07C19/01

Abstract: The present invention is directed towards a method of purification of chloroolefins having 3 carbons and to a method to provide stable compositions of chloroolefins having 3 carbons. The chloroolefins are purified via the use of a solid adsorbents for the removal of decomposition product such as phosgene and/or phosgene precursory from the reaction of the chloroolefins with oxygen. The chloroolefins stabilized against an increase of the phosgene level via the addition of inhibitors to the chloroolefins.

Abstract translation: 本发明涉及一种纯化具有3个碳原子的烯烃的方法，以及提供具有3个碳原子的氯烯烃的稳定组合物的方法。 氯烯烃通过使用固体吸附剂进行纯化，用于从氯烯烃与氧的反应中去除分解产物如光气和/或光气。 氯烯烃通过向氯烯烃中加入抑制剂而稳定，防止光气含量增加。

公开(公告)号：WO2011031598A1

公开(公告)日：2011-03-17

申请号：PCT/US2010/047453

申请日：2010-09-01

Applicant: ARKEMA INC. ,  COSTA, Joseph, S. ,  CHEN, Benjamin, B. ,  BONNET, Philippe

Inventor： COSTA, Joseph, S. ,  CHEN, Benjamin, B. ,  BONNET, Philippe

IPC: C23C16/455

CPC classification number: C08G18/4018 ,  C08G2101/0025 ,  C08G2101/005 ,  C08J9/146 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/18 ,  C08J2375/04

Abstract: The present invention relates to a method of producing more uniformly distributed polyurethane form using blowing agents. More particularly, the present invention relates to a method of producing more uniformly distributed polyurethane foam for an application in which flow of liquid polyurethane foam prior to solidification is important to its performance using a hydrochlorofluoroolefin (HCFO), such as 1233zd.

Abstract translation: 本发明涉及使用发泡剂制备更均匀分布的聚氨酯形式的方法。 更具体地说，本发明涉及生产更均匀分布的聚氨酯泡沫的方法，其中在凝固之前液体聚氨酯泡沫的流动对于使用氢氯氟烯烃（HCFO）如1233zd的性能来说是重要的。

公开(公告)号：WO2009158321A1

公开(公告)日：2009-12-30

申请号：PCT/US2009/048214

申请日：2009-06-23

Applicant: ARKEMA INC. ,  ELSHEIKH, Maher, Y. ,  BONNET, Philippe

Inventor： ELSHEIKH, Maher, Y. ,  BONNET, Philippe

IPC: C07C17/00

CPC classification number: C07C21/18 ,  C07C17/206 ,  C07C17/21 ,  C07C17/383 ,  C07C17/42 ,  C07C19/10 ,  C07C19/08

Abstract: A one reactor, gas phase catalyzed process for the fluorination of 1,1,2,3-tetrachloropropene (1230xa) to produce 1,1,1,2-tetrafluoropropene (1234yf) is disclosed. The process of the present invention is a catalytic, gas phase fluorination using a high pressure activated catalyst which is supported or unsupported. Fluorination products of the formula CF3R, where R is selected from -CCl=CH2, -CF=CH2, -CF2-CH3, -CFCl-CH3 and mixtures thereof are produced. Co-produced materials are separated from the desired product and recycled to the same reactor.

Abstract translation: 公开了一种用于氟化1,1,2,3-四氯丙烯（1230xa）以制备1,1,1,2-四氟丙烯（1234yf）的气相催化方法。 本发明的方法是使用负载或未负载的高压活化催化剂的催化气相氟化。 制备式CF 3 R的氟化产物，其中R选自-CCl = CH 2，-CF = CH 2，-CF 2 -CH 3，-CFCl-CH 3及其混合物。 将共同生产的材料与所需产物分离并再循环至相同的反应器。

公开(公告)号：WO2009151669A1

公开(公告)日：2009-12-17

申请号：PCT/US2009/036266

申请日：2009-03-06

Applicant: ARKEMA INC. ,  VAN HORN, Brett L. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  CROOKER, Richard M.

Inventor： VAN HORN, Brett L. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  ELSHEIKH, Maher Y. ,  CROOKER, Richard M.

IPC: C09K5/00

CPC classification number: C09K5/044 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/112 ,  C09K2205/122 ,  C09K2205/126 ,  C09K2205/32 ,  C09K2205/40 ,  C09K2205/41 ,  C10M171/008 ,  C10M2203/065 ,  C10M2203/1006 ,  C10M2205/028 ,  C10M2205/0285 ,  C10M2205/223 ,  C10M2207/2835 ,  C10M2209/043 ,  C10M2209/1033 ,  C10N2040/30 ,  C10N2220/301 ,  C10N2220/302 ,  C10N2220/303 ,  C10N2220/305 ,  C10N2240/30 ,  F25B1/053 ,  F25B1/10 ,  F25B9/006 ,  F25B31/002 ,  F25B2339/047 ,  F25B2400/18

Abstract: The invention relates to heat transfer agents and heat transfer compositions containing hydrocarbon lubricating oils and halogentaed alkene heat transfer fluid that promote oil flow and provide for improved oil return. The heat transfer compositions are useful in various heat transfer systems such as refrigeration, cooling, air conditioning, chiller operations.

Abstract translation: 本发明涉及含有烃润滑油和卤代烯烃传热流体的传热剂和传热组合物，其促进油流并提供改善的回油。 传热组合物可用于各种传热系统，例如制冷，冷却，空调，冷冻机操作。

公开(公告)号：WO2009110925A1

公开(公告)日：2009-09-11

申请号：PCT/US2008/076785

申请日：2008-09-18

Applicant: ARKEMA INC. ,  CHEN, Benjamin B. ,  BONNET, Philippe

Inventor： CHEN, Benjamin B. ,  BONNET, Philippe

IPC: C09K5/04

CPC classification number: C09K5/044 ,  C08J9/149 ,  C08J2203/12 ,  C08J2203/142 ,  C08J2207/04 ,  C09K2205/11 ,  C09K2205/32 ,  C11D7/5086

Abstract: Provided are azeotrope-like compositions comprising 1,1,1-trifluoro-3-chloropropene (HCFO-1233zd) and dimethoxymethane and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, solvent, and aerosol propellants.

Abstract translation: 提供包含1,1,1-三氟-3-氯丙烯（HCFO-1233zd）和二甲氧基甲烷的类共沸组合物及其用途，包括用于制冷剂组合物，制冷系统，发泡剂组合物，溶剂和气溶胶推进剂中。

公开(公告)号：WO2009035893A1

公开(公告)日：2009-03-19

申请号：PCT/US2008/075165

申请日：2008-09-04

Applicant: ARKEMA INC. ,  BONNET, Philippe ,  ELSHEIKH, Maher Y.

Inventor： BONNET, Philippe ,  ELSHEIKH, Maher Y.

IPC: C07C17/00

CPC classification number: C07C17/358 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389 ,  C07C21/18 ,  C08J9/146 ,  C09K3/30 ,  C09K5/045 ,  C09K2205/126 ,  C09K2205/22 ,  Y02P20/127

Abstract: Disclosed are the combinations containing Z and E stereoisomers of hydrofluoroolefins where the more toxic isomer is less than about 30 % weight of the combination (vs the sum of Z+E), to minimize the toxicity impact in the applications they will be used for such as cooling and heat fluids, foams blowing agents or solvents. Also disclosed are means to obtain combinations containing Z and E stereoisomers of hydrofluoroolefins.

Abstract translation: 公开了含有氢氟烯烃的Z和E立体异构体的组合，其中较毒的异构体小于组合的约30重量％（相对于Z + E的总和），以最小化其将用于这些的应用中的毒性影响 作为冷却和热流体，泡沫发泡剂或溶剂。 还公开了获得含有氢氟烯烃的Z和E立体异构体的组合的方法。

公开(公告)号：WO2009003165A1

公开(公告)日：2008-12-31

申请号：PCT/US2008/068560

申请日：2008-06-27

Applicant: ARKEMA INC. ,  ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  VAN HORN, Brett L.

Inventor： ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  CHEN, Benjamin B. ,  VAN HORN, Brett L.

IPC: C08F2/00

CPC classification number: C09K5/045 ,  A62D1/0028 ,  A62D1/0057 ,  C08F2/42 ,  C08J9/144 ,  C08J9/146 ,  C08J9/149 ,  C08J2325/06 ,  C08J2375/04 ,  C09K3/30 ,  C09K5/044 ,  C09K2205/126 ,  C11D3/0073 ,  C11D3/0084 ,  C11D7/5018 ,  C23G5/02809 ,  C23G5/02861

Abstract: Disclosed is a combination of hydrofluoroolefins and/or hydrochlorofluoroolefins with stabilizers wherein the stabilizers minimize the degradation of the hydrofluoroolefins and hydrochlorofluoroolefins during storage, handling and use yet allow for atmospheric degradation. The combinations exhibit low or zero ozone depletion potential and lower global warming potential making them of interest as replacements for chlorofluorocarbons and hydrfluorocarbons. The combinations of the present invention comprise hydrofluoroolefins and/or hydrochlorofluoroolefins in combination with a stabilizer or stabilizers selected from free radical scavengers, acid scavengers, oxygen scavengers, polymerization inhibitors and combinations thereof.

Abstract translation: 公开了氢氟烯烃和/或氢氯氟烯烃与稳定剂的组合，其中稳定剂使储存，处理和使用期间氢氟烯烃和氢氯氟烯烃的降解最小化，但允许大气降解。 这些组合表现出低或零臭氧消耗潜力和较低的全球变暖潜力，使其成为氯氟烃和氢氟碳化物的替代品。 本发明的组合包括与选自自由基清除剂，酸清除剂，除氧剂，聚合抑制剂及其组合的稳定剂或稳定剂组合的氢氟烯烃和/或氢氯氟烯烃。

公开(公告)号：WO2009003157A1

公开(公告)日：2008-12-31

申请号：PCT/US2008/068510

申请日：2008-06-27

Applicant: ARKEMA INC. ,  ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  WENDLINGER, Laurent

Inventor： ELSHEIKH, Maher Y. ,  BONNET, Philippe ,  WENDLINGER, Laurent

IPC: C07C17/00

CPC classification number: C07C21/18 ,  C07C17/206 ,  C07C17/25 ,  C07C17/278 ,  C07C19/08 ,  C07C19/01

Abstract: The present invention discloses a process for the synthesis of hydrofluoroolefins (HFO). The process is based on the following two steps: the liquid phase fluorination of a hydrochloropropane(s) to hydrofluoropropane(s) (HFP) followed by the dehydrofluorination of the hydrofluoropropane(s) (HFP) to hydrofluoroolefins (HFO).

Abstract translation: 本发明公开了一种合成氢氟烯烃（HFO）的方法。 该方法基于以下两个步骤：将氢氯丙烷与氟代丙烷（HFP）液相氟化，随后将氢氟烷（HFP）脱氢化为氢氟烯烃（HFO）。